Chemistry In Focus
6th Edition
ISBN: 9781305084476
Author: Tro, Nivaldo J., Neu, Don.
Publisher: Cengage Learning
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Chapter 12, Problem 36E
Interpretation Introduction
Interpretation:
The substance that is smelled first when a vial of perfume is opened, and the substance that can be smelled if the mixture is left on the skin for several hours are to be determined.
Concept Introduction:
A mixture that is composed of different molecules with a different range of intermolecular forces is called a perfume.
The molecules that have a high vapor pressure can vaporize easily and are called volatile liquids, whereas the molecules that have a low vapor pressure cannot vaporize easily and are called non-volatile liquids.
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LTS
Solid:
AT=Te-Ti
Trial 1
Trial 2
Trial 3
Average
ΔΗ
Mass water, g
24.096
23.976
23.975
Moles of solid, mol
0.01763
001767
0101781
Temp. change, °C
2.9°C
11700
2.0°C
Heat of reaction, J
-292.37J -170.473
-193.26J
AH, kJ/mole
16.58K 9.647 kJ 10.85 kr
16.58K59.64701
KJ
mol
12.35k
Minimum AS,
J/mol K
41.582
mol-k
Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn &
Show your calculations for:
AH in J and then in kJ/mole for Trial 1:
qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J
qsin =
qrxn =
292.35 292.37J
AH in J = 292.375 0.2923kJ
0.01763m01
=1.65×107
AH in kJ/mol =
=
16.58K
0.01763mol
mol
qrx
Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con
Kelvin.)
AS=AHIT
(1.65×10(9.64×103) + (1.0
Jimai
For the compound: C8H17NO2
Use the following information to come up with a plausible structure:
8
This compound has "carboxylic acid amide" and ether functional groups.
The peaks at 1.2ppm are two signals that are overlapping one another.
One of the two signals is a doublet that represents 6 hydrogens; the
other signal is a quartet that represents 3 hydrogens.
Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling
point, choose 2 next to the substance with the next highest boiling point, and so on.
substance
C
D
chemical symbol,
chemical formula
or Lewis structure.
CH,-N-CH,
CH,
H
H 10: H
C-C-H
H H H
Cale
H 10:
H-C-C-N-CH,
Bri
CH,
boiling point
(C)
Сен
(C) B
(Choose
Chapter 12 Solutions
Chemistry In Focus
Ch. 12 - Prob. 12.1YTCh. 12 - Which of the following molecules are polar?...Ch. 12 - Which of the following molecules do you expect to...Ch. 12 - Prob. 12.4YTCh. 12 - Prob. 12.5YTCh. 12 - Prob. 12.6YTCh. 12 - Prob. 12.7YTCh. 12 - Prob. 12.8YTCh. 12 - Prob. 12.9YTCh. 12 - Substance A is composed of molecules that have...
Ch. 12 - A representation of liquid water is shown below....Ch. 12 - Prob. 3SCCh. 12 - Prob. 4SCCh. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Why does sweating cool the human body?Ch. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Explain the hydrologic cycle.Ch. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - How does a water softener work?Ch. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - What is the SDWA?Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Explain the concerns that groups like the EWG or...Ch. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Which compound would you expect to have the...Ch. 12 - Which compound would you expect to have the...Ch. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Classify each molecule as polar or nonpolar:...Ch. 12 - Classify each molecule as polar or nonpolar:...Ch. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - How many grams of sucrose (C12H22O11) are present...Ch. 12 - How many grams of glucose (C6H12O6) are present in...Ch. 12 - Prob. 41ECh. 12 - How many grams of NaF are present in 4.5 L of a...Ch. 12 - A 250-g sample of hard water contains...Ch. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58E
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