Chemistry In Focus
Chemistry In Focus
6th Edition
ISBN: 9781305084476
Author: Tro, Nivaldo J., Neu, Don.
Publisher: Cengage Learning
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Chapter 12, Problem 3E
Interpretation Introduction

Interpretation:

The differences among gases, liquids and solids from a molecular viewpoint are to be explained.

Concept Introduction:

Intermolecular forces or cohesive forces keep the molecules or atoms combined together.

Intermolecular forces depend upon the types of molecules or atoms present in the substance and the distance of separation between them.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Chapter 12 Solutions

Chemistry In Focus

Ch. 12 - A representation of liquid water is shown below....Ch. 12 - Prob. 3SCCh. 12 - Prob. 4SCCh. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Why does sweating cool the human body?Ch. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Explain the hydrologic cycle.Ch. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - How does a water softener work?Ch. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - What is the SDWA?Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Explain the concerns that groups like the EWG or...Ch. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Which compound would you expect to have the...Ch. 12 - Which compound would you expect to have the...Ch. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Classify each molecule as polar or nonpolar:...Ch. 12 - Classify each molecule as polar or nonpolar:...Ch. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - How many grams of sucrose (C12H22O11) are present...Ch. 12 - How many grams of glucose (C6H12O6) are present in...Ch. 12 - Prob. 41ECh. 12 - How many grams of NaF are present in 4.5 L of a...Ch. 12 - A 250-g sample of hard water contains...Ch. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58E
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