General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Chapter 12, Problem 34P
Consider compounds A-E and label each pair of compounds as identical molecules, constitutional isomer, or not isomers of each other; (a) A and B; (b) A and C; (c) B and D (d) D and E; (e) B and E.
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1.
Draw 5 constitutional isomers of compounds with molecular formula CaHsO2
using expanded or condensed structure.
(a)
Butanal (C4H&O) has eight H atoms. Suppose that any of these H atoms can be replaced by a Cl atom to yield a molecule
with the formula C4H¬CIO. (a) Identify two H atoms where this substitution would yield constitutional isomers of C4H7CIO;
(b) enantiomers of C4H;CIO; (c) conformers of C4H;CIO.
H.
H
H
H
нн
H
Butanal
O=U
Draw the ve constitutional isomers having molecular formula C6H14.
Chapter 12 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 12.1 - How many hydrogen atoms are present in each...Ch. 12.1 - Which formulas represent acyclic alkanes and which...Ch. 12.2 - Are the compounds in each pair constitutional...Ch. 12.2 - Draw two isomers with molecular formula C6H14 that...Ch. 12.2 - Prob. 12.3PCh. 12.2 - Classify the carbon atoms in each compound as 1°,...Ch. 12.2 - Prob. 12.4PCh. 12.2 - Prob. 12.5PCh. 12.2 - Prob. 12.6PCh. 12.2 - Prob. 12.7P
Ch. 12.2 - Prob. 12.8PCh. 12.2 - Prob. 12.9PCh. 12.4 - Give the IUPAC name for each compound.Ch. 12.4 - Prob. 12.10PCh. 12.4 - Give the IUPAC name for each compound....Ch. 12.4 - Prob. 12.5PPCh. 12.4 - Prob. 12.6PPCh. 12.4 - Prob. 12.12PCh. 12.5 - Prob. 12.13PCh. 12.5 - Prob. 12.14PCh. 12.5 - Give the IUPAC name for each compound.Ch. 12.5 - Prob. 12.15PCh. 12.7 - Answer the following questions about pentane...Ch. 12.7 - Prob. 12.17PCh. 12.7 - Prob. 12.18PCh. 12.8 - Prob. 12.19PCh. 12.9 - Prob. 12.20PCh. 12.9 - Prob. 12.21PCh. 12.9 - Prob. 12.22PCh. 12 - Prob. 23PCh. 12 - Prob. 24PCh. 12 - The waxy coating on the surface of apple skins...Ch. 12 - Prob. 26PCh. 12 - Classify each carbon as 1°, 2°, 3°, or 4°. a....Ch. 12 - Give the structure of an alkane that fits each...Ch. 12 - Prob. 29PCh. 12 - Label each pair of compounds as constitutional...Ch. 12 - Consider compounds A, B, and C. Label each pair of...Ch. 12 - Consider compounds D,E, and F. Label each pair of...Ch. 12 - Prob. 33PCh. 12 - Consider compounds A-E and label each pair of...Ch. 12 - Draw structures that fit the following...Ch. 12 - Draw the five constitutional isomers having...Ch. 12 - Prob. 37PCh. 12 - Prob. 38PCh. 12 - Draw the five constitutional isomers that have...Ch. 12 - Pristane is a high molecular weight alkane found...Ch. 12 - Give the IUPAC name for each of the five...Ch. 12 - Give the IUPAC name for each of the five cyclic...Ch. 12 - Give the IUPAC name for each compoundCh. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each compound. c....Ch. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each cycloalkane.Ch. 12 - Give the IUPAC name for each ccycloalkane.Ch. 12 - Prob. 49PCh. 12 - Give the structure corresponding to each IUPAC...Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Draw three constitutional isomers having molecular...Ch. 12 - Draw four constitutional isomers having molecular...Ch. 12 - Draw a skeletal structure for each compound octane...Ch. 12 - Convert each compound to a skeletal structure CH3(...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Which compound in each pair has the higher melting...Ch. 12 - Which compound in each pair has the higher boiling...Ch. 12 - Branching in an alkane chain decreases surface...Ch. 12 - Explain why the boiling points of heptane [CH3( CH...Ch. 12 - Explain why hexane is more soluble in...Ch. 12 - Mineral oil and Vaseline are both mixtures of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the incomplete...Ch. 12 - Prob. 68PCh. 12 - Prob. 69PCh. 12 - Prob. 70PCh. 12 - Prob. 71PCh. 12 - Prob. 72PCh. 12 - Prob. 73PCh. 12 - Prob. 74PCh. 12 - Prob. 75PCh. 12 - Prob. 76PCh. 12 - Prob. 77PCh. 12 - Prob. 78PCh. 12 - Prob. 79PCh. 12 - A major component of animal fat is tristearin, (a)...Ch. 12 - Answer the following questions about the alkane...Ch. 12 - Prob. 82PCh. 12 - Answer the questions in Problem 12.81 for the...Ch. 12 - Prob. 84PCh. 12 - Prob. 85CPCh. 12 - Draw the structure of the 12 constitutional...Ch. 12 - Cyclopentane has a higher boiling point than...Ch. 12 - Prob. 88CP
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- 7. Which pair of compounds are isomers? A. C4H4 & C4H8 С. CН:СH2CHCHCIz & CHCH2CH-CH2CI В. СН:СH-CHОН & CH;СH2CООН D. CH,CH2COОCH3 & CH;COОСH-CHзarrow_forward8c) What is the relation between the following pairs H₂C O a. Cis-Trans O b. Structural O c. not isomers O d. Identical H3C CH3 H₂CH.arrow_forwardIn the six following sets, which pairs of structural formulas represent constitutional isomers?arrow_forward
- Draw structures that fit each description and name the functional group in each molecule: (a) two constitutional isomers with molecular formula C5H10O that contain different functional groups; (b) two constitutional isomers with molecular formula C6H10O that contain the same functional group.arrow_forwardDraw the ve constitutional isomers that have molecular formula C5H10 and contain one ring.arrow_forwardDraw three constitutional isomers having molecular formula C7H14 that contains a five-membered ring and two methyl groups bonded to that ring.arrow_forward
- HO₂ H COOH COOH V POH HOT COOH cooff VI Ho HO COOH COOH VI H H COOH COOH VIIL OH OH Question: In the structures / examples abovke Identify V, VI, VII and VIII as Identical enantiomers, ciastereomes, stereo/cumers and/or structural isomers (there are 6 pairs 7 Comp eand to discover te I&T I TEN TEM TIMIN).arrow_forwardJj.81.arrow_forwardc) Show four (4) isomers that have chemical formula of C7H₁1CIO.arrow_forward
- II. Draw all isomers of C,H,Br and name them using IUPAC Conventionarrow_forward3) Consider the structures shown below and: a) Cross the ones that are not constitutional isomers with molecular formula C5H10O. HO OH OH OH OH OH OH b) Draw two constitutional isomers with molecular formula C5H10O that are not represented above.arrow_forwardJj.12.arrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License