The given phenol has to be named. Concept Introduction: When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives. Phenol derivative with one substituent: IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible. Ortho- means disubstitution in 1,2 Meta- means disubstitution in 1,3 Para- means disubstitution in 1,4 In all the above derivatives of phenol, the first position is occupied by hydroxyl group. Phenol derivatives with two or more substituents: More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Question

For the condensation reaction between Alanine and histidine write the amididation reaction mechanism using arrows then write the three letter code for the product of the reaction and the one letter code for the product of the reaction.

Answer 1

Question

Chapter 14, Problem 14.76EP

(a)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(b)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(c)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(d)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

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For the condensation reaction between Alanine and histidine write the amididation reaction mechanism using arrows then write the three letter code for the product of the reaction and the one letter code for the product of the reaction.

Write the amididation reaction mechanism of p-aminophenol and acetic acid to produce acetaminophen please use arrows.

Name the following using IUPAC.

Answer 2

Question

Chapter 14, Problem 14.76EP

(a)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(b)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(c)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(d)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

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Answer 3

Question

Chapter 14, Problem 14.76EP

(a)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(b)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(c)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(d)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

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Answer 4

Question

Chapter 14, Problem 14.76EP

(a)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(b)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(c)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(d)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

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Answer 5

Chapter 14, Problem 14.76EP

(a)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(b)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(c)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(d)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 6

Chapter 14, Problem 14.76EP

(a)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 7

Chapter 14, Problem 14.76EP

(a)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given phenol has to be named.

Concept Introduction:

When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.

Phenol derivative with one substituent:

IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

In all the above derivatives of phenol, the first position is occupied by hydroxyl group.

Phenol derivatives with two or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Answer 14

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Answer 25

Ch. 14.1 - Prob. 1QQ Ch. 14.1 - Prob. 2QQ Ch. 14.2 - Prob. 1QQ Ch. 14.2 - Prob. 2QQ Ch. 14.2 - Prob. 3QQ Ch. 14.3 - Prob. 1QQ Ch. 14.3 - Prob. 2QQ Ch. 14.3 - Prob. 3QQ Ch. 14.3 - Prob. 4QQ Ch. 14.4 - Prob. 1QQ

Solution Summary: The author explains that when one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol.

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Chapter 14 Solutions