EBK ORGANIC AND BIOLOGICAL CHEMISTRY
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
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Chapter 12, Problem 12.50EP

(a)

Interpretation Introduction

Interpretation: To identify the substances malate, oxaloacetate, fumarate, αketoglutarate, and citrate that contains six carbon atoms.

Concept introduction: There are a number of metabolic reaction that occur in the human body for completion of functions. During these metabolic reactions, the various metabolic intermediates are formed for the short time to complete the reactions. Polyfunctional carboxylate ions are also the metabolic intermediate formed during metabolic pathways.

Polyfunctional carboxylate ions act as a substrate in the metabolic pathways and can be divided into two parts depending upon the parent carboxylic acid.

The first class consists of malate, oxaloacetate and fumarate ion which are derivative of succinic acid.

The chemical structures for carboxylate ion derived from succinic acid are as follows:

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 12, Problem 12.50EP , additional homework tip  1

The second class consists of αketoglutarate and citrate ion which is a derivative of glutaric acid.

The chemical structures for carboxylate ion derived from glutaric acid are as follows:

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 12, Problem 12.50EP , additional homework tip  2

(b)

Interpretation Introduction

Interpretation: To identify the substances malate, oxaloacetate, fumarate, αketoglutarate, and citrate that contains a hydroxy functional group.

Concept introduction: There are a number of metabolic reaction that occur in the human body for completion of functions. During these metabolic reactions, the various metabolic intermediates are formed for the short time to complete the reactions. Polyfunctional carboxylate ions are also the metabolic intermediate formed during metabolic pathways.

Polyfunctional carboxylate ions act as a substrate in the metabolic pathways and can be divided into two parts depending upon the parent carboxylic acid.

The first class consists of malate, oxaloacetate and fumarate ion which are derivative of succinic acid.

The chemical structures for carboxylate ion derived from succinic acid are as follows:

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 12, Problem 12.50EP , additional homework tip  3

The second class consists of αketoglutarate and citrate ion which is a derivative of glutaric acid.

The chemical structures for carboxylate ion derived from glutaric acid are as follows:

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 12, Problem 12.50EP , additional homework tip  4

(c)

Interpretation Introduction

Interpretation: To identify the substances malate, oxaloacetate, fumarate, αketoglutarate, and citrate that has a charge of 3.

Concept introduction: There are a number of metabolic reaction that occur in the human body for completion of functions. During these metabolic reactions, the various metabolic intermediates are formed for the short time to complete the reactions. Polyfunctional carboxylate ions are also the metabolic intermediate formed during metabolic pathways.

Polyfunctional carboxylate ions act as a substrate in the metabolic pathways and can be divided into two parts depending upon the parent carboxylic acid.

The first class consists of malate, oxaloacetate and fumarate ion which are derivative of succinic acid.

The chemical structures for carboxylate ion derived from succinic acid are as follows:

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 12, Problem 12.50EP , additional homework tip  5

The second class consists of αketoglutarate and citrate ion which is a derivative of glutaric acid.

The chemical structures for carboxylate ion derived from glutaric acid are as follows:

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 12, Problem 12.50EP , additional homework tip  6

(d)

Interpretation Introduction

Interpretation: To identify the substances malate, oxaloacetate, fumarate, αketoglutarate, and citrate that are glutaric acid derivative.

Concept introduction: There are a number of metabolic reaction that occur in the human body for completion of functions. During these metabolic reactions, the various metabolic intermediates are formed for the short time to complete the reactions. Polyfunctional carboxylate ions are also the metabolic intermediate formed during metabolic pathways.

Polyfunctional carboxylate ions act as a substrate in the metabolic pathways and can be divided into two parts depending upon the parent carboxylic acid.

The first class consists of malate, oxaloacetate and fumarate ion which are derivative of succinic acid.

The chemical structures for carboxylate ion derived from succinic acid are as follows:

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 12, Problem 12.50EP , additional homework tip  7

The second class consists of αketoglutarate and citrate ion which is a derivative of glutaric acid.

The chemical structures for carboxylate ion derived from glutaric acid are as follows:

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 12, Problem 12.50EP , additional homework tip  8

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Chapter 12 Solutions

EBK ORGANIC AND BIOLOGICAL CHEMISTRY

Ch. 12.3 - Which of the following statements concerning...Ch. 12.4 - Prob. 1QQCh. 12.4 - Prob. 2QQCh. 12.5 - Prob. 1QQCh. 12.5 - Prob. 2QQCh. 12.5 - Prob. 3QQCh. 12.6 - Which of the following occurs in the second stage...Ch. 12.6 - Which of the following stages in the biochemical...Ch. 12.6 - Prob. 3QQCh. 12.7 - Prob. 1QQCh. 12.7 - Prob. 2QQCh. 12.7 - Prob. 3QQCh. 12.7 - How many NADH and FADH2 molecules are produced,...Ch. 12.7 - Which of the following citric acid cycle...Ch. 12.7 - In which of the following listings of citric acid...Ch. 12.8 - Which of the following is a fuel for the electron...Ch. 12.8 - Which of the following is a mobile electron...Ch. 12.8 - What is the substrate that initially interacts...Ch. 12.8 - The number of fixed enzyme sites in the electron...Ch. 12.8 - Prob. 5QQCh. 12.8 - In which step in the electron transport chain does...Ch. 12.9 - Prob. 1QQCh. 12.9 - Prob. 2QQCh. 12.9 - Prob. 3QQCh. 12.10 - Prob. 1QQCh. 12.10 - Prob. 2QQCh. 12.11 - Prob. 1QQCh. 12.11 - Prob. 2QQCh. 12.11 - Prob. 3QQCh. 12.12 - How many different B vitamins participate in the...Ch. 12.12 - Prob. 2QQCh. 12 - Classify anabolism and catabolism as synthetic or...Ch. 12 - Classify anabolism and catabolism as...Ch. 12 - What is a metabolic pathway?Ch. 12 - Prob. 12.4EPCh. 12 - Classify each of the following processes as...Ch. 12 - Prob. 12.6EPCh. 12 - Prob. 12.7EPCh. 12 - Prob. 12.8EPCh. 12 - Prob. 12.9EPCh. 12 - Indicate whether each of the following statements...Ch. 12 - Prob. 12.11EPCh. 12 - Prob. 12.12EPCh. 12 - Prob. 12.13EPCh. 12 - Prob. 12.14EPCh. 12 - Prob. 12.15EPCh. 12 - Prob. 12.16EPCh. 12 - Prob. 12.17EPCh. 12 - Prob. 12.18EPCh. 12 - Prob. 12.19EPCh. 12 - Prob. 12.20EPCh. 12 - Prob. 12.21EPCh. 12 - Prob. 12.22EPCh. 12 - Prob. 12.23EPCh. 12 - Write a generalized chemical equation, containing...Ch. 12 - Prob. 12.25EPCh. 12 - Prob. 12.26EPCh. 12 - Prob. 12.27EPCh. 12 - Prob. 12.28EPCh. 12 - Prob. 12.29EPCh. 12 - Prob. 12.30EPCh. 12 - Prob. 12.31EPCh. 12 - Prob. 12.32EPCh. 12 - Prob. 12.33EPCh. 12 - Prob. 12.34EPCh. 12 - What identical structural subunits do the...Ch. 12 - Prob. 12.36EPCh. 12 - Prob. 12.37EPCh. 12 - Prob. 12.38EPCh. 12 - Prob. 12.39EPCh. 12 - Prob. 12.40EPCh. 12 - Prob. 12.41EPCh. 12 - Prob. 12.42EPCh. 12 - Classify each of the following molecules as (1) an...Ch. 12 - Prob. 12.44EPCh. 12 - Prob. 12.45EPCh. 12 - Prob. 12.46EPCh. 12 - Prob. 12.47EPCh. 12 - Prob. 12.48EPCh. 12 - Prob. 12.49EPCh. 12 - Prob. 12.50EPCh. 12 - Prob. 12.51EPCh. 12 - Prob. 12.52EPCh. 12 - Prob. 12.53EPCh. 12 - Prob. 12.54EPCh. 12 - Prob. 12.55EPCh. 12 - Prob. 12.56EPCh. 12 - Prob. 12.57EPCh. 12 - Prob. 12.58EPCh. 12 - List, by name, the four general stages of the...Ch. 12 - Which, by name, of the four general stages of the...Ch. 12 - Prob. 12.61EPCh. 12 - Prob. 12.62EPCh. 12 - Prob. 12.63EPCh. 12 - Prob. 12.64EPCh. 12 - Prob. 12.65EPCh. 12 - Prob. 12.66EPCh. 12 - Prob. 12.67EPCh. 12 - Prob. 12.68EPCh. 12 - Prob. 12.69EPCh. 12 - Prob. 12.70EPCh. 12 - Prob. 12.71EPCh. 12 - Prob. 12.72EPCh. 12 - Prob. 12.73EPCh. 12 - Prob. 12.74EPCh. 12 - Prob. 12.75EPCh. 12 - Prob. 12.76EPCh. 12 - Prob. 12.77EPCh. 12 - Prob. 12.78EPCh. 12 - Prob. 12.79EPCh. 12 - Prob. 12.80EPCh. 12 - Prob. 12.81EPCh. 12 - Prob. 12.82EPCh. 12 - Prob. 12.83EPCh. 12 - Prob. 12.84EPCh. 12 - Prob. 12.85EPCh. 12 - Prob. 12.86EPCh. 12 - Prob. 12.87EPCh. 12 - Prob. 12.88EPCh. 12 - Prob. 12.89EPCh. 12 - Indicate whether each of the following changes...Ch. 12 - Prob. 12.91EPCh. 12 - Prob. 12.92EPCh. 12 - Prob. 12.93EPCh. 12 - Prob. 12.94EPCh. 12 - Prob. 12.95EPCh. 12 - Prob. 12.96EPCh. 12 - Prob. 12.97EPCh. 12 - Prob. 12.98EPCh. 12 - Prob. 12.99EPCh. 12 - Prob. 12.100EPCh. 12 - Prob. 12.101EPCh. 12 - Prob. 12.102EPCh. 12 - Prob. 12.103EPCh. 12 - Prob. 12.104EPCh. 12 - Prob. 12.105EPCh. 12 - Prob. 12.106EPCh. 12 - Prob. 12.107EPCh. 12 - Prob. 12.108EPCh. 12 - Prob. 12.109EPCh. 12 - Prob. 12.110EPCh. 12 - Prob. 12.111EPCh. 12 - Prob. 12.112EPCh. 12 - Prob. 12.113EPCh. 12 - Prob. 12.114EPCh. 12 - Prob. 12.115EPCh. 12 - Prob. 12.116EPCh. 12 - Prob. 12.117EPCh. 12 - Prob. 12.118EPCh. 12 - Prob. 12.119EPCh. 12 - Prob. 12.120EPCh. 12 - Prob. 12.121EPCh. 12 - Prob. 12.122EPCh. 12 - Prob. 12.123EPCh. 12 - Prob. 12.124EPCh. 12 - Prob. 12.125EPCh. 12 - Prob. 12.126EPCh. 12 - Prob. 12.127EPCh. 12 - Prob. 12.128EPCh. 12 - Indicate whether or not each of the following B...Ch. 12 - Prob. 12.130EPCh. 12 - Prob. 12.131EPCh. 12 - Prob. 12.132EP
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