Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 10, Problem 23P
Interpretation Introduction

Interpretation:

The number of different isomers expected from the chlorination of (R)-2-chlorobutane and the number of fractions obtained by fractional distillation are to be given. Also, the optical activity of these fractions is to be checked.

Concept introduction:

A mixture of isomeric monochlorinated products is formed by the chlorination of higher alkanes. Chlorination is unselective, thus it leads to the complex mixture of products.

The optically active compounds are those that contain at least one chiral center.

A chiral center is a carbon atom attached to 4 different substituents.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

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