(a) Interpretation: The enol tautomer of compound (a) is to be drawn. Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

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Answer 1

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Chapter 11, Problem 11.24P

Interpretation Introduction

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Interpretation Introduction

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

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How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom molecule

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Answer 2

Question

Chapter 11, Problem 11.24P

Interpretation Introduction

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Interpretation Introduction

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

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Answer 3

Question

Chapter 11, Problem 11.24P

Interpretation Introduction

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Interpretation Introduction

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

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Answer 4

Question

Chapter 11, Problem 11.24P

Interpretation Introduction

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Interpretation Introduction

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

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Answer 5

Chapter 11, Problem 11.24P

Interpretation Introduction

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Interpretation Introduction

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Answer 6

Chapter 11, Problem 11.24P

Interpretation Introduction

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Answer 7

Chapter 11, Problem 11.24P

Interpretation Introduction

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Answer 8

Interpretation Introduction

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Answer 9

Interpretation Introduction

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11 - Problem 11.1 Neopheliosyne B is a novel acetylenic...Ch. 11 - Give the IUPAC name for each compound.Ch. 11 - Give the structures corresponding to each of the...Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Which bases can deprotonate acetylene? The pKa...Ch. 11 - Draw the organic products formed when each alkyne...Ch. 11 - Draw additional resonance structures for each...Ch. 11 - Problem 11.9 Draw the products formed when is...Ch. 11 - Explain the following result. Although alkenes...

(a) Interpretation: The enol tautomer of compound (a) is to be drawn. Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Solution Summary: The author explains that the enol tautomer of compound (a) is shown in Figure 2.

Concept explainers

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

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Chapter 11 Solutions

(a) Interpretation: The enol tautomer of compound (a) is to be drawn. Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

Solution Summary: The author explains that the enol tautomer of compound (a) is shown in Figure 2.

Concept explainers

(a) Interpretation: The enol tautomer of compound (a) is to be drawn. Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

(b) Interpretation: The keto tautomer of compound (b) is to be drawn. Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

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Chapter 11 Solutions

(a)

Interpretation: The enol tautomer of compound (a) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

(b)

Interpretation: The keto tautomer of compound (b) is to be drawn.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.