Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 13, Problem 13.9P
Interpretation Introduction

(a)

Interpretation:

The different number of absorptions observed in the NMR spectrum is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of atom of a particular element present in different environment can be detected. Chemical shift is defined as the distance from the reference point. Protons present in different environment gives different absoprtion peak in NMR spectrum.

Interpretation Introduction

(b)

Interpretation:

The different number of absorptions observed in the NMR spectrum is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of atom of a particular element present in different environment can be detected. Chemical shift is defined as the distance from the reference point. Protons present in different environment gives different absoprtion peak in NMR spectrum.

Interpretation Introduction

(c)

Interpretation:

The different number of absorptions observed in the NMR spectrum is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of atom of a particular element present in different environment can be detected. Chemical shift is defined as the distance from the reference point. Protons present in different environment gives different absoprtion peak in NMR spectrum.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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