Concept explainers
(a)
Interpretation: To identify whether the statement “the mitochondrion inner membrane is highly permeable to small molecules” about mitochondrion structural characteristics is true or false.
Concept introduction: In eukaryotic cells, the water-based material which is present between the nucleus and cell membrane of a cell is known as cytoplasm. The various small structures are present in the cytoplasm which perform a particular function of the cell and are known as organelles.
A mitochondrion is an organelle which is responsible for the production of energy which is required for the completion of various functions of the body.
(b)
Interpretation: To identify whether the statement “mitochondria have a sausage-like shape” about mitochondrion structural characteristics is true or false.
Concept introduction: In eukaryotic cells, the water-based material which is present between the nucleus and cell membrane of a cell is known as cytoplasm. The various small structures are present in the cytoplasm which perform a particular function of the cell and are known as organelles.
A mitochondrion is an organelle which is responsible for the production of energy which is required for the completion of various functions of the body.
(c)
Interpretation: To identify whether the statement “cristae are small folds on the inner membrane” about mitochondrion structural characteristics is true or false.
Concept introduction: In eukaryotic cells, the water-based material which is present between the nucleus and cell membrane of a cell is known as cytoplasm. The various small structures are present in the cytoplasm which perform a particular function of the cell and are known as organelles.
A mitochondrion is an organelle which is responsible for the production of energy which is required for the completion of various functions of the body.
(d)
Interpretation: To identify whether the statement “the inner most area of a mitochondrion is called the matrix” about mitochondrion structural characteristics is true or false.
Concept introduction: In eukaryotic cells, the water-based material which is present between the nucleus and cell membrane of a cell is known as cytoplasm. The various small structures are present in the cytoplasm which perform a particular function of the cell and are known as organelles.
A mitochondrion is an organelle which is responsible for the production of energy which is required for the completion of various functions of the body.

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Chapter 12 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
- (a) Draw the structures of A and B in the following reaction. (i) NaNH2, NH3(1) A + B (ii) H3O+arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardConsider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forward
- In a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardGiven the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forward
- Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardk₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forwardk₁ Given the reaction R₂ R + R, indicate k-1 (A). the rate law with respect to R2: (B). the rate law with respect to R: d[R₂] dt d[R] dtarrow_forward
- Given the reaction R+ Q → P, indicate (A). the rate law with respect to P: (B). the rate law with respect to R: (C). the rate law with respect to Q: d[P] dt d[R] dt d[Q] dtarrow_forwardThe reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.arrow_forwarda. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?arrow_forward
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