The member that is expected to be more soluble among the given pair has to be identified. Concept Introduction: Alcohol is an organic compound that has hydroxyl as its functional group . Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Answer 1

Question

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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synthesize 1-propyne starting with propane.

starting reactant IV target + enantiomer 1) BH3, THF 2) H₂O2, NaOH, H₂O 1) Hg(OAc)2, THF, H₂O (or ROH) 2) NaBH4 D2, Pt/C H₂, Pt/C D2, Lindlar catalyst or Ni₂B H₂, Lindlar catalyst or Ni₂B NaNH, OH/H₂O or SH/H₂S H₂O/H₂O 1) 03 2) H₂O 1) 03 2) (CH3)2S HBr, w/ROOR HBr, (cold, dark, no ROOR) Naº, NH3(e) NBS (trace Br2), light HgSO4, H2SO4, H₂O Naº, ROH 1) Sia₂BH, THF 2) H2O2, NaOH, H₂O H3O/ROH or H₂O*/RSH OR/ROH or SR/RSH 1) OsO4, NMO 2) NaHSO3, H₂O 1) MCPBA (peroxy acid) 2) H3O, H2O (or ROH or RSH) KMnO4 (warm, concentrated) Br₂/H₂O Br₂, heat or light Br2, cold, dark, no peroxides (CH3)3CO(CH3)3COH ROH or RSH H₂O KMnO4/OH (cold, dilute)

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Answer 2

Question

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Answer 3

Question

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Answer 4

Question

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Answer 5

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 6

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 7

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.1 - Prob. 1QQ Ch. 14.1 - Prob. 2QQ Ch. 14.2 - Prob. 1QQ Ch. 14.2 - Prob. 2QQ Ch. 14.2 - Prob. 3QQ Ch. 14.3 - Prob. 1QQ Ch. 14.3 - Prob. 2QQ Ch. 14.3 - Prob. 3QQ Ch. 14.3 - Prob. 4QQ Ch. 14.4 - Prob. 1QQ

Solution Summary: The author explains that alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it.

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Chapter 14 Solutions