Glycosidic linkage has to be located in cellobiose. Concept Introduction: Carbohydrates that are composed of two monosaccharide units are known as disaccharides. This is formed when one hydroxyl group of one monosaccharide reacts with a hydroxyl group of another monosaccharide. The bond formed between the two monosaccharide units is C − O bond and this linkage is known as glycosidic linkage. Carbon atom that is present in the glycosidic linkage is bonded to two oxygen atoms. Depending on the orientation of the glycosidic linkage, the glycoside bond can be of two types. They are α -glycoside and β -glycoside. In α -glycoside, the bond is oriented down from the carbon C1 while in β -glycoside, the bond is oriented up from the carbon C1 .

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Answer 1

Question

Chapter 14.5, Problem 14.16P

(a)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be located in cellobiose.

Concept Introduction:

Carbohydrates that are composed of two monosaccharide units are known as disaccharides. This is formed when one hydroxyl group of one monosaccharide reacts with a hydroxyl group of another monosaccharide. The bond formed between the two monosaccharide units is C−O bond and this linkage is known as glycosidic linkage. Carbon atom that is present in the glycosidic linkage is bonded to two oxygen atoms.

Depending on the orientation of the glycosidic linkage, the glycoside bond can be of two types. They are α-glycoside and β-glycoside. In α-glycoside, the bond is oriented down from the carbon C1 while in β-glycoside, the bond is oriented up from the carbon C1.

(b)

Interpretation Introduction

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

(c)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).

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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point

Answer 2

Question

Chapter 14.5, Problem 14.16P

(a)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be located in cellobiose.

Concept Introduction:

Carbohydrates that are composed of two monosaccharide units are known as disaccharides. This is formed when one hydroxyl group of one monosaccharide reacts with a hydroxyl group of another monosaccharide. The bond formed between the two monosaccharide units is C−O bond and this linkage is known as glycosidic linkage. Carbon atom that is present in the glycosidic linkage is bonded to two oxygen atoms.

Depending on the orientation of the glycosidic linkage, the glycoside bond can be of two types. They are α-glycoside and β-glycoside. In α-glycoside, the bond is oriented down from the carbon C1 while in β-glycoside, the bond is oriented up from the carbon C1.

(b)

Interpretation Introduction

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

(c)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).

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Answer 3

Question

Chapter 14.5, Problem 14.16P

(a)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be located in cellobiose.

Concept Introduction:

Carbohydrates that are composed of two monosaccharide units are known as disaccharides. This is formed when one hydroxyl group of one monosaccharide reacts with a hydroxyl group of another monosaccharide. The bond formed between the two monosaccharide units is C−O bond and this linkage is known as glycosidic linkage. Carbon atom that is present in the glycosidic linkage is bonded to two oxygen atoms.

Depending on the orientation of the glycosidic linkage, the glycoside bond can be of two types. They are α-glycoside and β-glycoside. In α-glycoside, the bond is oriented down from the carbon C1 while in β-glycoside, the bond is oriented up from the carbon C1.

(b)

Interpretation Introduction

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

(c)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).

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Answer 4

Question

Chapter 14.5, Problem 14.16P

(a)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be located in cellobiose.

Concept Introduction:

Carbohydrates that are composed of two monosaccharide units are known as disaccharides. This is formed when one hydroxyl group of one monosaccharide reacts with a hydroxyl group of another monosaccharide. The bond formed between the two monosaccharide units is C−O bond and this linkage is known as glycosidic linkage. Carbon atom that is present in the glycosidic linkage is bonded to two oxygen atoms.

Depending on the orientation of the glycosidic linkage, the glycoside bond can be of two types. They are α-glycoside and β-glycoside. In α-glycoside, the bond is oriented down from the carbon C1 while in β-glycoside, the bond is oriented up from the carbon C1.

(b)

Interpretation Introduction

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

(c)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).

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Answer 5

Chapter 14.5, Problem 14.16P

(a)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be located in cellobiose.

Concept Introduction:

Carbohydrates that are composed of two monosaccharide units are known as disaccharides. This is formed when one hydroxyl group of one monosaccharide reacts with a hydroxyl group of another monosaccharide. The bond formed between the two monosaccharide units is C−O bond and this linkage is known as glycosidic linkage. Carbon atom that is present in the glycosidic linkage is bonded to two oxygen atoms.

Depending on the orientation of the glycosidic linkage, the glycoside bond can be of two types. They are α-glycoside and β-glycoside. In α-glycoside, the bond is oriented down from the carbon C1 while in β-glycoside, the bond is oriented up from the carbon C1.

(b)

Interpretation Introduction

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

(c)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 14.5, Problem 14.16P

(a)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be located in cellobiose.

Concept Introduction:

Carbohydrates that are composed of two monosaccharide units are known as disaccharides. This is formed when one hydroxyl group of one monosaccharide reacts with a hydroxyl group of another monosaccharide. The bond formed between the two monosaccharide units is C−O bond and this linkage is known as glycosidic linkage. Carbon atom that is present in the glycosidic linkage is bonded to two oxygen atoms.

Depending on the orientation of the glycosidic linkage, the glycoside bond can be of two types. They are α-glycoside and β-glycoside. In α-glycoside, the bond is oriented down from the carbon C1 while in β-glycoside, the bond is oriented up from the carbon C1.

Answer 7

Chapter 14.5, Problem 14.16P

(a)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be located in cellobiose.

Concept Introduction:

Carbohydrates that are composed of two monosaccharide units are known as disaccharides. This is formed when one hydroxyl group of one monosaccharide reacts with a hydroxyl group of another monosaccharide. The bond formed between the two monosaccharide units is C−O bond and this linkage is known as glycosidic linkage. Carbon atom that is present in the glycosidic linkage is bonded to two oxygen atoms.

Depending on the orientation of the glycosidic linkage, the glycoside bond can be of two types. They are α-glycoside and β-glycoside. In α-glycoside, the bond is oriented down from the carbon C1 while in β-glycoside, the bond is oriented up from the carbon C1.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.1 - Draw a Lewis structure for glucose that clearly...Ch. 14.2 - Prob. 14.2P Ch. 14.2 - Prob. 14.3P Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Rank the following compounds in order of...Ch. 14.2 - Prob. 14.6P Ch. 14.2 - Prob. 14.7P Ch. 14.2 - Prob. 14.8P Ch. 14.2 - Prob. 14.9P Ch. 14.3 - Prob. 14.10P

Solution Summary: The author explains the structure of cellobiose and the glycosidic linkage.

Concept explainers

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).

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Chapter 14 Solutions

Solution Summary: The author explains the structure of cellobiose and the glycosidic linkage.

Concept explainers

Interpretation: The carbon atoms has to be numbered in both rings of cellobiose.

Interpretation: Glycosidic linkage has to be classified as α or β in cellobiose. Concept Introduction: Refer part (a).

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Chapter 14 Solutions

Interpretation:

The carbon atoms has to be numbered in both rings of cellobiose.

Interpretation:

Glycosidic linkage has to be classified as α or β in cellobiose.

Concept Introduction:

Refer part (a).