The IUPAC name for the alcohol has to be assigned. Concept Introduction: IUPAC rules for naming alcohols that contain single hydroxyl group: • Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane. • The numbering has to be given so that the hydroxyl group gets the least numbering. • Name and location of any other substituent present in the chain has to be identified. • If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering. • Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group. • If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer. • In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer. IUPAC rules for naming alcohols that contain more than one hydroxyl group: • The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Question

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Answer 1

Question

Chapter 14, Problem 14.28EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(a)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 1

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on opposite side of the double bond and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 2

Conclusion

IUPAC name for the given alcohol is trans-2-penten-1-ol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 3

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom and the double bond between second and third carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on same side of the double bond and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 4

Conclusion

IUPAC name for the given alcohol is cis-2-penten-1-ol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-methylcyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 5

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a methyl group is present in the second position. Therefore, the name of the given alcohol can be given as 2-methylcyclohexanol.

Looking for the stereochemistry, the given structure has substituents on above and below the ring of carbon atoms and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-methylcyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 6

Conclusion

IUPAC name for the given alcohol is trans-2-methylcyclohexanol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-3-bromocyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 7

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a bromo is present in the third position. Therefore, the name of the given alcohol can be given as 3-bromocyclohexanol.

Looking for the stereochemistry, the given structure has substituents on same side the ring of carbon atoms and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-3-bromocyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 8

Conclusion

IUPAC name for the given alcohol is cis-3-bromocyclohexanol.

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Answer 2

Question

Chapter 14, Problem 14.28EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(a)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 1

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on opposite side of the double bond and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 2

Conclusion

IUPAC name for the given alcohol is trans-2-penten-1-ol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 3

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom and the double bond between second and third carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on same side of the double bond and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 4

Conclusion

IUPAC name for the given alcohol is cis-2-penten-1-ol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-methylcyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 5

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a methyl group is present in the second position. Therefore, the name of the given alcohol can be given as 2-methylcyclohexanol.

Looking for the stereochemistry, the given structure has substituents on above and below the ring of carbon atoms and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-methylcyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 6

Conclusion

IUPAC name for the given alcohol is trans-2-methylcyclohexanol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-3-bromocyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 7

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a bromo is present in the third position. Therefore, the name of the given alcohol can be given as 3-bromocyclohexanol.

Looking for the stereochemistry, the given structure has substituents on same side the ring of carbon atoms and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-3-bromocyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 8

Conclusion

IUPAC name for the given alcohol is cis-3-bromocyclohexanol.

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Answer 3

Question

Chapter 14, Problem 14.28EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(a)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 1

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on opposite side of the double bond and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 2

Conclusion

IUPAC name for the given alcohol is trans-2-penten-1-ol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 3

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom and the double bond between second and third carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on same side of the double bond and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 4

Conclusion

IUPAC name for the given alcohol is cis-2-penten-1-ol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-methylcyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 5

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a methyl group is present in the second position. Therefore, the name of the given alcohol can be given as 2-methylcyclohexanol.

Looking for the stereochemistry, the given structure has substituents on above and below the ring of carbon atoms and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-methylcyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 6

Conclusion

IUPAC name for the given alcohol is trans-2-methylcyclohexanol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-3-bromocyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 7

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a bromo is present in the third position. Therefore, the name of the given alcohol can be given as 3-bromocyclohexanol.

Looking for the stereochemistry, the given structure has substituents on same side the ring of carbon atoms and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-3-bromocyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 8

Conclusion

IUPAC name for the given alcohol is cis-3-bromocyclohexanol.

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Answer 4

Question

Chapter 14, Problem 14.28EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(a)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 1

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on opposite side of the double bond and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 2

Conclusion

IUPAC name for the given alcohol is trans-2-penten-1-ol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 3

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom and the double bond between second and third carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on same side of the double bond and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 4

Conclusion

IUPAC name for the given alcohol is cis-2-penten-1-ol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-methylcyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 5

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a methyl group is present in the second position. Therefore, the name of the given alcohol can be given as 2-methylcyclohexanol.

Looking for the stereochemistry, the given structure has substituents on above and below the ring of carbon atoms and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-methylcyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 6

Conclusion

IUPAC name for the given alcohol is trans-2-methylcyclohexanol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-3-bromocyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 7

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a bromo is present in the third position. Therefore, the name of the given alcohol can be given as 3-bromocyclohexanol.

Looking for the stereochemistry, the given structure has substituents on same side the ring of carbon atoms and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-3-bromocyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 8

Conclusion

IUPAC name for the given alcohol is cis-3-bromocyclohexanol.

Want to see more full solutions like this?

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Answer 5

Chapter 14, Problem 14.28EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(a)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 1

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on opposite side of the double bond and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 2

Conclusion

IUPAC name for the given alcohol is trans-2-penten-1-ol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 3

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom and the double bond between second and third carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on same side of the double bond and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 4

Conclusion

IUPAC name for the given alcohol is cis-2-penten-1-ol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-methylcyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 5

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a methyl group is present in the second position. Therefore, the name of the given alcohol can be given as 2-methylcyclohexanol.

Looking for the stereochemistry, the given structure has substituents on above and below the ring of carbon atoms and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-methylcyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 6

Conclusion

IUPAC name for the given alcohol is trans-2-methylcyclohexanol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-3-bromocyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 7

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a bromo is present in the third position. Therefore, the name of the given alcohol can be given as 3-bromocyclohexanol.

Looking for the stereochemistry, the given structure has substituents on same side the ring of carbon atoms and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-3-bromocyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 8

Conclusion

IUPAC name for the given alcohol is cis-3-bromocyclohexanol.

Answer 6

Chapter 14, Problem 14.28EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(a)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 1

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on opposite side of the double bond and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 2

Conclusion

IUPAC name for the given alcohol is trans-2-penten-1-ol.

Answer 7

Chapter 14, Problem 14.28EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 8

(a)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-penten-1-ol.

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 1

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on opposite side of the double bond and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 2

Answer 13

Conclusion

IUPAC name for the given alcohol is trans-2-penten-1-ol.

Answer 14

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(b)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-2-penten-1-ol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 3

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom and the double bond between second and third carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on same side of the double bond and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 4

Conclusion

IUPAC name for the given alcohol is cis-2-penten-1-ol.

Answer 15

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 16

(b)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-2-penten-1-ol.

Answer 17

(b)

Expert Solution

Answer 18

(b)

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 3

The longest carbon chain in the above structure with the hydroxyl group is found to be a five carbon chain. Hence, the parent alkane is pentane. As there is a double bond present in the carbon chain, the name is converted as pentene. The hydroxyl group is found to be present on first carbon atom and the double bond between second and third carbon atom. Therefore, the name of the given alcohol can be given as 2-penten-1-ol.

Looking for the stereochemistry, the given structure has bulky group on same side of the double bond and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-2-penten-1-ol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 4

Answer 21

Conclusion

IUPAC name for the given alcohol is cis-2-penten-1-ol.

Answer 22

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(c)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-methylcyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 5

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a methyl group is present in the second position. Therefore, the name of the given alcohol can be given as 2-methylcyclohexanol.

Looking for the stereochemistry, the given structure has substituents on above and below the ring of carbon atoms and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-methylcyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 6

Conclusion

IUPAC name for the given alcohol is trans-2-methylcyclohexanol.

Answer 23

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 24

(c)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is trans-2-methylcyclohexanol.

Answer 25

(c)

Expert Solution

Answer 26

(c)

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 5

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a methyl group is present in the second position. Therefore, the name of the given alcohol can be given as 2-methylcyclohexanol.

Looking for the stereochemistry, the given structure has substituents on above and below the ring of carbon atoms and hence this is a trans isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is trans-2-methylcyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 6

Answer 29

Conclusion

IUPAC name for the given alcohol is trans-2-methylcyclohexanol.

Answer 30

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

(d)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-3-bromocyclohexanol.

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 7

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a bromo is present in the third position. Therefore, the name of the given alcohol can be given as 3-bromocyclohexanol.

Looking for the stereochemistry, the given structure has substituents on same side the ring of carbon atoms and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-3-bromocyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 8

Conclusion

IUPAC name for the given alcohol is cis-3-bromocyclohexanol.

Answer 31

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the alcohol has to be assigned.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

• Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. If the compound contains a unsaturated bond, then the respective name has to be changed with regard to alkane.

• The numbering has to be given so that the hydroxyl group gets the least numbering.

• Name and location of any other substituent present in the chain has to be identified.

• If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

• Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

• If the compound contains bulky groups on same side of the double bond, then it is a cis isomer and if the bulkyl groups are present on opposite side of the double bond, then it is a trans isomer.

• In case of cycloalkane compounds, if the substitutions are present on same side of the ring of carbon atoms, it is a cis isomer. If the substitutions are present above and below the ring, then it is a trans isomer.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

• The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Answer 32

(d)

Expert Solution

Answer to Problem 14.28EP

The IUPAC name of the given alcohol is cis-3-bromocyclohexanol.

Answer 33

(d)

Expert Solution

Answer 34

(d)

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

Given structure of alcohol is,

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 7

The longest carbon chain in the above structure with the hydroxyl group is found to be a six carbon cyclic chain. Hence, the parent cycloalkane is cyclohexane. As a hydroxyl group is present in the ring, the name can be given as cyclohexanol. Looking for the substituents present in the ring, it is found that a bromo is present in the third position. Therefore, the name of the given alcohol can be given as 3-bromocyclohexanol.

Looking for the stereochemistry, the given structure has substituents on same side the ring of carbon atoms and hence this is a cis isomer. This has to be included in the IUPAC name. Therefore, IUPAC name of the given compound is cis-3-bromocyclohexanol.

Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th, Chapter 14, Problem 14.28EP , additional homework tip 8