Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
expand_more
expand_more
format_list_bulleted
Question
Chapter 14.9, Problem 85PP
Interpretation Introduction
Interpretation:
The mass in grams of CaCO3 required to neutralize HCl should be determined.
Concept Introduction:
The relationship between moles, mass and molar mass of a substance is:
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
[Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V
(4 points)
Chapter 14 Solutions
Basic Chemistry
Ch. 14.1 - Indicate whether each of the following statements...Ch. 14.1 - Prob. 2PPCh. 14.1 - Prob. 3PPCh. 14.1 - Prob. 4PPCh. 14.1 - Write formulas for each of the following acids and...Ch. 14.1 - Write formulas for each of the following acids and...Ch. 14.2 - Identify the reactant that is a Brønsted-Lowry...Ch. 14.2 - Identify the reactant that is a Brønsted-Lowry...Ch. 14.2 - Write the formula for the conjugate base for each...Ch. 14.2 - Write the formula for the conjugate base for each...
Ch. 14.2 - Write the formula for the conjugate acid for each...Ch. 14.2 - Prob. 12PPCh. 14.2 - Prob. 13PPCh. 14.2 - Prob. 14PPCh. 14.2 - When ammonium chloride dissolves in water, the...Ch. 14.2 - Prob. 16PPCh. 14.3 - What is meant by the phrase "A strong acid has a...Ch. 14.3 - Prob. 18PPCh. 14.3 - Prob. 19PPCh. 14.3 - Prob. 20PPCh. 14.3 - Prob. 21PPCh. 14.3 - Prob. 22PPCh. 14.3 - Prob. 23PPCh. 14.3 - Prob. 24PPCh. 14.3 - Prob. 25PPCh. 14.3 - Write an equation for the acid-base reaction...Ch. 14.4 - Answer True or False for each of the following: A...Ch. 14.4 - Answer True or False for each of the following: A...Ch. 14.4 - Consider the following acids and their...Ch. 14.4 - Prob. 30PPCh. 14.4 - Phosphoric acid dissociates to form hydronium ion...Ch. 14.4 - Prob. 32PPCh. 14.5 - Why are the concentrations of H3O+ and OH equal in...Ch. 14.5 - Prob. 34PPCh. 14.5 - Prob. 35PPCh. 14.5 - Prob. 36PPCh. 14.5 - Indicate whether each of the following solutions...Ch. 14.5 - Indicate whether each of the following solutions...Ch. 14.5 - Calculate the [H3O+] of each aqueous solution with...Ch. 14.5 - Prob. 40PPCh. 14.5 - Calculate the [OH] of each aqueous solution with...Ch. 14.5 - Prob. 42PPCh. 14.6 - Prob. 43PPCh. 14.6 - Prob. 44PPCh. 14.6 - State whether each of the following solutions is...Ch. 14.6 - State whether each of the following solutions is...Ch. 14.6 - A solution with a pH of 3 is 10 times more acidic...Ch. 14.6 - A solution with a pH of 10 is 100 times more basic...Ch. 14.6 - Calculate the pH of each solution given the...Ch. 14.6 - Calculate the pOH of each solution given the...Ch. 14.6 - Prob. 51PPCh. 14.6 - Complete the following table:Ch. 14.6 - A patient with severe metabolic acidosis has a...Ch. 14.6 - A patient with respiratory alkalosis has a blood...Ch. 14.7 - Prob. 55PPCh. 14.7 - Prob. 56PPCh. 14.7 - Balance each of the following neutralization...Ch. 14.7 - Balance each of the following neutralization...Ch. 14.7 - Write a balanced equation for the neutralization...Ch. 14.7 - Prob. 60PPCh. 14.8 - If you need to determine the molarity of a formic...Ch. 14.8 - If you need to determine the molarity of an acetic...Ch. 14.8 - Prob. 63PPCh. 14.8 - What is the molarity of an acetic acid solution if...Ch. 14.8 - Prob. 65PPCh. 14.8 - A solution of 0.162MNaOH is used to titrate 25.0mL...Ch. 14.8 - A solution of 0.204MNaOH is used to titrate 50.0mL...Ch. 14.8 - A solution of 0.312 M KOH is used to titrate...Ch. 14.9 - Which of the following make a buffer system when...Ch. 14.9 - Prob. 70PPCh. 14.9 - Consider the buffer system of hydrofluoric acid,...Ch. 14.9 - Consider the buffer system of nitrous acid, HNO2 ,...Ch. 14.9 - Nitrous acid has a Ka of 4.5104 . What is the pH...Ch. 14.9 - Prob. 74PPCh. 14.9 - Using Table 14.4 for Ka values, compare the pH of...Ch. 14.9 - Using Table 14.4 for Ka values, compare the pH of...Ch. 14.9 - Someone with kidney failure excretes urine with...Ch. 14.9 - Someone with severe diabetes obtains energy by the...Ch. 14.9 - Prob. 79PPCh. 14.9 - Prob. 80PPCh. 14.9 - Prob. 81PPCh. 14.9 - After Larry had taken Nexium for 4 weeks, the pH...Ch. 14.9 - Prob. 83PPCh. 14.9 - Prob. 84PPCh. 14.9 - Prob. 85PPCh. 14.9 - Prob. 86PPCh. 14 - The chapter sections to review are shown in...Ch. 14 - Prob. 88UTCCh. 14 - Prob. 89UTCCh. 14 - Prob. 90UTCCh. 14 - Prob. 91UTCCh. 14 - Prob. 92UTCCh. 14 - Prob. 93UTCCh. 14 - Prob. 94UTCCh. 14 - Prob. 95UTCCh. 14 - Prob. 96UTCCh. 14 - The chapter sections to review are shown in...Ch. 14 - Prob. 98APPCh. 14 - Prob. 99APPCh. 14 - Prob. 100APPCh. 14 - Prob. 101APPCh. 14 - The chapter sections to review are shown in...Ch. 14 - Prob. 103APPCh. 14 - Prob. 104APPCh. 14 - Prob. 105APPCh. 14 - Prob. 106APPCh. 14 - Prob. 107APPCh. 14 - Prob. 108APPCh. 14 - Prob. 109APPCh. 14 - Prob. 110APPCh. 14 - Prob. 111APPCh. 14 - Prob. 112APPCh. 14 - Prob. 113APPCh. 14 - Prob. 114APPCh. 14 - Prob. 115CPCh. 14 - Prob. 116CPCh. 14 - Prob. 117CPCh. 14 - Prob. 118CPCh. 14 - Prob. 119CPCh. 14 - Prob. 120CPCh. 14 - Prob. 121CPCh. 14 - The following problems are related to the topics...Ch. 14 - Prob. 123CPCh. 14 - Prob. 124CPCh. 14 - Prob. 125CPCh. 14 - Prob. 126CPCh. 14 - Prob. 127CPCh. 14 - Prob. 128CPCh. 14 - Prob. 129CPCh. 14 - Prob. 130CPCh. 14 - Prob. 21CICh. 14 - Prob. 22CICh. 14 - Prob. 23CiCh. 14 - Prob. 24CiCh. 14 - Prob. 25CICh. 14 - Prob. 26CICh. 14 - Prob. 27CICh. 14 - Prob. 28CiCh. 14 - Prob. 29CICh. 14 - Prob. 30CICh. 14 - Prob. 31CICh. 14 - In the kidneys, the ammonia buffer system buffers...
Knowledge Booster
Similar questions
- 5. Consider the compounds shown below as ligands in coordination chemistry and identify their denticity; comment on their ability to form chelate complexes. (6 points) N N A B N N N IN N Carrow_forward1. Use standard reduction potentials to rationalize quantitatively why: (6 points) (a) Al liberates H2 from dilute HCl, but Ag does not; (b) Cl2 liberates Br2 from aqueous KBr solution, but does not liberate C12 from aqueous KCl solution; c) a method of growing Ag crystals is to immerse a zinc foil in an aqueous solution of AgNO3.arrow_forwardWhat would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 3 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure. Xarrow_forward
- What is the missing reactant R in this organic reaction? N N H3O+ +R + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure. fmarrow_forwardThe product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH3CN H+ N Click and drag to start drawing a structure. 5arrow_forwardAssign this HSQC Spectrum ( please editing clearly on the image)arrow_forward
- (a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³arrow_forwardfcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transferarrow_forward34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10arrow_forward
- elow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forwardPredict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co