(a) Interpretation: The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated. Concept introduction: The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons . Unsaturated hydrocarbon compound are of two types alkenes and alkynes . The alkene contains a double bond between two carbon atoms. The alkynes contain a triple bond between two carbon atoms and follow general formula C n H 2 n - 2 . The name of the alkyne compounds ends with a suffix − y n e .

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Answer 1

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 14, Problem 14.39AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contain a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with a suffix −yne.

Interpretation Introduction

(b)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of ethynylmagnesium bromide and ethylmagnesium bromide and its mechanism are to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Interpretation Introduction

(c)

Interpretation:

The reason as to why is it important for the side product to be soluble to minimize both side reactions discussed in part (a) and (b) is to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

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Answer 2

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 14, Problem 14.39AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contain a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with a suffix −yne.

Interpretation Introduction

(b)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of ethynylmagnesium bromide and ethylmagnesium bromide and its mechanism are to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Interpretation Introduction

(c)

Interpretation:

The reason as to why is it important for the side product to be soluble to minimize both side reactions discussed in part (a) and (b) is to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

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Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 14, Problem 14.39AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contain a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with a suffix −yne.

Interpretation Introduction

(b)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of ethynylmagnesium bromide and ethylmagnesium bromide and its mechanism are to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Interpretation Introduction

(c)

Interpretation:

The reason as to why is it important for the side product to be soluble to minimize both side reactions discussed in part (a) and (b) is to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 14, Problem 14.39AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contain a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with a suffix −yne.

Interpretation Introduction

(b)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of ethynylmagnesium bromide and ethylmagnesium bromide and its mechanism are to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Interpretation Introduction

(c)

Interpretation:

The reason as to why is it important for the side product to be soluble to minimize both side reactions discussed in part (a) and (b) is to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

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Answer 5

Chapter 14, Problem 14.39AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contain a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with a suffix −yne.

Interpretation Introduction

(b)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of ethynylmagnesium bromide and ethylmagnesium bromide and its mechanism are to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Interpretation Introduction

(c)

Interpretation:

The reason as to why is it important for the side product to be soluble to minimize both side reactions discussed in part (a) and (b) is to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Answer 6

Chapter 14, Problem 14.39AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contain a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with a suffix −yne.

Answer 7

Chapter 14, Problem 14.39AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contain a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with a suffix −yne.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of ethynylmagnesium bromide and ethylmagnesium bromide and its mechanism are to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason as to why excess of acetylene is avoided in reaction of ethynylmagnesium bromide and ethylmagnesium bromide and its mechanism are to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why is it important for the side product to be soluble to minimize both side reactions discussed in part (a) and (b) is to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why is it important for the side product to be soluble to minimize both side reactions discussed in part (a) and (b) is to be stated.

Concept introduction:

The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula CnH2n-2. The name of the alkyne compounds ends with suffix −yne.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14 - Prob. 14.1P Ch. 14 - Prob. 14.2P Ch. 14 - Prob. 14.3P Ch. 14 - Prob. 14.4P Ch. 14 - Prob. 14.5P Ch. 14 - Prob. 14.6P Ch. 14 - Prob. 14.7P Ch. 14 - Prob. 14.8P Ch. 14 - Prob. 14.9P Ch. 14 - Prob. 14.10P

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