Concept explainers
a)
Interpretation:
How to prepare tert-butyl chloride from tert-butylalcohol is to be stated.
Concept introduction:
tert-Alcohols when treated with HCl, HBr or HI in ether at 0oC give the corresponding tert-
To state:
How to prepare tert-butyl chloride from tert-butylalcohol.
b)
Interpretation:
How to .prepare 2-bromo-4-methylpentane from the corresponding alcohol is to be stated.
Concept introduction:
A secondary alkyl bromide is required. Secondary alkyl halides can be prepared by treating the alcohol required with PBr3 in ether solution.
To state:
How to prepare 2-bromo-4-methylpentane from the corresponding alcohol.
c)
Interpretation:
How to .prepare 1-bromo-5-methylhexane from the corresponding alcohol is to be stated.
Concept introduction:
A primary alkyl bromide is required. Primary alkyl halides can be prepared by treating the alcohol required with PBr3 in ether solution.
To state:
How to prepare1-bromo-5-methylhexane from the corresponding alcohol.
d)
Interpretation:
How to .prepare 1-fluoro-3,3-dimethylcyclopentane from the corresponding alcohol is to be stated.
Concept introduction:
A secondary alkyl fluoride is required. Secondary alkyl fluorides can be prepared by treating the alcohol required with diethylaminosulphur trifluoride and HF in pyridine.
To state:
How to prepare1-fluoro-3,3-dimethylcyclopentane from the corresponding alcohol.
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Chapter 10 Solutions
Organic Chemistry
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Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning