(a) Interpretation: The compound A obtained after reaction of 3-bromopropene with HBr in the presence of peroxides is to be stated. Concept introduction: The alkene undergoes addition reaction due to the presence of high electron density of the double bond. The addition of the haloacids onto an alkene follows the markonikov’s rule. That is hydrogen goes to the carbon that contains higher number of hydrogens.

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Answer 1

Question

Chapter 13, Problem 13.18P

Interpretation Introduction

(a)

Interpretation:

The compound A obtained after reaction of 3-bromopropene with HBr in the presence of peroxides is to be stated.

Concept introduction:

The alkene undergoes addition reaction due to the presence of high electron density of the double bond. The addition of the haloacids onto an alkene follows the markonikov’s rule. That is hydrogen goes to the carbon that contains higher number of hydrogens.

Interpretation Introduction

(b)

Interpretation:

The structure of the comnpound A is to be confirmed on the basis of NMR spectrum.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Part C: Communication (/9) 17. Compare and contrast the Thomson, Rutherford and Bohr models of the atom using the chart below. You can use words and/or diagrams in your answers. (9) What was the experiment that led to the model? Where is positive charge in the atom located in the model? Where are electrons located in the molecule? Thomson Model Rutherford Model Bohr Model 2

Answer 2

Question

Chapter 13, Problem 13.18P

Interpretation Introduction

(a)

Interpretation:

The compound A obtained after reaction of 3-bromopropene with HBr in the presence of peroxides is to be stated.

Concept introduction:

The alkene undergoes addition reaction due to the presence of high electron density of the double bond. The addition of the haloacids onto an alkene follows the markonikov’s rule. That is hydrogen goes to the carbon that contains higher number of hydrogens.

Interpretation Introduction

(b)

Interpretation:

The structure of the comnpound A is to be confirmed on the basis of NMR spectrum.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Answer 3

Question

Chapter 13, Problem 13.18P

Interpretation Introduction

(a)

Interpretation:

The compound A obtained after reaction of 3-bromopropene with HBr in the presence of peroxides is to be stated.

Concept introduction:

The alkene undergoes addition reaction due to the presence of high electron density of the double bond. The addition of the haloacids onto an alkene follows the markonikov’s rule. That is hydrogen goes to the carbon that contains higher number of hydrogens.

Interpretation Introduction

(b)

Interpretation:

The structure of the comnpound A is to be confirmed on the basis of NMR spectrum.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Answer 4

Question

Chapter 13, Problem 13.18P

Interpretation Introduction

(a)

Interpretation:

The compound A obtained after reaction of 3-bromopropene with HBr in the presence of peroxides is to be stated.

Concept introduction:

The alkene undergoes addition reaction due to the presence of high electron density of the double bond. The addition of the haloacids onto an alkene follows the markonikov’s rule. That is hydrogen goes to the carbon that contains higher number of hydrogens.

Interpretation Introduction

(b)

Interpretation:

The structure of the comnpound A is to be confirmed on the basis of NMR spectrum.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Answer 5

Chapter 13, Problem 13.18P

Interpretation Introduction

(a)

Interpretation:

The compound A obtained after reaction of 3-bromopropene with HBr in the presence of peroxides is to be stated.

Concept introduction:

The alkene undergoes addition reaction due to the presence of high electron density of the double bond. The addition of the haloacids onto an alkene follows the markonikov’s rule. That is hydrogen goes to the carbon that contains higher number of hydrogens.

Interpretation Introduction

(b)

Interpretation:

The structure of the comnpound A is to be confirmed on the basis of NMR spectrum.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 6

Chapter 13, Problem 13.18P

Interpretation Introduction

(a)

Interpretation:

The compound A obtained after reaction of 3-bromopropene with HBr in the presence of peroxides is to be stated.

Concept introduction:

The alkene undergoes addition reaction due to the presence of high electron density of the double bond. The addition of the haloacids onto an alkene follows the markonikov’s rule. That is hydrogen goes to the carbon that contains higher number of hydrogens.

Answer 7

Chapter 13, Problem 13.18P

Interpretation Introduction

(a)

Interpretation:

The compound A obtained after reaction of 3-bromopropene with HBr in the presence of peroxides is to be stated.

Concept introduction:

The alkene undergoes addition reaction due to the presence of high electron density of the double bond. The addition of the haloacids onto an alkene follows the markonikov’s rule. That is hydrogen goes to the carbon that contains higher number of hydrogens.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of the comnpound A is to be confirmed on the basis of NMR spectrum.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of the comnpound A is to be confirmed on the basis of NMR spectrum.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 10

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Answer 12

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Answer 13

Ch. 13 - Prob. 13.1P Ch. 13 - Prob. 13.2P Ch. 13 - Prob. 13.3P Ch. 13 - Prob. 13.4P Ch. 13 - Prob. 13.5P Ch. 13 - Prob. 13.6P Ch. 13 - Prob. 13.7P Ch. 13 - Prob. 13.8P Ch. 13 - Prob. 13.9P Ch. 13 - Prob. 13.10P

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