Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 13, Problem 18P
Interpretation Introduction
Interpretation:
The reagents required for the given reactants to produce 1,3-butadiene are to be determined.
Concept introduction:
Alcohols heated in the presence of mineral acids undergo elimination reaction and form
Primary alcohols undergo E2 elimination with concentrated sulfuric acid
Nickel boride
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Write structural formulas for the products that form when 1-butene reacts with each of
the following reagents:
(a) HI
(b) H2, Pt
(c) Dilute H2SO4, warm
(d) Cold concentrated H2SO4
(e) Cold concentrated H2SO4, then H2O and heat
(f) HBr
(g) Br2 in CCl4
(h) Br2 in H2O
(i) HCl
(j) O3, then Me2S
(k) OsO4, then NaHSO3/H2O
(l) KMnO4, OH-, heat, then H3O+
(m) Hg(OAc)2 in THF and H2O, then NaBH4, OH-
(n) BH3:THF,
then H2O2, OH-
6) Which is the organic product for the following reaction?
(a)
(b)
(c)
(d)
LOH
OH
COOH
OH
OH
COOH
COOH
KMnO4
H₂O
(e) None of the above products will be formed
Starting from bromoethane, the formation of which of the following
compound requires more than one step of reaction? 2
(a) Methoxyethane (b) Ethanol
(c) Ethanoic acid (d) Ethene
Chapter 13 Solutions
Organic Chemistry
Ch. 13 - Prob. 1PPCh. 13 - Prob. 2PPCh. 13 - Prob. 3PPCh. 13 - Practice Problem 13.4 From each set of resonance...Ch. 13 - Practice Problem 13.5 The following enol (an...Ch. 13 - Prob. 6PPCh. 13 - Practice Problem 13.7
Two compounds, A and B, have...Ch. 13 - Prob. 8PPCh. 13 - Prob. 9PPCh. 13 - Prob. 10PP
Ch. 13 - Prob. 11PPCh. 13 - Prob. 12PPCh. 13 - Prob. 13PPCh. 13 - Prob. 14PPCh. 13 - Prob. 15PPCh. 13 - Practice Problem 13.16
Diels–Alder reactions also...Ch. 13 - Prob. 17PPCh. 13 - Prob. 18PCh. 13 - What product would you expect from the following...Ch. 13 - Prob. 20PCh. 13 - Prob. 21PCh. 13 - Provide the reagents necessary for each of the...Ch. 13 - Prob. 23PCh. 13 - Prob. 24PCh. 13 - Prob. 25PCh. 13 - When 1-pentene reacts with N-bromosuccinimide...Ch. 13 - Prob. 27PCh. 13 - Prob. 28PCh. 13 - Prob. 29PCh. 13 - Prob. 30PCh. 13 - 13.31 Provide a mechanism that explains formation...Ch. 13 - 13.32 Provide a mechanism that explains formation...Ch. 13 - Treating either 1-chloro-3-methyl-2-butene or...Ch. 13 - Prob. 34PCh. 13 - Prob. 35PCh. 13 - Although both 1-bromobutane and 4-bromo-1-butene...Ch. 13 - Prob. 37PCh. 13 - Prob. 38PCh. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Prob. 44PCh. 13 - 13.44 When furan and maleimide undergo a...Ch. 13 - Two controversial hard insecticides are aldrin and...Ch. 13 - Prob. 47PCh. 13 - Prob. 48PCh. 13 - Prob. 49PCh. 13 - Prob. 50PCh. 13 - Explain the product distribution below based on...Ch. 13 - Mixing furan (Problem 13.44) with maleic anhydride...Ch. 13 - Prob. 53PCh. 13 - Prob. 54PCh. 13 - Prob. 1LGPCh. 13 - Prob. 2LGPCh. 13 - Prob. 1QCh. 13 - Prob. 2QCh. 13 - Prob. 3QCh. 13 - Prob. 4QCh. 13 - Prob. 5Q
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