The balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined. Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

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Answer 1

Question

Chapter 14, Problem 22CI

(a)

Interpretation Introduction

Interpretation : The balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(b)

Interpretation Introduction

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.

(c)

Interpretation Introduction

Interpretation : The balanced combustion reaction of octane needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(d)

Interpretation Introduction

Interpretation : The number of moles of octane in given volume needs to be determined.

Concept Introduction : The relation between density and mass is shown as follows:

d=mV

For given density and volume, mass of the species can be calculated by rearranging the above equation:

m=d×V

The number of moles can be calculated from mass and molar mass as follows:

n=mM

Here, m is mass and M is molar mass.

(e)

Interpretation Introduction

Interpretation : The volume of carbon dioxide at STP from combustion of gasoline used in one year needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

At the standard temperature and pressure state, the volume of 1 mol of a substance is equal to 22.4 L. This is calculated by putting the standard temperature and pressure values in the ideal gas equation as follows:

PV=nRT

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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.

Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

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Answer 2

Question

Chapter 14, Problem 22CI

(a)

Interpretation Introduction

Interpretation : The balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(b)

Interpretation Introduction

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.

(c)

Interpretation Introduction

Interpretation : The balanced combustion reaction of octane needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(d)

Interpretation Introduction

Interpretation : The number of moles of octane in given volume needs to be determined.

Concept Introduction : The relation between density and mass is shown as follows:

d=mV

For given density and volume, mass of the species can be calculated by rearranging the above equation:

m=d×V

The number of moles can be calculated from mass and molar mass as follows:

n=mM

Here, m is mass and M is molar mass.

(e)

Interpretation Introduction

Interpretation : The volume of carbon dioxide at STP from combustion of gasoline used in one year needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

At the standard temperature and pressure state, the volume of 1 mol of a substance is equal to 22.4 L. This is calculated by putting the standard temperature and pressure values in the ideal gas equation as follows:

PV=nRT

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Answer 3

Question

Chapter 14, Problem 22CI

(a)

Interpretation Introduction

Interpretation : The balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(b)

Interpretation Introduction

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.

(c)

Interpretation Introduction

Interpretation : The balanced combustion reaction of octane needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(d)

Interpretation Introduction

Interpretation : The number of moles of octane in given volume needs to be determined.

Concept Introduction : The relation between density and mass is shown as follows:

d=mV

For given density and volume, mass of the species can be calculated by rearranging the above equation:

m=d×V

The number of moles can be calculated from mass and molar mass as follows:

n=mM

Here, m is mass and M is molar mass.

(e)

Interpretation Introduction

Interpretation : The volume of carbon dioxide at STP from combustion of gasoline used in one year needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

At the standard temperature and pressure state, the volume of 1 mol of a substance is equal to 22.4 L. This is calculated by putting the standard temperature and pressure values in the ideal gas equation as follows:

PV=nRT

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Answer 4

Question

Chapter 14, Problem 22CI

(a)

Interpretation Introduction

Interpretation : The balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(b)

Interpretation Introduction

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.

(c)

Interpretation Introduction

Interpretation : The balanced combustion reaction of octane needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(d)

Interpretation Introduction

Interpretation : The number of moles of octane in given volume needs to be determined.

Concept Introduction : The relation between density and mass is shown as follows:

d=mV

For given density and volume, mass of the species can be calculated by rearranging the above equation:

m=d×V

The number of moles can be calculated from mass and molar mass as follows:

n=mM

Here, m is mass and M is molar mass.

(e)

Interpretation Introduction

Interpretation : The volume of carbon dioxide at STP from combustion of gasoline used in one year needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

At the standard temperature and pressure state, the volume of 1 mol of a substance is equal to 22.4 L. This is calculated by putting the standard temperature and pressure values in the ideal gas equation as follows:

PV=nRT

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Check out a sample textbook solution

See solution

Answer 5

Chapter 14, Problem 22CI

(a)

Interpretation Introduction

Interpretation : The balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(b)

Interpretation Introduction

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.

(c)

Interpretation Introduction

Interpretation : The balanced combustion reaction of octane needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

(d)

Interpretation Introduction

Interpretation : The number of moles of octane in given volume needs to be determined.

Concept Introduction : The relation between density and mass is shown as follows:

d=mV

For given density and volume, mass of the species can be calculated by rearranging the above equation:

m=d×V

The number of moles can be calculated from mass and molar mass as follows:

n=mM

Here, m is mass and M is molar mass.

(e)

Interpretation Introduction

Interpretation : The volume of carbon dioxide at STP from combustion of gasoline used in one year needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

At the standard temperature and pressure state, the volume of 1 mol of a substance is equal to 22.4 L. This is calculated by putting the standard temperature and pressure values in the ideal gas equation as follows:

PV=nRT

Answer 6

Chapter 14, Problem 22CI

(a)

Interpretation Introduction

Interpretation : The balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

Answer 7

Chapter 14, Problem 22CI

(a)

Interpretation Introduction

Interpretation : The balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

Answer 8

(b)

Interpretation Introduction

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.

Answer 9

(b)

Interpretation Introduction

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.

Answer 10

(c)

Interpretation Introduction

Interpretation : The balanced combustion reaction of octane needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

Answer 11

(c)

Interpretation Introduction

Interpretation : The balanced combustion reaction of octane needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

Answer 12

(d)

Interpretation Introduction

Interpretation : The number of moles of octane in given volume needs to be determined.

Concept Introduction : The relation between density and mass is shown as follows:

d=mV

For given density and volume, mass of the species can be calculated by rearranging the above equation:

m=d×V

The number of moles can be calculated from mass and molar mass as follows:

n=mM

Here, m is mass and M is molar mass.

Answer 13

(d)

Interpretation Introduction

Interpretation : The number of moles of octane in given volume needs to be determined.

Concept Introduction : The relation between density and mass is shown as follows:

d=mV

For given density and volume, mass of the species can be calculated by rearranging the above equation:

m=d×V

The number of moles can be calculated from mass and molar mass as follows:

n=mM

Here, m is mass and M is molar mass.

Answer 14

(e)

Interpretation Introduction

Interpretation : The volume of carbon dioxide at STP from combustion of gasoline used in one year needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

At the standard temperature and pressure state, the volume of 1 mol of a substance is equal to 22.4 L. This is calculated by putting the standard temperature and pressure values in the ideal gas equation as follows:

PV=nRT

Answer 15

(e)

Interpretation Introduction

Interpretation : The volume of carbon dioxide at STP from combustion of gasoline used in one year needs to be determined.

Concept Introduction : The combustion reaction is an exothermic reaction which is the reaction of molecule with oxygen to form carbon dioxide and water. The energy released during the combustion is called as enthalpy of combustion.

At the standard temperature and pressure state, the volume of 1 mol of a substance is equal to 22.4 L. This is calculated by putting the standard temperature and pressure values in the ideal gas equation as follows:

PV=nRT

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 14.1 - Indicate whether each of the following statements...Ch. 14.1 - Prob. 2PP Ch. 14.1 - Prob. 3PP Ch. 14.1 - Prob. 4PP Ch. 14.1 - Write formulas for each of the following acids and...Ch. 14.1 - Write formulas for each of the following acids and...Ch. 14.2 - Identify the reactant that is a Brønsted-Lowry...Ch. 14.2 - Identify the reactant that is a Brønsted-Lowry...Ch. 14.2 - Write the formula for the conjugate base for each...Ch. 14.2 - Write the formula for the conjugate base for each...

Solution Summary: The author explains how the balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept explainers

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.

Want to see the full answer?

Chapter 14 Solutions

Solution Summary: The author explains how the balanced chemical reaction for the nitrogen oxide and nitrogen dioxide production needs to be determined.

Concept explainers

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined. Concept Introduction : From number of moles, mass of any species can be calculated as follows: m=n×M Here, n is number of moles and M is molar mass.

Want to see the full answer?

Chapter 14 Solutions

Interpretation : The mass of nitrogen dioxide produced by one automobile in 1 year needs to be determined.

Concept Introduction : From number of moles, mass of any species can be calculated as follows:

m=n×M

Here, n is number of moles and M is molar mass.