Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated. Concept Introduction: Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula. Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Question

The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

Answer 1

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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In an experiment, the viscosity of water was measured at different temperatures and the table was constructed from the data obtained. a) Calculate the activation energy of viscous flow (kJ/mol). b) Calculate the viscosity at 30°C. T/°C 0 20 40 60 80 η/cpoise 1,972 1,005 0,656 0,469 0,356

Answer 2

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

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Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

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Answer 5

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 6

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 7

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 14

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Ch. 13.1 - Prob. 1QQ Ch. 13.1 - Prob. 2QQ Ch. 13.1 - Prob. 3QQ Ch. 13.2 - Prob. 1QQ Ch. 13.2 - Prob. 2QQ Ch. 13.2 - Prob. 3QQ Ch. 13.2 - Prob. 4QQ Ch. 13.3 - Prob. 1QQ Ch. 13.3 - Prob. 2QQ Ch. 13.3 - Prob. 3QQ

Solution Summary: The author explains that alkanes are more susceptible for addition reaction or substitution reaction.

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