Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 12, Problem 89AP
What is resonance? Give three examples of molecules or ions that exhibit resonance, and draw Lewis structures for each of the possible resonance forms.
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Use the References to access important values if needed for this question.
Use average bond enthalpies (linked above) to calculate the enthalpy change for the following gas-phase reaction.
2HBr(g) + Cl₂(g) → 2HCI(g) + Br₂(0)
To analyze the reaction, first draw Lewis structures for all reactant and product molecules.
Draw the reaction using separate sketchers for each species.
• Separate multiple reactants and/or products using the + sign from the drop-down arrow.
. Separate reactants from products using the symbol from the drop-down menu.
Remember to include nonbonding valence electrons in your Lewis structures.
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Use the References to access important values if needed for this question.
Use average bond enthalpies (linked above) to calculate the enthalpy change for the following gas-phase reaction.
CH3OH(g) + HI(g) - CH31(g) + H₂O(g)
To analyze the reaction, first draw Lewis structures for all reactant and product molecules.
• Draw the reaction using separate sketchers for each species.
●
Separate multiple reactants and/or products using the + sign from the drop-down arrow.
●
Separate reactants from products using the → symbol from the drop-down menu.
• Remember to include nonbonding valence electrons in your Lewis structures.
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10. You're preparing for a camping trip. you see two different stoves you can pack for your trip to do
all your cooking. Which fuel would you prefer to carry?
One stove uses fuel propane.
The other stove uses naphtha (hexane) fuel.
Start by writing a balanced combustion equation for both of these reactions. Use either standard
enthalpies of formation or bond energies to determine the enthalpy changes for the combustion of
these two fuels. Then suggest which stove, the one that uses propane or the one that uses naphtha,
would you recommend to pack for your camping trip? Explain. (You may need more space for
your response).
Chapter 12 Solutions
Introductory Chemistry: A Foundation
Ch. 12.2 - use differences in electronegativity to account...Ch. 12.2 - trong>Exercise 12.1 For each of the following...Ch. 12.5 - ns have different radii than their parent atoms....Ch. 12.6 - trong>Exercise 12.2 Write the Lewis structure for...Ch. 12.7 - trong>Exercise 12.3 Ozone is a very important...Ch. 12.7 - trong>Exercise 12.4 Write the Lewis structures...Ch. 12.9 - u have seen that molecules with four electron...Ch. 12.9 - Prob. 12.5SCCh. 12 - sing only the periodic table, predict the most...Ch. 12 - rite the proper charges so that an alkali metal, a...
Ch. 12 - hat is meant by a chemical bond?Ch. 12 - hy do atoms form bonds with one another? What can...Ch. 12 - ow does a bond between Naand Cldiffer from a bond...Ch. 12 - n your own words, what is meant by the term...Ch. 12 - xplain the difference between ionic bonding and...Ch. 12 - rue or false? In general, a larger atom has a...Ch. 12 - hy is there an octet rule (and what does actet...Ch. 12 - Does a Lewis structure tell which electrons came...Ch. 12 - If lithium and fluorine react, which has more...Ch. 12 - In a bond between fluorine and iodine, which has...Ch. 12 - We use differences in electronegative to account...Ch. 12 - Prob. 14ALQCh. 12 - Why do we only the consider the valence electrons...Ch. 12 - How do we determine the total number of valence...Ch. 12 - What is the main idea in the valence shell...Ch. 12 - The molecules NH3andBF3have the same general...Ch. 12 - How do we deal with multiple bonds in VSEPR...Ch. 12 - In Section 12.10 of your text, the term “effective...Ch. 12 - Prob. 21ALQCh. 12 - Prob. 22ALQCh. 12 - Prob. 1QAPCh. 12 - Prob. 2QAPCh. 12 - hat sorts of elements react to form ionic...Ch. 12 - n general terms, what is a covalent bond?Ch. 12 - escribe the type of bonding that exists in the...Ch. 12 - Prob. 6QAPCh. 12 - he relative ability of an atom in a molecule to...Ch. 12 - hat does it mean to say that a bond is polar? Give...Ch. 12 - Prob. 9QAPCh. 12 - What factor determines the relative level of...Ch. 12 - In each of the following groups, which element is...Ch. 12 - In each of the following groups. which element is...Ch. 12 - On the basis. of the electronegativity values...Ch. 12 - On the basis of the electronegativity values given...Ch. 12 - Which of the following molecules contain polar...Ch. 12 - Which of the following molecules contain polar...Ch. 12 - On the basis of the electronegativity values given...Ch. 12 - On the basis of the electronegativity values given...Ch. 12 - Which brand in each of the following pairs has the...Ch. 12 - Which hand in each of the following pairs has less...Ch. 12 - What is a dipole moment? Give four examples of...Ch. 12 - Why is the presence of a dipole moment in the...Ch. 12 - In each of the following diatomic molecules, which...Ch. 12 - In each of the following diatomic molecules. which...Ch. 12 - For each of the following bonds, draw a figure...Ch. 12 - For each of the following bonds, draw a figure...Ch. 12 - For each of the following bonds, draw a figure...Ch. 12 - For each of the following bonds, draw a figure...Ch. 12 - What does it mean when we say that in forming...Ch. 12 - Prob. 30QAPCh. 12 - Nonmetals form negative ions by (losing/gaining)...Ch. 12 - Explain how the atoms in covalent molecules...Ch. 12 - Which simple ion would each of the following...Ch. 12 - Which simple ion would each of the following...Ch. 12 - For each of the following numbers of electrons,...Ch. 12 - Give the formula of a negative ion that would have...Ch. 12 - On the basis of their electron configurations,...Ch. 12 - On the basis of their electron configurations,...Ch. 12 - Name the noble gas atom that has the same electron...Ch. 12 - Atoms form ions so as to achieve electron...Ch. 12 - Prob. 41QAPCh. 12 - Describe in general terms the structure of ionic...Ch. 12 - Why are cations always smaller than the atoms from...Ch. 12 - Why are anions always larger than the atoms from...Ch. 12 - For each of the following pairs, indicate which...Ch. 12 - Prob. 46QAPCh. 12 - Prob. 47QAPCh. 12 - For each of the following pairs, indicate which is...Ch. 12 - Why are the valence electrons of an atom the only...Ch. 12 - Explain what the “duet" and “octet” rules are and...Ch. 12 - What type of structure must each atom in a...Ch. 12 - When elements in the second and third periods...Ch. 12 - How many electrons are involved when two atoms in...Ch. 12 - Prob. 54QAPCh. 12 - Write the simple Lewis structure for each of the...Ch. 12 - Write the simple Lewis structure for each of the...Ch. 12 - Give the total number of valence electrons in each...Ch. 12 - Give the total number of valence electrons in each...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Prob. 62QAPCh. 12 - The “Chemistry in Focus“ segment Broccoli—Miracle...Ch. 12 - The “Chemistry in Focus" segment Hiding Carbon...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - What is the geometric structure of the water...Ch. 12 - What is the geometric sanctum of the ammonia...Ch. 12 - What is the geometric structure of the boron...Ch. 12 - What is the geometric structure of the...Ch. 12 - Why is the geometric structure of a molecule...Ch. 12 - Prob. 74QAPCh. 12 - How is the structure around a given atom related...Ch. 12 - Why are all diatomic molecules linear, regardless...Ch. 12 - Although the valence electron pairs in ammonia...Ch. 12 - Although both the BF3and NF3molecules contain the...Ch. 12 - For the indicated atom in each of the following...Ch. 12 - Prob. 80QAPCh. 12 - Using the VSEPR theory, predict the molecular...Ch. 12 - Prob. 82QAPCh. 12 - Using the VSEPR theory, predict the molecular...Ch. 12 - Using the VSEPR theory, predict the molecular...Ch. 12 - For each of the following molecules or ions,...Ch. 12 - For each of the following molecules or ion....Ch. 12 - The “Chemistry in Focus" segment Taste—It's the...Ch. 12 - Prob. 88QAPCh. 12 - What is resonance? Give three examples of...Ch. 12 - Prob. 90APCh. 12 - The geometric arrangement of electron pairs around...Ch. 12 - Choose the bond that is the least polar. Explain...Ch. 12 - Prob. 93APCh. 12 - Prob. 94APCh. 12 - Prob. 95APCh. 12 - For each of the following pairs of elements,...Ch. 12 - On the basis of the electronegativity values given...Ch. 12 - Which of the following molecules contain polar...Ch. 12 - Prob. 99APCh. 12 - Prob. 100APCh. 12 - or each of the following bonds, draw a figure...Ch. 12 - Prob. 102APCh. 12 - Prob. 103APCh. 12 - Prob. 104APCh. 12 - hich noble gas has the same electron configuration...Ch. 12 - Prob. 106APCh. 12 - rite the Lewis structure for each of the following...Ch. 12 - Prob. 108APCh. 12 - rite a Lewis structure for each of the following...Ch. 12 - Prob. 110APCh. 12 - rite a Lewis structure for each of the following...Ch. 12 - Prob. 112APCh. 12 - hy is the molecular structure of H2Ononlinear,...Ch. 12 - Prob. 114APCh. 12 - sing the VSEPR theory, predict the molecular...Ch. 12 - Prob. 116APCh. 12 - or each of the following molecules, indicate the...Ch. 12 - Prob. 118APCh. 12 - Prob. 119APCh. 12 - Prob. 120APCh. 12 - Prob. 121APCh. 12 - Classify the bonding in each of the following...Ch. 12 - ompare the electronegativities of each pair of...Ch. 12 - Prob. 124CPCh. 12 - rrange the atoms and/or ions in the following...Ch. 12 - Prob. 126CPCh. 12 - Prob. 127CPCh. 12 - he formulas of several chemical substances are...Ch. 12 - Prob. 1CRCh. 12 - hat does temperature measure? Are the molecules in...Ch. 12 - Prob. 3CRCh. 12 - Prob. 4CRCh. 12 - Prob. 5CRCh. 12 - hat is the enthalpy change for a process? Is...Ch. 12 - Prob. 7CRCh. 12 - Prob. 8CRCh. 12 - Prob. 9CRCh. 12 - What is a driving force? Name two common and...Ch. 12 - Prob. 11CRCh. 12 - Methane, CH4, is the major component of natural...Ch. 12 - What is electronegative radiation? Give some...Ch. 12 - Prob. 14CRCh. 12 - Do atoms in excited states emit radiation...Ch. 12 - Prob. 16CRCh. 12 - Schrodinger and de Broglie suggested a...Ch. 12 - Describe the general characteristics of the first...Ch. 12 - Prob. 19CRCh. 12 - Describe the sublevels and orbitals that...Ch. 12 - Describe electron spin. How does electron spin...Ch. 12 - Prob. 22CRCh. 12 - List the order in which the orbitals are filled as...Ch. 12 - Prob. 24CRCh. 12 - Prob. 25CRCh. 12 - Prob. 26CRCh. 12 - What are the representative elements? In what...Ch. 12 - Prob. 28CRCh. 12 - Prob. 29CRCh. 12 - Prob. 30CRCh. 12 - Prob. 31CRCh. 12 - Prob. 32CRCh. 12 - Prob. 33CRCh. 12 - Prob. 34CRCh. 12 - Give evidence that ionic bonds are very strong....Ch. 12 - Prob. 36CRCh. 12 - Prob. 37CRCh. 12 - For three simple molecules of your own choice,...Ch. 12 - Prob. 39CRCh. 12 - Prob. 40CRCh. 12 - Prob. 41CRCh. 12 - Prob. 42CRCh. 12 - Prob. 43CRCh. 12 - Prob. 44CRCh. 12 - Prob. 45CRCh. 12 - Prob. 46CR
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- hat does temperature measure? Are the molecules in a beaker of warm water moving at the same speed as the molecules in a beaker of cold water? Explain? What is heat? Is heat the same as temperature?arrow_forwardWhat main factors control the magnitude of lattice energies? Give a specific example of a compound that should have a high lattice energy, and explain why its lattice energy is high.arrow_forwardBond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forward
- Compare your answers from parts a and b of Exercise 69 of Chapter 3 with H values calculated for each reaction using standard enthalpies of formation in Appendix 4. Do enthalpy changes calculated from bond energies give a reasonable estimate of the actual values?arrow_forwardUsing the bond energies in Table 7.2, determine the approximate enthalpy change for each of the following reactions: (a) Cl2(g)+3F2(g)2ClF3(g) (b) H2C=CH2(g)+H2(g)H3CCH3(g) (c) 2C2H6(g)+7O2(g)4CO2(g)+6H2O(g) .arrow_forwardWrite the Lewis structure for nitrosyl fluoride, FNO. Using only a periodic table, identify (a) which is the longer bond. (b) which is the stronger bond. (c) which is the more polar bond.arrow_forward
- Write all resonance structures of chlorobenzene, C6H5Cl, a molecule with the same cyclic structure as benzene. In all structures, keep the CCl bond as a single bond. Which resonance structures are the most important?arrow_forwardUse the References to access important values if needed for this question. Use average bond enthalpies (linked above) to calculate the enthalpy change for the following gas-phase reaction. Br₂(g) + Cl₂(g) →→→→→→2BrCl(g) To analyze the reaction, first draw Lewis structures for all reactant and product molecules. • Draw the reaction using separate sketchers for each species. • Separate multiple reactants and/or products using the + sign from the drop-down arrow. • Separate reactants from products using the symbol from the drop-down menu. . Remember to include nonbonding valence electrons in your Lewis structures. AHreaction CO Submit Answer kj Referen ChemDoodle [ ] کر remove te Enthalpy of Reaction Using Bond Energies - Draw Lewis: This is group attempt 1 of 10 Autosaved at 9:15 PMarrow_forwardChemistry not physicsarrow_forward
- In chemical reactions, heat is converted into chemical energy (the potential energy stored in chemical bonds) or vice versa. Bond energy is the energy required to break one mole of the bond in the gas phase. Since it takes energy to break a bond, bond energies are always positive. Conversely, energy is released when bonds are formed. Thus, the enthalpy change for a reaction can be approximated from Part A Calculate the bond energy per mole for breaking all the bonds in methane, CH4. ΔΗ Σ(ΔΗ breaking) + Σ(ΔΗ forming) Express your answer to four significant figures and include the appropriate units. where H represents bond energies for the breaking (positive bond energy) or forming (negative bond energy) of a bond and Hrxn represents the overall enthalpy for the • View Available Hint(s) reaction. Use the table to answer questions about bond energies. HẢ Bond energy Bond (kJ/mol ) Value Units AHCH, = C-C 347 C=C 611 Submit Сн 414 C-O 360 Part B C=OinCO2 799 O-0 142 Calculate the bond…arrow_forwardIn an ionic compound, the size of the ions affects the internuclear distance (the distance between the centers of adjacent ions), which affects lattice energy (a measure of the attractive force holding those ions together). Based on ion sizes, rank these compounds of their expected lattice energy. Note: Many sources define lattice energies as negative values. Please rank by magnitude and ignore the sign. |Lattice energy| = absolute value of the lattice energy. MgCl2, MgBr2, MgI2, MgF2 Rank from greatest lattice energt (strongest bonds) to least lattice energy (weakest bonds).arrow_forwardPlease answer both questions as they are calculated together but just a heads up they are different questions. Thank you for helping mearrow_forward
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