Concept explainers
In terms of Raoult’s law, distinguish between an ideal liquid-liquid solution and a nonideal liquid-liquid solution. lf a solution is ideal, what is true about ∆Hsoln, ∆T for the solution formation, and the interactive forces within the pure solute and pure solvent as compared to the interactive forces within the solution? Give an example of an ideal solution. Answer the previous two questions for solutions that exhibit either negative or positive deviations from Raoult’s law.
Trending nowThis is a popular solution!
Chapter 11 Solutions
Chemistry with Access Code, Hybrid Edition
Additional Science Textbook Solutions
Human Physiology: An Integrated Approach (8th Edition)
Organic Chemistry
HUMAN ANATOMY
Fundamentals Of Thermodynamics
Cosmic Perspective Fundamentals
Human Biology: Concepts and Current Issues (8th Edition)
- What would be the freezing point of a solution formed by adding 1.0 mole of glucose (a molecular compound) to the following amounts of water? a. 250 g (0.25 kg) b. 500 g (0.500 kg) c. 1000 g (1.000 kg) d. 2000 g (2.000 kg)arrow_forwardA forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?arrow_forwardDefine the terms in Raoults law. Figure 10-9 illustrates the net transfer of water molecules from pure water to an aqueous solution of a nonvolatile solute. Explain why eventually all of the water from the beaker of pure water will transfer to the aqueous solution. If the experiment illustrated in Fig. 10-9 was performed using a volatile solute, what would happen? How do you calculate the total vapor pressure when both the solute and solvent are volatile?arrow_forward
- Freezing point depression is one means of determining the molar mass of a compound. The freezing point depression constant of benzene is 5.12 C/m. a. When a 0.503 g sample of the white crystalline dimer is dissolved in 10.0 g benzene, the freezing point of benzene is decreased by 0542 C. Verify that the molar mass of the dimer is 475 g/mol when determined by freezing point depression. Assume no dissociation of the dimer occurs. b. The correct molar mass of the dimer is 487 g/mol. Explain why the dissociation equilibrium causes the freezing point depression calculation to yield a lower molar mass for the dimer.arrow_forwardThe vapor pressures of several solutions of water-propanol (CH3CH2CH2OH) were determined at various compositions, with the following data collected at 45C: H2O Vapor pressure(torr) 0 74.0 0.15 77.3 0.37 80.2 0.54 81.6 0.69 80.6 0.83 78.2 1.00 71.9 a. Are solutions of water and propanol ideal? Explain. b. Predict the sign of Hsoln for water-propanol solutions. c. Are the interactive forces between propanol and water molecules weaker than, stronger than, or equal to the interactive forces between the pure substances? Explain. d. Which of the solutions in the data would have the lowest normal boiling point?arrow_forwardVapor-pressure lowering is a colligative property, as are freezing-point depression and boiling-point elevation. What is a colligative property? Why is the freezing point depressed for a solution as compared to the pure solvent? Why is the boiling point elevated for a solution as compared to the pure solvent? Explain how to calculate T for a freezing-point depression problem or a boiling-point elevation problem. Of the solvents listed in Table 10-5, which would have the largest freezing-point depression for a 0.50 molal solution? Which would have the smallest boiling-point elevation for a 0.50 molal solution? A common application of freezing-point depression and boiling-point elevation experiments is to provide a means to calculate the molar mass of a nonvolatile solute. What data are needed to calculate the molar mass of a nonvolatile solute? Explain how you would manipulate these data to calculate the molar mass of the nonvolatile solute.arrow_forward
- A 1.40-g sample of polyethylene, a common plastic, is dissolved in enough organic solvent to give 100.0 mL of solution. What is the average molar mass of the polymer if the measured osmotic pressure of the solution is 1.86 mm Hg at 25 C?arrow_forwardBradykinin is a small peptide (9 amino acids; 1060 g/mol) that lowers blood pressure by causing blood vessels to dilate. What is the osmotic pressure of a solution of this protein at 20 C if 0.033 g of the peptide is dissolved in water to give 50.0 mL of solution?arrow_forwardWhich solute has the greatest effect on the boiling pointof 1.00 kg of water: 50.0 g of strontium chloride (SrCl2) or 150.0 g of carbon tetrachloride (CCl4) ? Justify youranswer.arrow_forward
- What is the freezing point and normal boiling point of a solution made by adding 39 mL of acetone, C3H6O, to 225 mL of water? The densities of acetone and water are 0.790 g/cm3 and 1.00 g/cm3, respectively.arrow_forwarda. Use the following data to calculate the enthalpy of hydration for calcium chloride and calcium iodide. Lattice Energy Hsoln CaCl2(s) 2247kj/mol 46kj/mol Cal2(s) 2059kj/mol 104kj/mol b. Based on your answers to part a, which ion, Cl or I, is more strongly attracted to water?arrow_forwardUrea, (NH2)2CO, has been used to melt ice from sidewalks, because the use of salt is harmful to plants. If the saturated aqueous solution contains 41% urea by mass, what is the freezing point? (The answer will be approximate, because the equation in the text applies accurately only to dilute solutions.)arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning