Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Textbook Question
Chapter 13.1, Problem 13.1CE
How could the data in Table 13.2 be used to predict the solubility in water of 1-octanol or 1-decanol?
Table 13.2 Solubilities of Alcohols in Water, 20°C
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how do i determine water solubility for each one?
1. Consider the solubility and boiling point of the following pair of compounds: n-butyl alcohol and diethyl ether. The boiling points for the compounds are 118 °C and 35 °C respectively. The solubility for both compounds is the same (8g/100g water). Explain this observation for (i) boiling point disparity; (ii) solubility similarity
a. H-bonds form in diethyl ether; n-butyl alcohol forms H-bonds in water
b. H-bonds form in n-butyl alcohol; diethyl ether forms H-bonds in water
c. H-bonds in n-butyl alcohol; Both compounds form H-bonds in water
d. Both compounds form H-bonds; Both compounds form H-bonds in water
2. Account for the bond angle differences between (i) H-C-H (109.5°) in methane and H-S-H (90°); H-C-H (109.5°) and H-O-H (107.5°) in water.
a. The H-S-H has two lone pairs; The H-O-H has two lone pairs
b. The H-S-H has no hybridization at p-orbitals; The H-O-H has two lone pairs
c. The H-S-H has two lone pairs; The H-O-H has no hybridization…
Description
Solubility in
water (+/-)
Sample
Skeletal Structure
(i.e., physical state, odor,
clarity and color)
Ethanol
1-Butanol
Cyclohexanol
Isoamyl
alcohol
Phenoliolpgy Environmental Science
Explain in 2 – 3 sentences the solubility of alcohols and phenols in water.
Chapter 13 Solutions
Chemistry: The Molecular Science
Ch. 13.1 - How could the data in Table 13.2 be used to...Ch. 13.1 - Prob. 13.2CECh. 13.1 - Prob. 13.1PSPCh. 13.1 - Prob. 13.2PSPCh. 13.2 - Prob. 13.3ECh. 13.2 - Determine whether each of these masses of NH4Cl...Ch. 13.4 - Prob. 13.5CECh. 13.4 - Explain why water that has been used to cool a...Ch. 13.4 - If a substance has a positive enthalpy of...Ch. 13.5 - Suppose that a trout stream at 25 C is in...
Ch. 13.6 - Prob. 13.4PSPCh. 13.6 - Prob. 13.8ECh. 13.6 - Drinking water may contain small quantities of...Ch. 13.6 - Prob. 13.9CECh. 13.6 - A 500-mL bottle of Evian bottled water contains 12...Ch. 13.6 - The mass fraction of gold in seawater is 1 103...Ch. 13.6 - Prob. 13.6PSPCh. 13.6 - Prob. 13.7PSPCh. 13.6 - Prob. 13.8PSPCh. 13.6 - Prob. 13.9PSPCh. 13.6 - Prob. 13.12ECh. 13.6 - Prob. 13.13CECh. 13.7 - The vapor pressure of an aqueous solution of urea....Ch. 13.7 - Prob. 13.14ECh. 13.7 - Prob. 13.15ECh. 13.7 - Prob. 13.11PSPCh. 13.7 - Suppose that you are closing a cabin in the north...Ch. 13.7 - A student determines the freezing point to be 5.15...Ch. 13.7 - Prob. 13.17CECh. 13.7 - Prob. 13.13PSPCh. 13.9 - Prob. 13.18CECh. 13.10 - Prob. 13.19ECh. 13.10 - Prob. 13.20ECh. 13 - Prob. 1QRTCh. 13 - Prob. 2QRTCh. 13 - Prob. 3QRTCh. 13 - Prob. 4QRTCh. 13 - Prob. 5QRTCh. 13 - Prob. 6QRTCh. 13 - Prob. 7QRTCh. 13 - Prob. 8QRTCh. 13 - Prob. 9QRTCh. 13 - Prob. 10QRTCh. 13 - Prob. 11QRTCh. 13 - Prob. 12QRTCh. 13 - Prob. 13QRTCh. 13 - Prob. 14QRTCh. 13 - Beakers (a), (b), and (c) are representations of...Ch. 13 - Prob. 16QRTCh. 13 - Simple acids such as formic acid, HCOOH, and...Ch. 13 - Prob. 18QRTCh. 13 - Prob. 19QRTCh. 13 - Prob. 20QRTCh. 13 - Prob. 21QRTCh. 13 - Prob. 22QRTCh. 13 - Prob. 23QRTCh. 13 - Prob. 24QRTCh. 13 - Prob. 25QRTCh. 13 - Prob. 26QRTCh. 13 - Refer to Figure 13.10 ( Sec. 13-4b) to answer...Ch. 13 - Prob. 28QRTCh. 13 - Prob. 29QRTCh. 13 - Prob. 30QRTCh. 13 - The Henrys law constant for nitrogen in blood...Ch. 13 - Prob. 32QRTCh. 13 - Prob. 33QRTCh. 13 - Prob. 34QRTCh. 13 - Prob. 35QRTCh. 13 - Prob. 36QRTCh. 13 - Prob. 37QRTCh. 13 - Prob. 38QRTCh. 13 - Prob. 39QRTCh. 13 - Prob. 40QRTCh. 13 - A sample of water contains 0.010 ppm lead ions,...Ch. 13 - Prob. 42QRTCh. 13 - Prob. 43QRTCh. 13 - Prob. 44QRTCh. 13 - Prob. 45QRTCh. 13 - Prob. 46QRTCh. 13 - Prob. 47QRTCh. 13 - Prob. 48QRTCh. 13 - Prob. 49QRTCh. 13 - Prob. 50QRTCh. 13 - Consider a 13.0% solution of sulfuric acid,...Ch. 13 - You want to prepare a 1.0 mol/kg solution of...Ch. 13 - Prob. 53QRTCh. 13 - Prob. 54QRTCh. 13 - Prob. 55QRTCh. 13 - A 12-oz (355-mL) Pepsi contains 38.9 mg...Ch. 13 - Prob. 57QRTCh. 13 - Prob. 58QRTCh. 13 - Prob. 59QRTCh. 13 - Prob. 60QRTCh. 13 - Prob. 61QRTCh. 13 - Prob. 62QRTCh. 13 - Prob. 63QRTCh. 13 - Prob. 64QRTCh. 13 - Prob. 65QRTCh. 13 - Prob. 66QRTCh. 13 - Calculate the boiling point and the freezing point...Ch. 13 - Prob. 68QRTCh. 13 - Prob. 69QRTCh. 13 - Prob. 70QRTCh. 13 - Prob. 71QRTCh. 13 - Prob. 72QRTCh. 13 - The freezing point of p-dichlorobenzene is 53.1 C,...Ch. 13 - Prob. 74QRTCh. 13 - Prob. 75QRTCh. 13 - A 1.00 mol/kg aqueous sulfuric acid solution,...Ch. 13 - Prob. 77QRTCh. 13 - Prob. 78QRTCh. 13 - Prob. 79QRTCh. 13 - Prob. 80QRTCh. 13 - Prob. 81QRTCh. 13 - Differentiate between the dispersed phase and the...Ch. 13 - Prob. 83QRTCh. 13 - Prob. 84QRTCh. 13 - Prob. 85QRTCh. 13 - Prob. 86QRTCh. 13 - Prob. 87QRTCh. 13 - Prob. 88QRTCh. 13 - Prob. 89QRTCh. 13 - Prob. 90QRTCh. 13 - Prob. 91QRTCh. 13 - Prob. 92QRTCh. 13 - Prob. 93QRTCh. 13 - Prob. 94QRTCh. 13 - Prob. 95QRTCh. 13 - Prob. 96QRTCh. 13 - Prob. 97QRTCh. 13 - Prob. 98QRTCh. 13 - Prob. 99QRTCh. 13 - Prob. 100QRTCh. 13 - Prob. 101QRTCh. 13 - Prob. 102QRTCh. 13 - In The Rime of the Ancient Mariner the poet Samuel...Ch. 13 - Prob. 104QRTCh. 13 - Prob. 105QRTCh. 13 - Calculate the molality of a solution made by...Ch. 13 - Prob. 107QRTCh. 13 - Prob. 108QRTCh. 13 - Prob. 109QRTCh. 13 - Prob. 110QRTCh. 13 - The organic salt [(C4H9)4N][ClO4] consists of the...Ch. 13 - A solution, prepared by dissolving 9.41 g NaHSO3...Ch. 13 - A 0.250-M sodium sulfate solution is added to a...Ch. 13 - Prob. 114QRTCh. 13 - Prob. 115QRTCh. 13 - Prob. 116QRTCh. 13 - Prob. 117QRTCh. 13 - Prob. 118QRTCh. 13 - Prob. 119QRTCh. 13 - Refer to Figure 13.10 ( Sec. 13-4b) to determine...Ch. 13 - Prob. 121QRTCh. 13 - Prob. 122QRTCh. 13 - Prob. 123QRTCh. 13 - Prob. 124QRTCh. 13 - In your own words, explain why (a) seawater has a...Ch. 13 - Prob. 126QRTCh. 13 - Prob. 127QRTCh. 13 - Prob. 128QRTCh. 13 - Prob. 129QRTCh. 13 - Prob. 130QRTCh. 13 - Prob. 131QRTCh. 13 - A 0.109 mol/kg aqueous solution of formic...Ch. 13 - Prob. 133QRTCh. 13 - Maple syrup sap is 3% sugar (sucrose) and 97%...Ch. 13 - Prob. 137QRTCh. 13 - Prob. 13.ACPCh. 13 - Prob. 13.BCPCh. 13 - Prob. 13.CCP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY