Structural formula for the given name has to be drawn. Concept Introduction: Nomenclature of Ether compounds: The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are, Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group. Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ ether ’. Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively. Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Question

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Answer 1

Question

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 8

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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below: QUESTION: Summarise and report these results including an indication of measurement uncertainty. In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical). Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…

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Answer 2

Question

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 8

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Answer 3

Question

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 8

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Answer 4

Question

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 8

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 8

Answer 6

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 1

Answer 7

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 8

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 1

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 2

Answer 13

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 14

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 2

Answer 15

(b)

Expert Solution

Answer 16

(b)

Expert Solution

Answer 17

Expert Solution

Answer 18

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 3

Answer 19

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 20

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 3

Answer 21

(c)

Expert Solution

Answer 22

(c)

Expert Solution

Answer 23

Expert Solution

Answer 24

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 4

Answer 25

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 26

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 4

Answer 27

(d)

Expert Solution

Answer 28

(d)

Expert Solution

Answer 29

Expert Solution

Answer 30

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 5

Answer 31

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 32

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 5

Answer 33

(e)

Expert Solution

Answer 34

(e)

Expert Solution

Answer 35

Expert Solution

Answer 36

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 6

Answer 37

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 38

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 6

Answer 39

(f)

Expert Solution

Answer 40

(f)

Expert Solution

Answer 41

Expert Solution

Answer 42

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 7

Answer 43

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 44

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 7

Answer 45

(g)

Expert Solution

Answer 46

(g)

Expert Solution

Answer 47

Expert Solution

Answer 48

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 8

Answer 49

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 50

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

Organic Chemistry, Chapter 11, Problem 11.11P , additional homework tip 8