Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Textbook Question
Chapter 11, Problem 11.12P
Each compound given in this problem is a common organic solvent. From each pair of compounds, select the solvent with the greater solubility in water.
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compound given are a common organic solvent. From the pair of compounds, select the solvent with the greater solubility in water.
Which of the following best describes the solubility of aldehydes and ketones?
A) They are all soluble in water and organic solvents.
B) They are water soluble but not soluble in organic solvents.
C) They are soluble in all organic solvents but only soluble in water for low molecular mass species.
D) They are all soluble in water but only soluble in organic solvents for low molecular mass species.
Ester compounds often have a sweet, pleasant odor. Many
characteristic fruit scents are largely due to the natural presence
of one or more ester compounds. As such, artificial scents for
foods are often composed of complex mixtures of various esters.
The exact identity and ratio of ingredients that compose a
particular scent are closely guarded secrets in the food and
fragrance industry.
Suppose that you are a chemist working for a company that i
creating a new line of air fresheners. The company is considering
three scents: apple, pear, and pineapple. The project manager has
asked you to prepare the ester compounds that are largely
responsible for these scents. The structural formulas for these
ester compounds are shown here:
Alcohols for Air Freshener Project
Molar mass Density Cost, per
(g/mL)
Reagent
(g/mol)
1.00 L
methanol
32.04
0.79
$46.20
ethanol
46.07
0.79
$112.00
1-propanol
60.10
0.80
$72.70
1-butanol
74.12
0.81
$72.60
Use the structural formulas of the alcohols and…
Chapter 11 Solutions
Organic Chemistry
Ch. 11.2 - Write IUPAC and common names for these ethers. (a)...Ch. 11.3 - Arrange these compounds in order of increasing...Ch. 11.4 - Show how you might use the Williamson ether...Ch. 11.4 - Show how ethyl hexyl ether might be prepared by a...Ch. 11.5 - Account for the fact that treatment of tert-butyl...Ch. 11.5 - Draw structural formulas for the major products of...Ch. 11.6 - Prob. 11.7PCh. 11.8 - Draw the expected products of Sharpless...Ch. 11.9 - Prob. AQCh. 11.9 - Prob. BQ
Ch. 11.9 - Prob. CQCh. 11.9 - Prob. DQCh. 11 - Write names for these compounds. Where possible,...Ch. 11 - Prob. 11.11PCh. 11 - Each compound given in this problem is a common...Ch. 11 - Account for the fact that tetrahydrofuran (THF) is...Ch. 11 - Prob. 11.14PCh. 11 - Write equations to show a combination of reactants...Ch. 11 - Propose a mechanism for this reaction.Ch. 11 - Prob. 11.17PCh. 11 - Prob. 11.18PCh. 11 - Prob. 11.19PCh. 11 - Prob. 11.20PCh. 11 - Ethylene oxide is the starting material for the...Ch. 11 - Prob. 11.22PCh. 11 - Predict the structural formula of the major...Ch. 11 - The following equation shows the reaction of...Ch. 11 - Propose a mechanism to account for this...Ch. 11 - Acid-catalyzed hydrolysis of the following epoxide...Ch. 11 - Prob. 11.27PCh. 11 - Prob. 11.28PCh. 11 - Prob. 11.29PCh. 11 - Propose a mechanism for the following...Ch. 11 - Show reagents and experimental conditions to...Ch. 11 - Starting with cis-3-hexene, show how to prepare...Ch. 11 - Show reagents to convert cycloheptene to each of...Ch. 11 - Show reagents to convert bromocyclopentane to each...Ch. 11 - Prob. 11.35PCh. 11 - Starting with acetylene and ethylene oxide as the...Ch. 11 - Following are the steps in the industrial...Ch. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - Aldehydes and ketones react with one molecule of...Ch. 11 - Prob. 11.42PCh. 11 - Write the products of the following sequences of...Ch. 11 - Using your reaction roadmap as a guide, show how...Ch. 11 - Using your reaction roadmap as a guide, show how...Ch. 11 - Using your reaction roadmap as a guide, show how...Ch. 11 - During the synthesis of the antiasthmatic drug...Ch. 11 - Prob. 11.48P
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- provide the IUPAC or common name for this compoundarrow_forwardA) Provide four different ways that 2-methylpropanal could be made from an alkene, an alcohol, an ester and an acetal in a single step. an alkene H an alcohol 2-methylpropanal an ester an acetalarrow_forward1. What allows some organic compounds to be soluble in water? 2. If two solutions are insoluble with each other, describe how a mixture of the two solutions would appear. 3. Explain the saying “like dissolves like” 4. What is the trend in solubility for alcohols in water as the number of carbons in the parent chain increases. Explain this trend? 5. Which of the following would be the most soluble and least soluble in water Primary amines, secondary amines, tertiary amines. Explain your reasoning. 6. Would you expect an alcohol with a 20-carbon parent chain to be soluble or insoluble in oil? Why?arrow_forward
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