IUPAC name for the given compound has to be chosen from the given options. Concept Introduction: IUPAC rules for naming thioalcohols that contain single thiol group: • Longest carbon chain has to be identified that contains thiol group also. The chain name is obtained by adding the suffix “-thiol”. If the compound contains an unsaturated bond, then the respective name has to be changed with regard to alkane . • The numbering has to be given so that the thiol group gets the least numbering. • Name and location of any other substituent present in the chain has to be identified. • If in a ring the thiol group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering. IUPAC rules for naming thioalcohols that contain more than one thiol group: • The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of thiol groups that is present.

Question

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

Answer 1

Question

Chapter 14.20, Problem 3QQ

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be chosen from the given options.

Concept Introduction:

IUPAC rules for naming thioalcohols that contain single thiol group:

• Longest carbon chain has to be identified that contains thiol group also. The chain name is obtained by adding the suffix “-thiol”. If the compound contains an unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the thiol group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the thiol group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

IUPAC rules for naming thioalcohols that contain more than one thiol group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of thiol groups that is present.

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