Common name for the thiol that is given has to be assigned. Concept Introduction: Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Question

starting reactant IV target + enantiomer 1) BH3, THF 2) H₂O2, NaOH, H₂O 1) Hg(OAc)2, THF, H₂O (or ROH) 2) NaBH4 D2, Pt/C H₂, Pt/C D2, Lindlar catalyst or Ni₂B H₂, Lindlar catalyst or Ni₂B NaNH, OH/H₂O or SH/H₂S H₂O/H₂O 1) 03 2) H₂O 1) 03 2) (CH3)2S HBr, w/ROOR HBr, (cold, dark, no ROOR) Naº, NH3(e) NBS (trace Br2), light HgSO4, H2SO4, H₂O Naº, ROH 1) Sia₂BH, THF 2) H2O2, NaOH, H₂O H3O/ROH or H₂O*/RSH OR/ROH or SR/RSH 1) OsO4, NMO 2) NaHSO3, H₂O 1) MCPBA (peroxy acid) 2) H3O, H2O (or ROH or RSH) KMnO4 (warm, concentrated) Br₂/H₂O Br₂, heat or light Br2, cold, dark, no peroxides (CH3)3CO(CH3)3COH ROH or RSH H₂O KMnO4/OH (cold, dilute)

Answer 1

Question

Chapter 14, Problem 14.133EP

(a)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(b)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(c)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(d)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

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starting reactant IV target + enantiomer 1) BH3, THF 2) H₂O2, NaOH, H₂O 1) Hg(OAc)2, THF, H₂O (or ROH) 2) NaBH4 D2, Pt/C H₂, Pt/C D2, Lindlar catalyst or Ni₂B H₂, Lindlar catalyst or Ni₂B NaNH, OH/H₂O or SH/H₂S H₂O/H₂O 1) 03 2) H₂O 1) 03 2) (CH3)2S HBr, w/ROOR HBr, (cold, dark, no ROOR) Naº, NH3(e) NBS (trace Br2), light HgSO4, H2SO4, H₂O Naº, ROH 1) Sia₂BH, THF 2) H2O2, NaOH, H₂O H3O/ROH or H₂O*/RSH OR/ROH or SR/RSH 1) OsO4, NMO 2) NaHSO3, H₂O 1) MCPBA (peroxy acid) 2) H3O, H2O (or ROH or RSH) KMnO4 (warm, concentrated) Br₂/H₂O Br₂, heat or light Br2, cold, dark, no peroxides (CH3)3CO(CH3)3COH ROH or RSH H₂O KMnO4/OH (cold, dilute)

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Indicate whether the ability of atoms to associate with each other depends on electron affinity.

Answer 2

Question

Chapter 14, Problem 14.133EP

(a)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(b)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(c)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(d)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

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Answer 3

Question

Chapter 14, Problem 14.133EP

(a)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(b)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(c)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(d)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

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Answer 4

Question

Chapter 14, Problem 14.133EP

(a)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(b)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(c)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(d)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

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Answer 5

Chapter 14, Problem 14.133EP

(a)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(b)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(c)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

(d)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 6

Chapter 14, Problem 14.133EP

(a)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 7

Chapter 14, Problem 14.133EP

(a)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Common name for the thiol that is given has to be assigned.

Concept Introduction:

Common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used as a suffix. This is the older name for thiols. The name of the alkyl group is given that is followed by the word mercaptan with a space between the two words.

Answer 14

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Answer 25

Ch. 14.1 - Prob. 1QQ Ch. 14.1 - Prob. 2QQ Ch. 14.2 - Prob. 1QQ Ch. 14.2 - Prob. 2QQ Ch. 14.2 - Prob. 3QQ Ch. 14.3 - Prob. 1QQ Ch. 14.3 - Prob. 2QQ Ch. 14.3 - Prob. 3QQ Ch. 14.3 - Prob. 4QQ Ch. 14.4 - Prob. 1QQ

Solution Summary: The author explains that common names are not IUPAC names. For giving a common name for thiol, the term mercaptan is used.

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