In Exercise 96 in Chapter 8, the pressure of CO 2 in a bottle of sparkling wine was calculated assuming that the CO 2 was insoluble in water. This was a bad assumption. Redo this problem by assuming that CO 2 obeys Henry’ s law. Use the data given in that problem to calculate the partial pressure of CO 2 in the gas phase and the solubility of CO 2 in the wine at 25°C. The Henry’s law constant for CO 2 is 3.1 × w −2 mol/L · atm at 25°C with Henry’s law in the form C = kP, where C is the concentration of the gas in mol/L.
In Exercise 96 in Chapter 8, the pressure of CO 2 in a bottle of sparkling wine was calculated assuming that the CO 2 was insoluble in water. This was a bad assumption. Redo this problem by assuming that CO 2 obeys Henry’ s law. Use the data given in that problem to calculate the partial pressure of CO 2 in the gas phase and the solubility of CO 2 in the wine at 25°C. The Henry’s law constant for CO 2 is 3.1 × w −2 mol/L · atm at 25°C with Henry’s law in the form C = kP, where C is the concentration of the gas in mol/L.
Solution Summary: The author explains how Henry's law gives the relationship between the pressure of the gas and the concentration of gas dissolved.
In Exercise 96 in Chapter 8, the pressure of CO2 in a bottle of sparkling wine was calculated assuming that the CO2 was insoluble in water. This was a bad assumption. Redo this problem by assuming that CO2 obeys Henry’ s law. Use the data given in that problem to calculate the partial pressure of CO2 in the gas phase and the solubility of CO2 in the wine at 25°C. The Henry’s law constant for CO2 is 3.1 × w−2 mol/L · atm at 25°C with Henry’s law in the form C = kP, where C is the concentration of the gas in mol/L.
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
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