Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 14, Problem 14.130CP
Interpretation Introduction
Interpretation:
Determine the effect of temperature on the equilibrium of an exothermic reaction. Use the Arrhenius equation and the equilibrium constant expression to explain the relationship.
Concept introduction:
- Le Chatelier’s principle states that any system in equilibrium that is subject to change in concentration, temperature, volume or pressure, will adjust itself to account for the changes and will reach a new equilibrium.
- The Arrhenius equation is shows the dependence of the rate on the activation energy and the temperature of the reaction.
- The equilibrium constant using concentrations of Kcwhichisalso the ratio of the forward and reverse rates.
To classify:
The effect of temperature on Kc for an exothermic reaction.
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Arrange the following compounds / ions in increasing nucleophilicity (least to
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CH3NH2
CH3C=C:
CH3COO
1
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1, 2, 3
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2, 3, 1
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Chapter 14 Solutions
Chemistry (7th Edition)
Ch. 14 - Prob. 14.1PCh. 14 - APPLY 14.2 Nitrogen dioxide, a pollutant that...Ch. 14 - Prob. 14.3PCh. 14 - APPLY 14.4 Lactic acid, which builds up in muscle...Ch. 14 - Conceptual PRACTICE 14.5 The following pictures...Ch. 14 - Conceptual APPLY 14.6 The equilibrium constant...Ch. 14 - PRACTICE 14.7 In the industrial synthesis of...Ch. 14 - APPLY 14.8 At 25 °C, Kp = 25 for the reaction...Ch. 14 - Prob. 14.9PCh. 14 - APPLY 14.10For the reaction...
Ch. 14 - Prob. 14.11PCh. 14 - APPLY 14.12 Magnesium hydroxide is the active...Ch. 14 - Prob. 14.13PCh. 14 - Prob. 14.14ACh. 14 - Prob. 14.15PCh. 14 - Conceptual APPLY 14.16 The reaction A2 + B2 2...Ch. 14 - PRACTICE 14.17 The H2/CO ratio in mixtures of...Ch. 14 - APPLY 14.18 Calculate the equilibrium...Ch. 14 - PRACTICE 14.19 Calculate the equilibrium...Ch. 14 - APPLY 14.20 Calculate the equilibrium...Ch. 14 - Prob. 14.21PCh. 14 - Prob. 14.22ACh. 14 - Prob. 14.23PCh. 14 - Prob. 14.24ACh. 14 - Prob. 14.25PCh. 14 - Prob. 14.26ACh. 14 - Prob. 14.27PCh. 14 - Prob. 14.28ACh. 14 - Prob. 14.29PCh. 14 - Prob. 14.30ACh. 14 - Prob. 14.31PCh. 14 - Prob. 14.32ACh. 14 - Prob. 14.33PCh. 14 - Prob. 14.34PCh. 14 - Prob. 14.35PCh. 14 - Prob. 14.36PCh. 14 - PROBLEM 14.37 The affinity of hemoglobin (Hb) for...Ch. 14 - Prob. 14.38PCh. 14 - Prob. 14.39CPCh. 14 - The following pictures represent the equilibrium...Ch. 14 - The reaction A2+BA+AB has an equilibrium constant...Ch. 14 - Prob. 14.42CPCh. 14 - Prob. 14.43CPCh. 14 - Prob. 14.44CPCh. 14 - The following pictures represent equilibrium...Ch. 14 - Prob. 14.46CPCh. 14 - Prob. 14.47CPCh. 14 - Prob. 14.48CPCh. 14 - Prob. 14.49CPCh. 14 - Prob. 14.50SPCh. 14 - Identify the true statement about the...Ch. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - For each of the following equilibria, write the...Ch. 14 - Prob. 14.55SPCh. 14 - Prob. 14.56SPCh. 14 - Prob. 14.57SPCh. 14 - For each of the following equilibria, write the...Ch. 14 - Prob. 14.59SPCh. 14 - 14.60 If Kc = 7.5 × 10-9 at 1000 K for the...Ch. 14 - Prob. 14.61SPCh. 14 - Prob. 14.62SPCh. 14 - Prob. 14.63SPCh. 14 - Prob. 14.64SPCh. 14 - Prob. 14.65SPCh. 14 - Prob. 14.66SPCh. 14 - Prob. 14.67SPCh. 14 - Prob. 14.68SPCh. 14 - Prob. 14.69SPCh. 14 - Prob. 14.70SPCh. 14 - Prob. 14.71SPCh. 14 - Prob. 14.72SPCh. 14 - Prob. 14.73SPCh. 14 - Prob. 14.74SPCh. 14 - Prob. 14.75SPCh. 14 - Prob. 14.76SPCh. 14 - Prob. 14.77SPCh. 14 - Prob. 14.78SPCh. 14 - Prob. 14.79SPCh. 14 - Prob. 14.80SPCh. 14 - Prob. 14.81SPCh. 14 - Prob. 14.82SPCh. 14 - Prob. 14.83SPCh. 14 - Prob. 14.84SPCh. 14 - Prob. 14.85SPCh. 14 - Prob. 14.86SPCh. 14 - Prob. 14.87SPCh. 14 - Prob. 14.88SPCh. 14 - Prob. 14.89SPCh. 14 - Prob. 14.90SPCh. 14 - Prob. 14.91SPCh. 14 - Prob. 14.92SPCh. 14 - Prob. 14.93SPCh. 14 - Prob. 14.94SPCh. 14 - Prob. 14.95SPCh. 14 - Prob. 14.96SPCh. 14 - Prob. 14.97SPCh. 14 - Prob. 14.98SPCh. 14 - Prob. 14.99SPCh. 14 - Prob. 14.100SPCh. 14 - Prob. 14.101SPCh. 14 - Prob. 14.102SPCh. 14 - Prob. 14.103SPCh. 14 - Prob. 14.104SPCh. 14 - Consider the endothermic reaction...Ch. 14 - Prob. 14.106SPCh. 14 - Prob. 14.107SPCh. 14 - Prob. 14.108SPCh. 14 - Prob. 14.109SPCh. 14 - Prob. 14.110SPCh. 14 - Prob. 14.111SPCh. 14 - Prob. 14.112SPCh. 14 - Prob. 14.113SPCh. 14 - Prob. 14.114SPCh. 14 - Prob. 14.115SPCh. 14 - Prob. 14.116SPCh. 14 - Prob. 14.117SPCh. 14 - Prob. 14.118SPCh. 14 - Forward and reverse rate constants for the...Ch. 14 - Prob. 14.120CPCh. 14 - Prob. 14.121CPCh. 14 - Prob. 14.122CPCh. 14 - Prob. 14.123CPCh. 14 - Prob. 14.124CPCh. 14 - Prob. 14.125CPCh. 14 - Prob. 14.126CPCh. 14 - Prob. 14.127CPCh. 14 - Prob. 14.128CPCh. 14 - Prob. 14.129CPCh. 14 - Prob. 14.130CPCh. 14 - At 1000 K, Kp, = 2.1 106 and H=107.7kJ for the...Ch. 14 - Prob. 14.132CPCh. 14 - Prob. 14.133CPCh. 14 - Prob. 14.134CPCh. 14 - Prob. 14.135CPCh. 14 - Prob. 14.136CPCh. 14 - Prob. 14.137CPCh. 14 - Prob. 14.138CPCh. 14 - Prob. 14.139CPCh. 14 - Prob. 14.140CPCh. 14 - Prob. 14.141CPCh. 14 - Prob. 14.142CPCh. 14 - Prob. 14.143CPCh. 14 - Prob. 14.144CPCh. 14 - Prob. 14.145CPCh. 14 - Prob. 14.146CPCh. 14 - Prob. 14.147MPCh. 14 - Prob. 14.148MPCh. 14 - Prob. 14.149MPCh. 14 - Prob. 14.150MPCh. 14 - Prob. 14.151MPCh. 14 - Prob. 14.152MPCh. 14 - Prob. 14.153MPCh. 14 - Prob. 14.154MPCh. 14 - Prob. 14.155MPCh. 14 - Prob. 14.156MPCh. 14 - Prob. 14.157MPCh. 14 - Prob. 14.158MPCh. 14 - Prob. 14.159MP
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