Explanation Electrophilic substitution reactions in naphthalene: Fries rule: The most stable arrangement of a polynuclear compound is that form which has a maximum number of rings in the benzenoid condition. The most efficient stabilization of the intermediate carbocation produced by electrophilic attack on naphthalene comes from those resonance forms that retains one fully benzenoid ring. In case of 1-substitution, two structures can be obtained(A, B). In case of 2-substitution, one structure can be obtained(F). The intermediate from attack at the 1-position is more stable and therefore, the 1-substituted product is more favored in the electrophilic substitution of naphthalene. The carbocation formed by the attack of electrophile at 1-position of naphthalene is much more stabilize by resonance since it has four contributing structures in which aromatic character is retained in one of the ring...

ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM

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ISBN: 9781319399849

Author: ATKINS

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Chapter 11, Problem 11C.9E

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Interpretation:

The number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures has to be given.

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Chapter 11, Problem 11C.8E

Chapter 11, Problem 11C.10E

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Chapter 11 Solutions

ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

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The number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures has to be given.

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Interpretation: The number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures has to be given.

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Chapter 11 Solutions

Interpretation:

The number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures has to be given.