Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 13, Problem 23QRT
Interpretation Introduction
Interpretation:
The process of dissolving
Concept Introduction:
Dissolving ionic solids in liquids: On dissolving ionic solids in water, water molecules surround cations and anions are called hydration.
Hydration enthalpy is defined asthe enthalpy change when new attractions form between ions and water-molecule dipoles. Energy always that require to separate the ions from crystal lattice, and energy always released when ions become hydrated because molecular dipoles attract the molecules to the ions.
The relation between the enthalpy of solution as follows,
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 13 Solutions
Chemistry: The Molecular Science
Ch. 13.1 - How could the data in Table 13.2 be used to...Ch. 13.1 - Prob. 13.2CECh. 13.1 - Prob. 13.1PSPCh. 13.1 - Prob. 13.2PSPCh. 13.2 - Prob. 13.3ECh. 13.2 - Determine whether each of these masses of NH4Cl...Ch. 13.4 - Prob. 13.5CECh. 13.4 - Explain why water that has been used to cool a...Ch. 13.4 - If a substance has a positive enthalpy of...Ch. 13.5 - Suppose that a trout stream at 25 C is in...
Ch. 13.6 - Prob. 13.4PSPCh. 13.6 - Prob. 13.8ECh. 13.6 - Drinking water may contain small quantities of...Ch. 13.6 - Prob. 13.9CECh. 13.6 - A 500-mL bottle of Evian bottled water contains 12...Ch. 13.6 - The mass fraction of gold in seawater is 1 103...Ch. 13.6 - Prob. 13.6PSPCh. 13.6 - Prob. 13.7PSPCh. 13.6 - Prob. 13.8PSPCh. 13.6 - Prob. 13.9PSPCh. 13.6 - Prob. 13.12ECh. 13.6 - Prob. 13.13CECh. 13.7 - The vapor pressure of an aqueous solution of urea....Ch. 13.7 - Prob. 13.14ECh. 13.7 - Prob. 13.15ECh. 13.7 - Prob. 13.11PSPCh. 13.7 - Suppose that you are closing a cabin in the north...Ch. 13.7 - A student determines the freezing point to be 5.15...Ch. 13.7 - Prob. 13.17CECh. 13.7 - Prob. 13.13PSPCh. 13.9 - Prob. 13.18CECh. 13.10 - Prob. 13.19ECh. 13.10 - Prob. 13.20ECh. 13 - Prob. 1QRTCh. 13 - Prob. 2QRTCh. 13 - Prob. 3QRTCh. 13 - Prob. 4QRTCh. 13 - Prob. 5QRTCh. 13 - Prob. 6QRTCh. 13 - Prob. 7QRTCh. 13 - Prob. 8QRTCh. 13 - Prob. 9QRTCh. 13 - Prob. 10QRTCh. 13 - Prob. 11QRTCh. 13 - Prob. 12QRTCh. 13 - Prob. 13QRTCh. 13 - Prob. 14QRTCh. 13 - Beakers (a), (b), and (c) are representations of...Ch. 13 - Prob. 16QRTCh. 13 - Simple acids such as formic acid, HCOOH, and...Ch. 13 - Prob. 18QRTCh. 13 - Prob. 19QRTCh. 13 - Prob. 20QRTCh. 13 - Prob. 21QRTCh. 13 - Prob. 22QRTCh. 13 - Prob. 23QRTCh. 13 - Prob. 24QRTCh. 13 - Prob. 25QRTCh. 13 - Prob. 26QRTCh. 13 - Refer to Figure 13.10 ( Sec. 13-4b) to answer...Ch. 13 - Prob. 28QRTCh. 13 - Prob. 29QRTCh. 13 - Prob. 30QRTCh. 13 - The Henrys law constant for nitrogen in blood...Ch. 13 - Prob. 32QRTCh. 13 - Prob. 33QRTCh. 13 - Prob. 34QRTCh. 13 - Prob. 35QRTCh. 13 - Prob. 36QRTCh. 13 - Prob. 37QRTCh. 13 - Prob. 38QRTCh. 13 - Prob. 39QRTCh. 13 - Prob. 40QRTCh. 13 - A sample of water contains 0.010 ppm lead ions,...Ch. 13 - Prob. 42QRTCh. 13 - Prob. 43QRTCh. 13 - Prob. 44QRTCh. 13 - Prob. 45QRTCh. 13 - Prob. 46QRTCh. 13 - Prob. 47QRTCh. 13 - Prob. 48QRTCh. 13 - Prob. 49QRTCh. 13 - Prob. 50QRTCh. 13 - Consider a 13.0% solution of sulfuric acid,...Ch. 13 - You want to prepare a 1.0 mol/kg solution of...Ch. 13 - Prob. 53QRTCh. 13 - Prob. 54QRTCh. 13 - Prob. 55QRTCh. 13 - A 12-oz (355-mL) Pepsi contains 38.9 mg...Ch. 13 - Prob. 57QRTCh. 13 - Prob. 58QRTCh. 13 - Prob. 59QRTCh. 13 - Prob. 60QRTCh. 13 - Prob. 61QRTCh. 13 - Prob. 62QRTCh. 13 - Prob. 63QRTCh. 13 - Prob. 64QRTCh. 13 - Prob. 65QRTCh. 13 - Prob. 66QRTCh. 13 - Calculate the boiling point and the freezing point...Ch. 13 - Prob. 68QRTCh. 13 - Prob. 69QRTCh. 13 - Prob. 70QRTCh. 13 - Prob. 71QRTCh. 13 - Prob. 72QRTCh. 13 - The freezing point of p-dichlorobenzene is 53.1 C,...Ch. 13 - Prob. 74QRTCh. 13 - Prob. 75QRTCh. 13 - A 1.00 mol/kg aqueous sulfuric acid solution,...Ch. 13 - Prob. 77QRTCh. 13 - Prob. 78QRTCh. 13 - Prob. 79QRTCh. 13 - Prob. 80QRTCh. 13 - Prob. 81QRTCh. 13 - Differentiate between the dispersed phase and the...Ch. 13 - Prob. 83QRTCh. 13 - Prob. 84QRTCh. 13 - Prob. 85QRTCh. 13 - Prob. 86QRTCh. 13 - Prob. 87QRTCh. 13 - Prob. 88QRTCh. 13 - Prob. 89QRTCh. 13 - Prob. 90QRTCh. 13 - Prob. 91QRTCh. 13 - Prob. 92QRTCh. 13 - Prob. 93QRTCh. 13 - Prob. 94QRTCh. 13 - Prob. 95QRTCh. 13 - Prob. 96QRTCh. 13 - Prob. 97QRTCh. 13 - Prob. 98QRTCh. 13 - Prob. 99QRTCh. 13 - Prob. 100QRTCh. 13 - Prob. 101QRTCh. 13 - Prob. 102QRTCh. 13 - In The Rime of the Ancient Mariner the poet Samuel...Ch. 13 - Prob. 104QRTCh. 13 - Prob. 105QRTCh. 13 - Calculate the molality of a solution made by...Ch. 13 - Prob. 107QRTCh. 13 - Prob. 108QRTCh. 13 - Prob. 109QRTCh. 13 - Prob. 110QRTCh. 13 - The organic salt [(C4H9)4N][ClO4] consists of the...Ch. 13 - A solution, prepared by dissolving 9.41 g NaHSO3...Ch. 13 - A 0.250-M sodium sulfate solution is added to a...Ch. 13 - Prob. 114QRTCh. 13 - Prob. 115QRTCh. 13 - Prob. 116QRTCh. 13 - Prob. 117QRTCh. 13 - Prob. 118QRTCh. 13 - Prob. 119QRTCh. 13 - Refer to Figure 13.10 ( Sec. 13-4b) to determine...Ch. 13 - Prob. 121QRTCh. 13 - Prob. 122QRTCh. 13 - Prob. 123QRTCh. 13 - Prob. 124QRTCh. 13 - In your own words, explain why (a) seawater has a...Ch. 13 - Prob. 126QRTCh. 13 - Prob. 127QRTCh. 13 - Prob. 128QRTCh. 13 - Prob. 129QRTCh. 13 - Prob. 130QRTCh. 13 - Prob. 131QRTCh. 13 - A 0.109 mol/kg aqueous solution of formic...Ch. 13 - Prob. 133QRTCh. 13 - Maple syrup sap is 3% sugar (sucrose) and 97%...Ch. 13 - Prob. 137QRTCh. 13 - Prob. 13.ACPCh. 13 - Prob. 13.BCPCh. 13 - Prob. 13.CCP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in the following reaction. Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is a weak base used to neutralize strong acid (pKa < 0) produced by the reaction. Redraw the product to show the configuration(s) that form at C-2 and C-4. Br2 OH CH2Cl2 Na* HCO3 Br HO OH + Na Br +arrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); H₂O2/HO (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI + enant OH Solvent Reagent(s) Solvent Reagent(s)arrow_forwardGermanium (Ge) is a semiconductor with a bandgap of 2.2 eV. How could you dope Ge to make it a p-type semiconductor with a larger bandgap? Group of answer choices It is impossible to dope Ge and have this result in a larger bandgap. Dope the Ge with silicon (Si) Dope the Ge with gallium (Ga) Dope the Ge with phosphorus (P)arrow_forward
- Which of the following semiconductors would you choose to have photons with the longest possible wavelengths be able to promote electrons to the semiconductor's conduction band? Group of answer choices Si Ge InSb CdSarrow_forwardWhich of the following metals is the only one with all of its bands completely full? Group of answer choices K Na Ca Alarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); Reagents: H₂O (B); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI OH - α-α Br + enant Solvent Reagent(s) Solvent Reagent(s)arrow_forward
- Based on concepts from Lecture 3-5, which of the following ionic compounds should be most soluble in water? Group of answer choices MgO BeO CaO BaOarrow_forwardFrom an energy standpoint, which two process - in the correct order - are involved in the dissolving of an ionic compound crystal? Group of answer choices Water coordination to the ions followed by sublimation into the gas phase Sublimation of the crystal into gas-phase ions followed by water coordination to the ions Ion dissociation from the crystal followed by water coordination to the ions Water coordination to the ions followed by ion dissociation from the crystalarrow_forwardFor which Group 2 metal (M), is this process the most exothermic? M2+(g) + O2−(g) + CO2(g) → MO(s) + CO2(g) Group of answer choices M = Sr M = Mg M = Ca M = Baarrow_forward
- 2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); R₂BH (6); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI Solvent Reagent(s) Solvent Reagent(s) HO OHarrow_forwardFor which of the following ionic compounds would you expect the smallest difference between its theoretical and experimental lattice enthalpies? (You may assume these all have the same unit cell structure.) Electronegativities: Ca (1.0), Fe (1.8), Mg (1.2), O (3.5), S (2.5), Zn (1.6) Group of answer choices ZnO MgS CaO FeSarrow_forwardIn the Born-Haber cycle for KCl crystal formation, what enthalpy component must be divided by two? Group of answer choices KCl(s) enthalpy of formation Ionization energy for K(g) K(s) sublimation enthalpy Cl2 bond dissociation enthalpyarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY