CONNECT FOR THERMODYNAMICS: AN ENGINEERI
9th Edition
ISBN: 9781260048636
Author: CENGEL
Publisher: MCG
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Chapter 12.6, Problem 24P
Using the Clapeyron equation, estimate the enthalpy of vaporization of refrigerant-134a at 40°C, and compare it to the tabulated value.
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Chapter 12 Solutions
CONNECT FOR THERMODYNAMICS: AN ENGINEERI
Ch. 12.6 - What is the difference between partial...Ch. 12.6 - Consider the function z(x, y). Plot a differential...Ch. 12.6 - Consider a function z(x, y) and its partial...Ch. 12.6 - Prob. 4PCh. 12.6 - Prob. 5PCh. 12.6 - Consider a function f(x) and its derivative df/dx....Ch. 12.6 - Conside the function z(x, y), its partial...Ch. 12.6 - Consider air at 350 K and 0.75 m3/kg. Using Eq....Ch. 12.6 - Consider air at 350 K and 0.75 m3/kg. Using Eq....Ch. 12.6 - Nitrogen gas at 800 R and 50 psia behaves as an...
Ch. 12.6 - Consider an ideal gas at 400 K and 100 kPa. As a...Ch. 12.6 - Using the equation of state P(v a) = RT, verify...Ch. 12.6 - Prove for an ideal gas that (a) the P = constant...Ch. 12.6 - Verify the validity of the last Maxwell relation...Ch. 12.6 - Verify the validity of the last Maxwell relation...Ch. 12.6 - Show how you would evaluate T, v, u, a, and g from...Ch. 12.6 - Prob. 18PCh. 12.6 - Prob. 19PCh. 12.6 - Prob. 20PCh. 12.6 - Prove that (PT)=kk1(PT)v.Ch. 12.6 - Prob. 22PCh. 12.6 - Prob. 23PCh. 12.6 - Using the Clapeyron equation, estimate the...Ch. 12.6 - Prob. 26PCh. 12.6 - Determine the hfg of refrigerant-134a at 10F on...Ch. 12.6 - Prob. 28PCh. 12.6 - Prob. 29PCh. 12.6 - Two grams of a saturated liquid are converted to a...Ch. 12.6 - Prob. 31PCh. 12.6 - Prob. 32PCh. 12.6 - Prob. 33PCh. 12.6 - Prob. 34PCh. 12.6 - Prob. 35PCh. 12.6 - Prob. 36PCh. 12.6 - Determine the change in the internal energy of...Ch. 12.6 - Prob. 38PCh. 12.6 - Determine the change in the entropy of helium, in...Ch. 12.6 - Prob. 40PCh. 12.6 - Estimate the specific heat difference cp cv for...Ch. 12.6 - Derive expressions for (a) u, (b) h, and (c) s for...Ch. 12.6 - Derive an expression for the specific heat...Ch. 12.6 - Derive an expression for the specific heat...Ch. 12.6 - Derive an expression for the isothermal...Ch. 12.6 - Prob. 46PCh. 12.6 - Show that cpcv=T(PT)V(VT)P.Ch. 12.6 - Show that the enthalpy of an ideal gas is a...Ch. 12.6 - Prob. 49PCh. 12.6 - Show that = ( P/ T)v.Ch. 12.6 - Prob. 51PCh. 12.6 - Prob. 52PCh. 12.6 - Prob. 53PCh. 12.6 - Prob. 54PCh. 12.6 - Prob. 55PCh. 12.6 - Does the Joule-Thomson coefficient of a substance...Ch. 12.6 - The pressure of a fluid always decreases during an...Ch. 12.6 - Will the temperature of helium change if it is...Ch. 12.6 - Estimate the Joule-Thomson coefficient of...Ch. 12.6 - Estimate the Joule-Thomson coefficient of...Ch. 12.6 - Prob. 61PCh. 12.6 - Steam is throttled slightly from 1 MPa and 300C....Ch. 12.6 - What is the most general equation of state for...Ch. 12.6 - Prob. 64PCh. 12.6 - Consider a gas whose equation of state is P(v a)...Ch. 12.6 - Prob. 66PCh. 12.6 - What is the enthalpy departure?Ch. 12.6 - On the generalized enthalpy departure chart, the...Ch. 12.6 - Why is the generalized enthalpy departure chart...Ch. 12.6 - What is the error involved in the (a) enthalpy and...Ch. 12.6 - Prob. 71PCh. 12.6 - Saturated water vapor at 300C is expanded while...Ch. 12.6 - Determine the enthalpy change and the entropy...Ch. 12.6 - Prob. 74PCh. 12.6 - Prob. 75PCh. 12.6 - Prob. 77PCh. 12.6 - Propane is compressed isothermally by a...Ch. 12.6 - Prob. 81PCh. 12.6 - Prob. 82RPCh. 12.6 - Starting with the relation dh = T ds + vdP, show...Ch. 12.6 - Using the cyclic relation and the first Maxwell...Ch. 12.6 - For ideal gases, the development of the...Ch. 12.6 - Show that cv=T(vT)s(PT)vandcp=T(PT)s(vT)PCh. 12.6 - Temperature and pressure may be defined as...Ch. 12.6 - For a homogeneous (single-phase) simple pure...Ch. 12.6 - For a homogeneous (single-phase) simple pure...Ch. 12.6 - Prob. 90RPCh. 12.6 - Prob. 91RPCh. 12.6 - Estimate the cpof nitrogen at 300 kPa and 400 K,...Ch. 12.6 - Prob. 93RPCh. 12.6 - Prob. 94RPCh. 12.6 - Prob. 95RPCh. 12.6 - Methane is to be adiabatically and reversibly...Ch. 12.6 - Prob. 97RPCh. 12.6 - Prob. 98RPCh. 12.6 - Prob. 99RPCh. 12.6 - An adiabatic 0.2-m3 storage tank that is initially...Ch. 12.6 - Prob. 102FEPCh. 12.6 - Consider the liquidvapor saturation curve of a...Ch. 12.6 - For a gas whose equation of state is P(v b) = RT,...Ch. 12.6 - Prob. 105FEPCh. 12.6 - Prob. 106FEP
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- 4) A sample of argon at 01 atm pressure and 25C expands reversibly and adiabatically from 0.5 L to 1.0 L. Calculate its final temperature, the work done during the expansion, and the change in internal energy. The molar heat capacity of argon at constant volume is 12.48 JK-1mol-1.arrow_forwardA mole sample of liquid ammonia at 273 Kelvin is cooled to liquid ammonia at 240 Kelvin. The process is done irreversibly by placing the sample in liquid nitrogen at 77 Kelvin. The heat capacity relationship for ammonia gas is given below. Assuming that the heat of vaporization is 23.4 KiloJoules per mole, answer the questions that follow. What is the entropy change of this process (in Joules per Kelvin)? Express answer in THREE SIGNIFICANT FIGURES. What is the entropy change of the surroundings for this process (in Joules per Kelvin)? Express answer in THREE SIGNIFICANT FIGURES. What is the total entropy change (or the entropy of the universe) for this process (in Joules per Kelvin)? Express answer in THREE SIGNIFICANT FIGURES.arrow_forwardCalculate the molar entropy change (cal/mol-K) for the irreversible vaporization of superheated liquid water at 102 °C. = 9.7 kcal/mol, vap- C P, liquid water = 18 cal/mol-K Cp P, steam (cal/mol-K) = 7.2 + 2.4 x 10-3Tarrow_forward
- Three moles of an ideal gas at 100 kPa pressure and 20oC are heated reversibly at constant pressure until the final temperature is 80oC. For the gas, the heat capacity at constant pressure varies with themperature according to the equation; Cp = 35.56 + 1.34 x 10-2 T J mol1 K-1 . Calculate q, w . DU and DH Answer: [7.18 kJ; -1.50 kJ; 5.68 kJ; 7.18 kJ]arrow_forwardWhat is the enthalpy of refrigerant 134a with s = 0.94190 at 0.85MPa? (Superheated Vapor)arrow_forwardEstimate the Joule-Thomson coefficient of refrigerant-134a at 240 kPa and 20°C. Assume the second state will be selected for a pressure of 200 kPa. Use data from the tables. The Joule-Thomson coefficient of refrigerant-134a is K/kPa.arrow_forward
- At a pressure of 0.1 MPa, the specific enthalpies of water at temperatures of20°C and 30°C are 84.03 kJ/kg and 125.9 kJ/kg respectively. Find the specificenthalpy of water at 22°C and 0.1 MPa by linear interpolation.arrow_forwardQuestion : Determine the units of the quantity s ̄/Ru, where s ̄ is the molar specific entropy and Ru is the universal gas constant. Explain your answer pleasearrow_forwardSaturated water vapor at 200.111 oC is isothermally condensed to a saturated liquid in a piston-cylinder device. Calculate (d) change of entropy, and (e) change of enthalpy.arrow_forward
- Estimate the Joule-Thomson coefficient for steam at 3MPA and 300°C using the steam tables. Estimate the Joule-Thomson coefficient for steam at 6MPA and 500°C using the steam tables. During phase change the Joule-Thomson coefficient is always positive or negative? Using gure A-14E (or A-14) in the tables of your book, is the Joule-Thomson coefficient ever negative for r134a? If so, where is it negative relative to temperature and pressure?arrow_forwardCO2 needs to be compressed from p1=1bar, t1=300k to p2=40bar to transport it to remote sites for sequestration. what is the minimum energy requirement per kg of CO2 for the compressor? Should the compressor operate adiabatically or isothermally for the best energy efficiency? The environment is at Tenv=300k. Use accurate thermodynamic data for CO2 in this problem.arrow_forwardDerive Clausius-Clapeyron equation.arrow_forward
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