
(a)
Interpretation:
Structural formula for the simplest secondary alcohol with an acyclic R group has to be drawn.
Concept Introduction:
Alcohols are classified as primary, secondary, or tertiary depending upon the number of carbon atoms that is bonded to the carbon atom bearing hydroxyl group.
Primary alcohol is the one in which the carbon atom bearing the hydroxyl group is bonded to only one other carbon atom.
Secondary alcohol is the one in which the carbon atom bearing the hydroxyl group is bonded to two other carbon atoms.
Tertiary alcohol is the one in which the carbon atom bearing the hydroxyl group is bonded to three other carbon atoms.
Primary is denoted as
(b)
Interpretation:
Structural formula for the simplest tertiary alcohol with a cyclic R group has to be drawn.
Concept Introduction:
Alcohols are classified as primary, secondary, or tertiary depending upon the number of carbon atoms that is bonded to the carbon atom bearing hydroxyl group.
Primary alcohol is the one in which the carbon atom bearing the hydroxyl group is bonded to only one other carbon atom.
Secondary alcohol is the one in which the carbon atom bearing the hydroxyl group is bonded to two other carbon atoms.
Tertiary alcohol is the one in which the carbon atom bearing the hydroxyl group is bonded to three other carbon atoms.
Primary is denoted as

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Chapter 14 Solutions
General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card)
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- Draw the mechanism for the following Friedel-Craft reaction. AlBr3 Brarrow_forward(a) Draw the structures of A and B in the following reaction. (i) NaNH2, NH3(1) A + B (ii) H3O+arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Consider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Given the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardk₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forward
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