The type of reaction of methane with chlorine when exposed to light has to be classified and the chemical equation has to be written. Concept Introduction: Addition reaction: In addition reaction, two or more molecules are combined to form a larger product. Addition reactions are seen in alkenes (double bond compounds), alkynes (triple bond compounds). It is the reverse of an elimination reaction. Substitution reaction of alkanes : Functionalization of alkanes is done by substitution reaction, where an atom (in alkanes, a hydrogen atom) in the original molecule replaces an atom or group of atoms. Alkane substitution takes place by a radical chain mechanism.

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Answer 1

Question

Chapter 11, Problem 11.3E

(a)

Interpretation Introduction

Interpretation:

The type of reaction of methane with chlorine when exposed to light has to be classified and the chemical equation has to be written.

Concept Introduction:

Addition reaction: In addition reaction, two or more molecules are combined to form a larger product. Addition reactions are seen in alkenes (double bond compounds), alkynes (triple bond compounds). It is the reverse of an elimination reaction.

Substitution reaction of alkanes:

Functionalization of alkanes is done by substitution reaction, where an atom (in alkanes, a hydrogen atom) in the original molecule replaces an atom or group of atoms. Alkane substitution takes place by a radical chain mechanism.

(b)

Interpretation Introduction

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).

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Give the structure(s) of the product(s) the reaction below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise I'm struggling to see how this reaction will go! I am wondering if it will cycle on itself but I'm not sure how I drew out a decagon but I'm a bit lost

Give the structure(s) of the product(s) for the reactions below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise .

Calculate the residence time of strontium (Sr2+) in the world ocean, given that the average concentration of strontium in the world’s rivers is approximately 0.87 µmol L-1 (5 pts).

Answer 2

Question

Chapter 11, Problem 11.3E

(a)

Interpretation Introduction

Interpretation:

The type of reaction of methane with chlorine when exposed to light has to be classified and the chemical equation has to be written.

Concept Introduction:

Addition reaction: In addition reaction, two or more molecules are combined to form a larger product. Addition reactions are seen in alkenes (double bond compounds), alkynes (triple bond compounds). It is the reverse of an elimination reaction.

Substitution reaction of alkanes:

Functionalization of alkanes is done by substitution reaction, where an atom (in alkanes, a hydrogen atom) in the original molecule replaces an atom or group of atoms. Alkane substitution takes place by a radical chain mechanism.

(b)

Interpretation Introduction

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 11, Problem 11.3E

(a)

Interpretation Introduction

Interpretation:

The type of reaction of methane with chlorine when exposed to light has to be classified and the chemical equation has to be written.

Concept Introduction:

Addition reaction: In addition reaction, two or more molecules are combined to form a larger product. Addition reactions are seen in alkenes (double bond compounds), alkynes (triple bond compounds). It is the reverse of an elimination reaction.

Substitution reaction of alkanes:

Functionalization of alkanes is done by substitution reaction, where an atom (in alkanes, a hydrogen atom) in the original molecule replaces an atom or group of atoms. Alkane substitution takes place by a radical chain mechanism.

(b)

Interpretation Introduction

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 11, Problem 11.3E

(a)

Interpretation Introduction

Interpretation:

The type of reaction of methane with chlorine when exposed to light has to be classified and the chemical equation has to be written.

Concept Introduction:

Addition reaction: In addition reaction, two or more molecules are combined to form a larger product. Addition reactions are seen in alkenes (double bond compounds), alkynes (triple bond compounds). It is the reverse of an elimination reaction.

Substitution reaction of alkanes:

Functionalization of alkanes is done by substitution reaction, where an atom (in alkanes, a hydrogen atom) in the original molecule replaces an atom or group of atoms. Alkane substitution takes place by a radical chain mechanism.

(b)

Interpretation Introduction

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 11, Problem 11.3E

(a)

Interpretation Introduction

Interpretation:

The type of reaction of methane with chlorine when exposed to light has to be classified and the chemical equation has to be written.

Concept Introduction:

Addition reaction: In addition reaction, two or more molecules are combined to form a larger product. Addition reactions are seen in alkenes (double bond compounds), alkynes (triple bond compounds). It is the reverse of an elimination reaction.

Substitution reaction of alkanes:

Functionalization of alkanes is done by substitution reaction, where an atom (in alkanes, a hydrogen atom) in the original molecule replaces an atom or group of atoms. Alkane substitution takes place by a radical chain mechanism.

(b)

Interpretation Introduction

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 11, Problem 11.3E

(a)

Interpretation Introduction

Interpretation:

The type of reaction of methane with chlorine when exposed to light has to be classified and the chemical equation has to be written.

Concept Introduction:

Addition reaction: In addition reaction, two or more molecules are combined to form a larger product. Addition reactions are seen in alkenes (double bond compounds), alkynes (triple bond compounds). It is the reverse of an elimination reaction.

Substitution reaction of alkanes:

Functionalization of alkanes is done by substitution reaction, where an atom (in alkanes, a hydrogen atom) in the original molecule replaces an atom or group of atoms. Alkane substitution takes place by a radical chain mechanism.

Answer 7

Chapter 11, Problem 11.3E

(a)

Interpretation Introduction

Interpretation:

The type of reaction of methane with chlorine when exposed to light has to be classified and the chemical equation has to be written.

Concept Introduction:

Addition reaction: In addition reaction, two or more molecules are combined to form a larger product. Addition reactions are seen in alkenes (double bond compounds), alkynes (triple bond compounds). It is the reverse of an elimination reaction.

Substitution reaction of alkanes:

Functionalization of alkanes is done by substitution reaction, where an atom (in alkanes, a hydrogen atom) in the original molecule replaces an atom or group of atoms. Alkane substitution takes place by a radical chain mechanism.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

Solution Summary: The author explains the chemical equation for the reaction of methane with chlorine when exposed to light.

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).

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Chapter 11 Solutions

Solution Summary: The author explains the chemical equation for the reaction of methane with chlorine when exposed to light.

Interpretation: The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written. Concept Introduction: Refer to part (a).

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Chapter 11 Solutions

Interpretation:

The type of reaction of ethene with bromine in absence of light has to be classified and the chemical equation has to be written.

Concept Introduction:

Refer to part (a).