(a) Interpretation: The structure of the molecule C 3 H 7 Br is to be stated. Concept introduction: Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

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Answer 1

Question

Chapter 13, Problem 13.16P

Interpretation Introduction

(a)

Interpretation:

The structure of the molecule C3H7Br is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule C2H3Cl3 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule C5H8Br4 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

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One method for the analysis of Fe3+, which is used with a variety of sample matrices, is to form the highly colored Fe3+–thioglycolic acid complex. The complex absorbs strongly at 535 nm. Standardizing the method is accomplished using external standards. A 10.00-ppm Fe3+ working standard is prepared by transferring a 10-mL aliquot of a 100.0 ppm stock solution of Fe3+ to a 100-mL volumetric flask and diluting to volume. Calibration standards of 1.00, 2.00, 3.00, 4.00, and 5.00 ppm are prepared by transferring appropriate amounts of the 10.0 ppm working solution into separate 50-mL volumetric flasks, each of which contains 5 mL of thioglycolic acid, 2 mL of 20% w/v ammonium citrate, and 5 mL of 0.22 M NH3. After diluting to volume and mixing, the absorbances of the external standards are measured against an appropriate blank. Samples are prepared for analysis by taking a portion known to contain approximately 0.1 g of Fe3+, dissolving it in a minimum amount of HNO3, and diluting to…

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Answer 2

Question

Chapter 13, Problem 13.16P

Interpretation Introduction

(a)

Interpretation:

The structure of the molecule C3H7Br is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule C2H3Cl3 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule C5H8Br4 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

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Answer 3

Question

Chapter 13, Problem 13.16P

Interpretation Introduction

(a)

Interpretation:

The structure of the molecule C3H7Br is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule C2H3Cl3 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule C5H8Br4 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

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Answer 4

Question

Chapter 13, Problem 13.16P

Interpretation Introduction

(a)

Interpretation:

The structure of the molecule C3H7Br is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule C2H3Cl3 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule C5H8Br4 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

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Answer 5

Chapter 13, Problem 13.16P

Interpretation Introduction

(a)

Interpretation:

The structure of the molecule C3H7Br is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule C2H3Cl3 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule C5H8Br4 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Answer 6

Chapter 13, Problem 13.16P

Interpretation Introduction

(a)

Interpretation:

The structure of the molecule C3H7Br is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Answer 7

Chapter 13, Problem 13.16P

Interpretation Introduction

(a)

Interpretation:

The structure of the molecule C3H7Br is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule C2H3Cl3 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule C2H3Cl3 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule C5H8Br4 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule C5H8Br4 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13 - Prob. 13.1P Ch. 13 - Prob. 13.2P Ch. 13 - Prob. 13.3P Ch. 13 - Prob. 13.4P Ch. 13 - Prob. 13.5P Ch. 13 - Prob. 13.6P Ch. 13 - Prob. 13.7P Ch. 13 - Prob. 13.8P Ch. 13 - Prob. 13.9P Ch. 13 - Prob. 13.10P

Solution Summary: The author explains the nuclear magnetic resonance spectra of a molecule.

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