The IUPAC name for the given alcohol has to be assigned. Concept Introduction: IUPAC rules for naming alcohols that contain single hydroxyl group: Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. The numbering has to be given so that the hydroxyl group gets the least numbering. Name and location of any other substituent present in the chain has to be identified. If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering. Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group. IUPAC rules for naming alcohols that contain more than one hydroxyl group: The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Question

a) What does Wilkins's letter, (pages 2-4) add to this picture? b) What does Franklin and Gosling’s letter (pages 4-5) add to the picture? c) Why couldn’t Watson & Crick credibly publish without the inclusion of the other two letters?

Answer 1

Question

Chapter 14, Problem 14.7EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

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Answer 2

Question

Chapter 14, Problem 14.7EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

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Answer 3

Question

Chapter 14, Problem 14.7EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

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Answer 4

Question

Chapter 14, Problem 14.7EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

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Answer 5

Chapter 14, Problem 14.7EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 6

Chapter 14, Problem 14.7EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 7

Chapter 14, Problem 14.7EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the given alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 14

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Answer 25

Ch. 14.1 - Prob. 1QQ Ch. 14.1 - Prob. 2QQ Ch. 14.2 - Prob. 1QQ Ch. 14.2 - Prob. 2QQ Ch. 14.2 - Prob. 3QQ Ch. 14.3 - Prob. 1QQ Ch. 14.3 - Prob. 2QQ Ch. 14.3 - Prob. 3QQ Ch. 14.3 - Prob. 4QQ Ch. 14.4 - Prob. 1QQ

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Chapter 14 Solutions