a) Interpretation: How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown. Concept introduction: In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst. To show: How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Question

Reaction of p-nitroaniline with sodium nitrite and hydrochloric acid at 0°C, followed by treatment with N,N-diethylaniline.

Answer 1

Question

Chapter 10.SE, Problem 47AP

Interpretation Introduction

a)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

b)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

c)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

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Answer 2

Question

Chapter 10.SE, Problem 47AP

Interpretation Introduction

a)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

b)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

c)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Expert Solution & Answer

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Answer 3

Question

Chapter 10.SE, Problem 47AP

Interpretation Introduction

a)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

b)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

c)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Expert Solution & Answer

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Answer 4

Question

Chapter 10.SE, Problem 47AP

Interpretation Introduction

a)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

b)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

c)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Expert Solution & Answer

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Answer 5

Chapter 10.SE, Problem 47AP

Interpretation Introduction

a)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

b)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Interpretation Introduction

c)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Answer 6

Chapter 10.SE, Problem 47AP

Interpretation Introduction

a)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Answer 7

Chapter 10.SE, Problem 47AP

Interpretation Introduction

a)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Answer 8

Interpretation Introduction

b)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Answer 9

Interpretation Introduction

b)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Answer 10

Interpretation Introduction

c)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Answer 11

Interpretation Introduction

c)

Interpretation:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction is to be shown.

Concept introduction:

In Suzuki-Miyaura reaction biaryl compounds are prepared by a coupling reaction between aromatic or vinyl substituted boronic acid with an aromatic or vinyl organo-halide in the presence of Pd catalyst.

To show:

How the biaryl compound shown can be prepared using Suzuki-Miyaura reaction.

Answer 12

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Answer 23

Ch. 10.1 - Prob. 1P Ch. 10.1 - Draw structures corresponding to the following...Ch. 10.2 - Prob. 3P Ch. 10.2 - Taking the relative reactivities of 1Â°, 2Â°, and...Ch. 10.4 - Prob. 5P Ch. 10.4 - The major product of the reaction of...Ch. 10.4 - Prob. 7P Ch. 10.5 - Prob. 8P Ch. 10.6 - Prob. 9P Ch. 10.6 - How might you replace a halogen substituent by a...

Solution Summary: The author explains how the biaryl compound can be prepared using Suzuki-Miyaura reaction.

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