The product formed by the oxidation of cyclohexanol with potassium dichromate should be determined. Concept Introduction: The oxidation of primary alcohols with potassium dichromate, K 2 Cr 2 O 7 , results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid . Whereas the oxidation of secondary alcohols with potassium dichromate, K 2 Cr 2 O 7 , results in the formation of ketone of corresponding alcohol.

Question

PROBLEM 11-38 Develop syntheses for the following compounds. As starting materials, you may use cyclopentanol, alcohols containing no more than four carbon atoms, and any common reagents and solvents. (a) trans-cyclopentane-1,2-diol (b) 1-chloro-1-ethyleyclopentane f (c) OCH, CH₂ (e) OCH₂CH₂ C-CH₂CH₂ (1) OCH,

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 14.2, Problem 14.5P

Interpretation Introduction

Interpretation:

The product formed by the oxidation of cyclohexanol with potassium dichromate should be determined.

Concept Introduction:

The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

Interpretation Introduction

Interpretation:

The product formed by the oxidation of 2-pentanol with potassium dichromate should be determined.

Concept Introduction: The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

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PROBLEM 11-38 Develop syntheses for the following compounds. As starting materials, you may use cyclopentanol, alcohols containing no more than four carbon atoms, and any common reagents and solvents. (a) trans-cyclopentane-1,2-diol (b) 1-chloro-1-ethyleyclopentane f (c) OCH, CH₂ (e) OCH₂CH₂ C-CH₂CH₂ (1) OCH,

PROBLEM 10-14 Show two ways you could synthesize each of the following secondary alcohols by adding an appropriate Grignard reagent to an aldehyde. (b) (a) OH OH (c) H OH

a ,b ,c

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 14.2, Problem 14.5P

Interpretation Introduction

Interpretation:

The product formed by the oxidation of cyclohexanol with potassium dichromate should be determined.

Concept Introduction:

The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

Interpretation Introduction

Interpretation:

The product formed by the oxidation of 2-pentanol with potassium dichromate should be determined.

Concept Introduction: The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 14.2, Problem 14.5P

Interpretation Introduction

Interpretation:

The product formed by the oxidation of cyclohexanol with potassium dichromate should be determined.

Concept Introduction:

The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

Interpretation Introduction

Interpretation:

The product formed by the oxidation of 2-pentanol with potassium dichromate should be determined.

Concept Introduction: The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 14.2, Problem 14.5P

Interpretation Introduction