Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Textbook Question
Chapter 14.7, Problem 57PP
Balance each of the following neutralization reactions:
a.
b.
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C
This question shows how molecular orbital (MO) theory can be used to understand the chemical
properties of elemental oxygen O₂ and its anionic derivative superoxide Oz.
a)
Draw the MO energy diagram for both O2 and O2. Clearly label your diagram with atomic orbital names
and molecular orbital symmetry labels and include electrons.
Draw the Lewis structure of O2. How does the MO description of O2 differ from the Lewis structure, and
how does this difference relate to the high reactivity and magnetic properties of oxygen?
) Use the MO diagram in (a) to explain the difference in bond length and bond energy between superoxide
ion (Oz, 135 pm, 360 kJ/mol) and oxygen (O2, 120.8 pm, 494 kJ/mol).
Please draw
-Page: 8
nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]".
What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry
of [Co(H2O)]?
b)
Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron
configurations of [Co(H2O)]:
Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance
or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of
[Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1
kJ/mol)
Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange
an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low
in configuration vs in the high spin configuration? What can you say about the importance of exchange energy
07
Chapter 14 Solutions
Basic Chemistry
Ch. 14.1 - Indicate whether each of the following statements...Ch. 14.1 - Prob. 2PPCh. 14.1 - Prob. 3PPCh. 14.1 - Prob. 4PPCh. 14.1 - Write formulas for each of the following acids and...Ch. 14.1 - Write formulas for each of the following acids and...Ch. 14.2 - Identify the reactant that is a Brønsted-Lowry...Ch. 14.2 - Identify the reactant that is a Brønsted-Lowry...Ch. 14.2 - Write the formula for the conjugate base for each...Ch. 14.2 - Write the formula for the conjugate base for each...
Ch. 14.2 - Write the formula for the conjugate acid for each...Ch. 14.2 - Prob. 12PPCh. 14.2 - Prob. 13PPCh. 14.2 - Prob. 14PPCh. 14.2 - When ammonium chloride dissolves in water, the...Ch. 14.2 - Prob. 16PPCh. 14.3 - What is meant by the phrase "A strong acid has a...Ch. 14.3 - Prob. 18PPCh. 14.3 - Prob. 19PPCh. 14.3 - Prob. 20PPCh. 14.3 - Prob. 21PPCh. 14.3 - Prob. 22PPCh. 14.3 - Prob. 23PPCh. 14.3 - Prob. 24PPCh. 14.3 - Prob. 25PPCh. 14.3 - Write an equation for the acid-base reaction...Ch. 14.4 - Answer True or False for each of the following: A...Ch. 14.4 - Answer True or False for each of the following: A...Ch. 14.4 - Consider the following acids and their...Ch. 14.4 - Prob. 30PPCh. 14.4 - Phosphoric acid dissociates to form hydronium ion...Ch. 14.4 - Prob. 32PPCh. 14.5 - Why are the concentrations of H3O+ and OH equal in...Ch. 14.5 - Prob. 34PPCh. 14.5 - Prob. 35PPCh. 14.5 - Prob. 36PPCh. 14.5 - Indicate whether each of the following solutions...Ch. 14.5 - Indicate whether each of the following solutions...Ch. 14.5 - Calculate the [H3O+] of each aqueous solution with...Ch. 14.5 - Prob. 40PPCh. 14.5 - Calculate the [OH] of each aqueous solution with...Ch. 14.5 - Prob. 42PPCh. 14.6 - Prob. 43PPCh. 14.6 - Prob. 44PPCh. 14.6 - State whether each of the following solutions is...Ch. 14.6 - State whether each of the following solutions is...Ch. 14.6 - A solution with a pH of 3 is 10 times more acidic...Ch. 14.6 - A solution with a pH of 10 is 100 times more basic...Ch. 14.6 - Calculate the pH of each solution given the...Ch. 14.6 - Calculate the pOH of each solution given the...Ch. 14.6 - Prob. 51PPCh. 14.6 - Complete the following table:Ch. 14.6 - A patient with severe metabolic acidosis has a...Ch. 14.6 - A patient with respiratory alkalosis has a blood...Ch. 14.7 - Prob. 55PPCh. 14.7 - Prob. 56PPCh. 14.7 - Balance each of the following neutralization...Ch. 14.7 - Balance each of the following neutralization...Ch. 14.7 - Write a balanced equation for the neutralization...Ch. 14.7 - Prob. 60PPCh. 14.8 - If you need to determine the molarity of a formic...Ch. 14.8 - If you need to determine the molarity of an acetic...Ch. 14.8 - Prob. 63PPCh. 14.8 - What is the molarity of an acetic acid solution if...Ch. 14.8 - Prob. 65PPCh. 14.8 - A solution of 0.162MNaOH is used to titrate 25.0mL...Ch. 14.8 - A solution of 0.204MNaOH is used to titrate 50.0mL...Ch. 14.8 - A solution of 0.312 M KOH is used to titrate...Ch. 14.9 - Which of the following make a buffer system when...Ch. 14.9 - Prob. 70PPCh. 14.9 - Consider the buffer system of hydrofluoric acid,...Ch. 14.9 - Consider the buffer system of nitrous acid, HNO2 ,...Ch. 14.9 - Nitrous acid has a Ka of 4.5104 . What is the pH...Ch. 14.9 - Prob. 74PPCh. 14.9 - Using Table 14.4 for Ka values, compare the pH of...Ch. 14.9 - Using Table 14.4 for Ka values, compare the pH of...Ch. 14.9 - Someone with kidney failure excretes urine with...Ch. 14.9 - Someone with severe diabetes obtains energy by the...Ch. 14.9 - Prob. 79PPCh. 14.9 - Prob. 80PPCh. 14.9 - Prob. 81PPCh. 14.9 - After Larry had taken Nexium for 4 weeks, the pH...Ch. 14.9 - Prob. 83PPCh. 14.9 - Prob. 84PPCh. 14.9 - Prob. 85PPCh. 14.9 - Prob. 86PPCh. 14 - The chapter sections to review are shown in...Ch. 14 - Prob. 88UTCCh. 14 - Prob. 89UTCCh. 14 - Prob. 90UTCCh. 14 - Prob. 91UTCCh. 14 - Prob. 92UTCCh. 14 - Prob. 93UTCCh. 14 - Prob. 94UTCCh. 14 - Prob. 95UTCCh. 14 - Prob. 96UTCCh. 14 - The chapter sections to review are shown in...Ch. 14 - Prob. 98APPCh. 14 - Prob. 99APPCh. 14 - Prob. 100APPCh. 14 - Prob. 101APPCh. 14 - The chapter sections to review are shown in...Ch. 14 - Prob. 103APPCh. 14 - Prob. 104APPCh. 14 - Prob. 105APPCh. 14 - Prob. 106APPCh. 14 - Prob. 107APPCh. 14 - Prob. 108APPCh. 14 - Prob. 109APPCh. 14 - Prob. 110APPCh. 14 - Prob. 111APPCh. 14 - Prob. 112APPCh. 14 - Prob. 113APPCh. 14 - Prob. 114APPCh. 14 - Prob. 115CPCh. 14 - Prob. 116CPCh. 14 - Prob. 117CPCh. 14 - Prob. 118CPCh. 14 - Prob. 119CPCh. 14 - Prob. 120CPCh. 14 - Prob. 121CPCh. 14 - The following problems are related to the topics...Ch. 14 - Prob. 123CPCh. 14 - Prob. 124CPCh. 14 - Prob. 125CPCh. 14 - Prob. 126CPCh. 14 - Prob. 127CPCh. 14 - Prob. 128CPCh. 14 - Prob. 129CPCh. 14 - Prob. 130CPCh. 14 - Prob. 21CICh. 14 - Prob. 22CICh. 14 - Prob. 23CiCh. 14 - Prob. 24CiCh. 14 - Prob. 25CICh. 14 - Prob. 26CICh. 14 - Prob. 27CICh. 14 - Prob. 28CiCh. 14 - Prob. 29CICh. 14 - Prob. 30CICh. 14 - Prob. 31CICh. 14 - In the kidneys, the ammonia buffer system buffers...
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