
Concept explainers
Interpretation:
The amount of reagents required and range of osmotic pressure has to be calculated.
Concept Introduction:
The mass of the compound is calculated by taking the products of molar mass of the compound to the given mass. The mass of compound can be given by,
Mass of compound(in grams)=Molar mass (in g)×Given mass(in g)

Answer to Problem 108AE
To calculate the mass of individual elements
Explanation of Solution
Mass of Sodium = 285-315 mg
Mass of Potassium = 14.1-17.3 mg
Mass of Calcium = 4.9-6.0 mg
Mass of Chlorine = 368-408 mg
Mass of Lactate = 231-261 mg
To calculate the mass of individual elements
Molar mass of Sodium lactate = 112.06 mg
Molar mass of Lactate = 89.07 mg
Molar mass of CaCl2.2H2O= 147.01 mg
Molecular mass of Calcium = 40.08 mg
Molar mass of KCl= 74.55 mg
Molecular weight of Potassium = 39.10 mg
Molar mass of NaCl = 58.44 mg
Molecular mass of Sodium= 22.99 mg
The average values for each ion are,
300.00 mg Na+,15.7 mg K+,5.45 mg Ca2+,388 mg Cl- and 246 mg Lactate
The source of Lactate is NaC3H5O3
Mass of Lactate = 246 mg C3H5O3-×112.06 mg NaC3H5O389.07 mg C3H5O3-=309.5 mg
The source of Ca2+ is CaCl2.2H2O
Mass of CaCl2.2H2O= 5.45 mg Ca2+×147.01 mg CaCl2.2H2O40.08 mg Ca2+=20 mg CaCl2.2H2O
The source of K+ is KCl
Mass of KCl= 15.7 mg K+×74.55 mg KCl39.10 mg K+=29.9 mg
Mass of Na+ added = 309.5 mg Sodium lactate-246.0 mg Lactate=63.5 mg Na+
Additional amount of Sodium 236.5 mg Na+ is added to get desired 300 mg
Mass of Sodium added = 236.5 mg Na+×58.44 mg NaCl22.99 mg Na+=601.2 mg
Mass of Cl- added = 20.0 mg CaCl2.2H2O×70.90 mg Cl-147.01 mg CaCl2.2H2O=9.6 mg
20.0 mg CaCl2.2H2O =9.6 mg Cl-29.9 mg KCl-15.7 mg K+ =14.2 mg Cl-601.2 mg NaCl-236.5 mg Na+=364.7 mg Cl-
Total Cl- = 388.5 mg
Therefore,
305.9 mg Sodium lactate, 20.0 mg CaCl2.2H2O, 29.9 mg KCl and 601.2 mg NaCl are required to prepare lactated Ringer’s reagent.
The mass of individual elements was calculated using their respective molar mass and molecular weight and the given weight. A typical analytical balance can nearly measure to 0.1 mg. Therefore, 305.9 mg Sodium lactate, 20.0 mg CaCl2.2H2O, 29.9 mg KCl and 601.2 mg NaCl are required to prepare lactated Ringer’s reagent.
Interpretation:
The osmotic pressure at minimum and maximum concentration has to be calculated.
Concept Introduction:
Colligative properties of a substance include the depression in the freezing point, elevation of boiling-point and osmotic pressure. These are dependant only on the number present and not based on the solute particles present in an ideal solution.
The osmotic pressure can be given by the equation,
Π=MRT
Here,Π=Osmotic pressure M=Molarity of solution R= Gas law constant T=Temperature

Answer to Problem 108AE
The range of osmotic pressure is 6.59 atm to 7.30 atm
Explanation of Solution
To calculate the osmotic pressure at minimum and maximum concentration
Record the given info
Mass of Sodium = 285-315 mg
Mass of Potassium = 14.1-17.3 mg
Mass of Calcium = 4.9-6.0 mg
Mass of Chlorine = 368-408 mg
Mass of Lactate = 231-261 mg
The masses of individual elements present in the reagent are recorded as shown above.
To calculate the minimum and maximum concentrations of ions
Molar mass of Lactate = 89.07 mg
Molecular mass of Calcium = 40.08 mg
Molecular weight of Potassium = 39.10 mg
Molecular mass of Sodium= 22.99 mg
At minimum concentration,
Molarity of Sodium = 285 mg Na+100. mL×1 mmol22.99 mg=0.124 M
Molarity of Potassium = 14.1 mg K+100.mL×1 mmol39.10 mg=0.00361 M
Molarity of Lactate = 231 mg C3H5O3-100.mL×1 mmol89.07 mg=0.0259 M
Molarity of Calcium = 4.9 mg Ca2+100.mL×1 mmol40.08 mg=0.0012 M
Molarity of Chlorine = 368 mg Cl-100.mL×1 mmol35.45 mg=0.104 M
The total concentration = 0.124+0.00361+0.0012+0.104+0.0259
= 0.259 M
At maximum concentration,
Molarity of Sodium = 315 mg Na+100. mL×1 mmol22.99 mg=0.137 M
Molarity of Potassium = 17.3 mg K+100.mL×1 mmol39.10 mg=0.00442 M
Molarity of Lactate = 261 mg C3H5O3-100.mL×1 mmol89.07 mg=0.0293 M
Molarity of Calcium = 6.0 mg Ca2+100.mL×1 mmol40.08 mg=0.0015 M
Molarity of Chlorine = 408 mg Cl-100.mL×1 mmol35.45 mg=0.115 M
The total concentration= 0.137+0.00442+0.0015+0.115+0.0293
= 0.287 M
To calculate the osmotic pressure at minimum and maximum concentration
At minimum concentration,
π=MRT =0.259 molL×0.08206 L atmK mol×310.K =6.59 atm
At maximum concentration,
π=MRT =0.287 molL×0.08206 L atmK mol×310.K =7.30 atm
At minimum concentration, osmotic pressure= 6.59 atm
At maximum concentration, osmotic pressure= 7.30 atm
The osmotic pressure at minimum and maximum concentrations was calculated using the molarities at minimum and maximum concentration. The osmotic pressure at minimum and maximum concentrations were 6.59 atm and 7.30 atm.
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Chapter 11 Solutions
Chemistry with Access Code, Hybrid Edition
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