5th Edition

ISBN: 9780078021558

Author: Janice Gorzynski Smith Dr.

Publisher: McGraw-Hill Education

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Textbook Question

Chapter 11, Problem 11.46P

Tautomerization in base resembles tautomerization in acid, but deprotonation precedes protonation in the two-step mechanism. (a) Draw a stepwise mechanism for the following tautomeization. (b) Then draw a stepwise mechanism for the reverse reaction, the conversion of the keto form to the enol.

Chapter 11, Problem 11.46P, 11.46 Tautomerization in base resembles tautomerization in acid, but deprotonation precedes

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Chapter 11, Problem 11.45P

Chapter 11, Problem 11.47P

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Reagan is doing an atomic absorption experiment that requires a set of zinc standards in the 0.4- 1.6 ppm range. A 1000 ppm Zn solution was prepared by dissolving the necessary amount of solid Zn(NO3)2 in water. The standards can be prepared by diluting the 1000 ppm Zn solution. Table 1 shows one possible set of serial dilutions (stepwise dilution of a solution) that Reagan could perform to make the necessary standards. Solution A was prepared by diluting 5.00 ml of the 1000 ppm Zn standard to 50.00 ml. Solutions C-E are called "calibration standards" because they will be used to calibrate the atomic absorption spectrometer. Table 1: Dilutions of Zinc Solutions Solution Zinc Solution Volume Diluted Solution Concentration used volume (ppm Zn) (mL) (mL) concentration (ppm Zn) Solution concentration A 1000 5.00 50.00 1.00×10² (ppm Zn(NO3)2) 2.90×10² Solution concentration (M Zn(NO3)2 1.53×10-3 B Solution A 5.00 100.00 5.00 C Solution B 5.00 50.00 0.50 7.65×10-6 D Solution B 10.00 50.00…

Chapter 11 Solutions

Organic Chemistry

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