(a) Interpretation: The compound that boils at 57 ° C and the compound that boils at 141 ° C are to be identified among propanoic acid and methyl acetate. Concept introduction: Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds predicted on the basis of dipole moment, the strength of hydrogen bonding, number of carbon, molecular weight, and branching.

Question

Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br OH Br

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 15, Problem 15.13E

Interpretation Introduction

(a)

Interpretation:

The compound that boils at 57°C and the compound that boils at 141°C are to be identified among propanoic acid and methyl acetate.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds predicted on the basis of dipole moment, the strength of hydrogen bonding, number of carbon, molecular weight, and branching.

Interpretation Introduction

(b)

Interpretation:

The compound amoung propanoic acid and methyl acetate which is more soluble compound in water is to be predicted.

Concept introduction:

Solubility is a chemical property of substances. It describes the maximum amount of substances that can be dissolving in the solvent. The solubility of a compound depends on the nature of the compound. More polar compounds have more solubility in water due to the formation of strong intermolecular hydrogen bonding with water molecule.

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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br OH Br

Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability. a) H₂O, OH, CH3COOT b) NH3, H₂O, H₂S

Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution reaction with CN as the nucleophile. Br A B NH2 LL F C D OH CI LLI E Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d). a) H "Cl D + -OCH 3 Page 3 of 5

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 15, Problem 15.13E

Interpretation Introduction

(a)

Interpretation:

The compound that boils at 57°C and the compound that boils at 141°C are to be identified among propanoic acid and methyl acetate.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds predicted on the basis of dipole moment, the strength of hydrogen bonding, number of carbon, molecular weight, and branching.

Interpretation Introduction

(b)

Interpretation:

The compound amoung propanoic acid and methyl acetate which is more soluble compound in water is to be predicted.

Concept introduction:

Solubility is a chemical property of substances. It describes the maximum amount of substances that can be dissolving in the solvent. The solubility of a compound depends on the nature of the compound. More polar compounds have more solubility in water due to the formation of strong intermolecular hydrogen bonding with water molecule.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 15, Problem 15.13E

Interpretation Introduction

(a)

Interpretation:

The compound that boils at 57°C and the compound that boils at 141°C are to be identified among propanoic acid and methyl acetate.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds predicted on the basis of dipole moment, the strength of hydrogen bonding, number of carbon, molecular weight, and branching.

Interpretation Introduction

(b)

Interpretation:

The compound amoung propanoic acid and methyl acetate which is more soluble compound in water is to be predicted.

Concept introduction:

Solubility is a chemical property of substances. It describes the maximum amount of substances that can be dissolving in the solvent. The solubility of a compound depends on the nature of the compound. More polar compounds have more solubility in water due to the formation of strong intermolecular hydrogen bonding with water molecule.

Expert Solution & Answer

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See solution

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 15, Problem 15.13E

Interpretation Introduction