(a) Interpretation: The organic product that is formed in the given reaction is to be drawn. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as S N 2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 1

Question

Chapter 11, Problem 11.16P

Interpretation Introduction

(a)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Clouds of hot, luminous interstellar hydrogen gas can be seen in some parts of the galaxy. In some hydrogen atoms, electrons are excited to quantum levels with n = 100 or higher. (a) Calculate the wavelength observed on Earth if the electrons fall from the level with n = 100 to one with n = 2. (b) In what series would this transition be found? (c) Some of these high-energy electrons fall into intermediate states, such as n = 90. Would the wavelengths of a transition from the state with n = 100 to one with n = 90 be longer or shorter than those in the Balmer series? Explain your answer.

In the spectroscopic technique known as photoelectron spectroscopy (PES), ultraviolet radiation is directed at an atom or molecule. Electrons are ejected from the valence shell and their kinetic energies are measured. Since the energy of the incident ultraviolet photons is known and the kinetic energy of the ejected electron is measured, the ionization energy, I, can be deduced because total energy is conserved. (a) Show that the velocity, v, of the ejected electron and the frequency, n, of the incident radiation are related by hv = I + (1/2)mv^2? (b) Use this relation to calculate the ionization energy of a rubidium atom, knowing that light of wavelength 58.4 nm produces electrons with a velocity of 2,450 km/s Recall that 1 J = 1 kg.m^2/s^2

I) In Millikan's experiment, each droplet observed by the technicians contained an even number of electrons. If they had been unaware of this limitation, how would it have affected their report of an electron's charge?II) Millikan measured the charge of an electron in electrostatic units, esu. The data he collected included the following series of charges found on oil drops: 9.60 X 10^-10 esu, 1.92 X 10^-9 esu; 2.40 X 10^-9 esu; 2.88 X 10^-9 esu; and 4.80 X 10^-9 esu. (a) From this series, find the probable charge of the electron in electrostatic units. (b) Estimate the number of electrons in an oil drop with a charge of 6.72 X 10^-9 esu. The actual charge (in Coulombs) of an electron is 1.602 X 10^-19 C. What is the relationship between esu and Coulombs?

Answer 2

Question

Chapter 11, Problem 11.16P

Interpretation Introduction

(a)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 3

Question

Chapter 11, Problem 11.16P

Interpretation Introduction

(a)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 4

Question

Chapter 11, Problem 11.16P

Interpretation Introduction

(a)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 5

Chapter 11, Problem 11.16P

Interpretation Introduction

(a)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 6

Chapter 11, Problem 11.16P

Interpretation Introduction

(a)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 7

Chapter 11, Problem 11.16P

Interpretation Introduction

(a)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 8

Interpretation Introduction

(b)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 9

Interpretation Introduction

(b)

Interpretation: The organic product that is formed in the given reaction is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11 - Draw structures for the three alkynes having...Ch. 11 - Prob. 11.2P Ch. 11 - Give the IUPAC name for each compound.Ch. 11 - Give the structures corresponding to each of the...Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Which bases can deprotonate acetylene? The pKa...Ch. 11 - Draw the organic products formed when each alkyne...Ch. 11 - Prob. 11.9P Ch. 11 - Problem 11.9 Draw the products formed when is...

Solution Summary: The author explains that the organic product that is formed in the given reaction is shown in Figure 1.

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