The compounds A and B are to be differentiated using NMR technique. Concept introduction: Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depends upon its surrounding protons. Tetramethylsilane is taken as reference. Also, the spacing between splitted lines of NMR spectra is known as coupling constant. The angle between two intersected planes is known as dihedral angle.

Question

Indicate compound A that must react with ethylbenzene to obtain 4-ethylbenzene-1-sulfonic acid. 3-bromo-4-ethylbenzene-1-sulfonic acid.

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Chapter 13, Problem 13.60AP

Interpretation Introduction

Interpretation:

The compounds A and B are to be differentiated using NMR technique.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depends upon its surrounding protons. Tetramethylsilane is taken as reference. Also, the spacing between splitted lines of NMR spectra is known as coupling constant. The angle between two intersected planes is known as dihedral angle.

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Indicate compound A that must react with ethylbenzene to obtain 4-ethylbenzene-1-sulfonic acid. 3-bromo-4-ethylbenzene-1-sulfonic acid.

Part 1 of 2 Draw the structure of A, the minor E1 product of the reaction. esc I Skip Part Check H₂O, D 2 A + Click and drag to start drawing a structure. -0- F1 F2 1 2 # 3 Q A 80 F3 W E S D F4 $ 4 % 5 F5 ㅇ F6 R T Y F G X 5 & 7 + Save 2025 McGraw Hill LLC. All Rights Reserved. DII F7 F8 H * C 80 J Z X C V B N 4 F9 6

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