PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
2nd Edition
ISBN: 9781266811852
Author: SMITH
Publisher: MCG
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Chapter 14.2, Problem 14.3P
Interpretation Introduction
Interpretation:
Given monosaccharide has to be classified based on the number of carbon atoms present in the chain and also the carbonyl group.
Concept Introduction:
Simplest carbohydrates are known as monosaccharides. They contain three to six carbons generally in a chain form with a carbonyl group present in the terminal or the adjacent carbon atom from the terminal. Monosaccharides that have the carbonyl group at the terminal carbon atom
The number of carbon atoms present in the chain characterize the monosaccharide. They are given below.
- Carbon chain with three carbon atoms is triose.
- Carbon chain with four carbon atoms is tetrose.
- Carbon chain with five carbon atoms is as pentose.
- Carbon chain with six carbon atoms is as hexose.
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42. Which of the following halogenated compounds can be used successfully to prepare a Grignard reagent for
alcohol synthesis by subsequent reaction with an aldehyde or ketone? Which ones cannot and why?
H3C CH3
a.
Br
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b.
Cl
C.
I H
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d. Cl
e.
H
OCH3
Br
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
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?
Will the first
MgBr
product that forms in this reaction
create a new CC bond?
olo
?
OH
جمله
O Yes
Ⓒ No
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Click and drag to start drawing a
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Yes
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X
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PH
Assign all the protons
Chapter 14 Solutions
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
Ch. 14.1 - Draw a Lewis structure for glucose that clearly...Ch. 14.2 - Prob. 14.2PCh. 14.2 - Prob. 14.3PCh. 14.2 - Prob. 14.4PCh. 14.2 - Rank the following compounds in order of...Ch. 14.2 - Prob. 14.6PCh. 14.2 - Prob. 14.7PCh. 14.2 - Prob. 14.8PCh. 14.2 - Prob. 14.9PCh. 14.3 - Prob. 14.10P
Ch. 14.3 - Prob. 14.11PCh. 14.4 - Prob. 14.12PCh. 14.4 - Prob. 14.13PCh. 14.4 - Prob. 14.14PCh. 14.4 - Prob. 14.15PCh. 14.5 - Prob. 14.16PCh. 14.5 - Prob. 14.17PCh. 14.5 - Prob. 14.18PCh. 14.5 - Prob. 14.19PCh. 14.6 - Prob. 14.20PCh. 14 - Prob. 14.21UKCCh. 14 - Prob. 14.22UKCCh. 14 - Prob. 14.23UKCCh. 14 - Prob. 14.24UKCCh. 14 - Prob. 14.25UKCCh. 14 - Prob. 14.26UKCCh. 14 - Prob. 14.27UKCCh. 14 - Prob. 14.28UKCCh. 14 - Prob. 14.29UKCCh. 14 - Prob. 14.30UKCCh. 14 - Prob. 14.31APCh. 14 - Prob. 14.32APCh. 14 - Prob. 14.33APCh. 14 - Prob. 14.34APCh. 14 - Prob. 14.35APCh. 14 - Prob. 14.36APCh. 14 - Prob. 14.37APCh. 14 - Prob. 14.38APCh. 14 - Prob. 14.39APCh. 14 - Prob. 14.40APCh. 14 - Prob. 14.41APCh. 14 - Prob. 14.42APCh. 14 - Prob. 14.43APCh. 14 - Prob. 14.44APCh. 14 - Prob. 14.45APCh. 14 - Prob. 14.46APCh. 14 - Prob. 14.47APCh. 14 - Prob. 14.48APCh. 14 - Prob. 14.49APCh. 14 - Prob. 14.50APCh. 14 - Prob. 14.51APCh. 14 - Prob. 14.52APCh. 14 - Prob. 14.53APCh. 14 - Prob. 14.54APCh. 14 - Prob. 14.55APCh. 14 - Prob. 14.56APCh. 14 - Prob. 14.57APCh. 14 - Prob. 14.58APCh. 14 - Prob. 14.59APCh. 14 - Prob. 14.60APCh. 14 - Prob. 14.61APCh. 14 - Prob. 14.62APCh. 14 - Prob. 14.63APCh. 14 - Prob. 14.64APCh. 14 - Prob. 14.65APCh. 14 - Prob. 14.66APCh. 14 - Prob. 14.67APCh. 14 - Prob. 14.68APCh. 14 - Prob. 14.69APCh. 14 - Prob. 14.70APCh. 14 - Prob. 14.71APCh. 14 - Prob. 14.72APCh. 14 - Prob. 14.73CPCh. 14 - Prob. 14.74CP
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