General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 10, Problem 10.82SP
Interpretation Introduction
Interpretation:
A unit cell has to be defined.
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 10 Solutions
General Chemistry: Atoms First
Ch. 10.1 - The dipole moment of HF is = 1.83 D, and the bond...Ch. 10.1 - Prob. 10.2PCh. 10.1 - Prob. 10.3CPCh. 10.1 - Prob. 10.4CPCh. 10.2 - Prob. 10.5PCh. 10.2 - Prob. 10.6PCh. 10.4 - Prob. 10.7PCh. 10.4 - Chloroform (CHCl3) has Hvap = 29.2 kJ/mol and Svap...Ch. 10.5 - Prob. 10.9PCh. 10.5 - Prob. 10.10P
Ch. 10.8 - Prob. 10.11PCh. 10.8 - Prob. 10.12PCh. 10.8 - Prob. 10.13PCh. 10.8 - Prob. 10.14CPCh. 10.9 - Prob. 10.15PCh. 10.9 - Prob. 10.16CPCh. 10.11 - Prob. 10.17PCh. 10.11 - Prob. 10.18PCh. 10.11 - Prob. 10.19CPCh. 10.11 - Prob. 10.20PCh. 10.11 - Prob. 10.21PCh. 10 - Prob. 10.22CPCh. 10 - Prob. 10.23CPCh. 10 - Zinc sulfide, or sphalerite, crystallizes in the...Ch. 10 - Perovskite, a mineral containing calcium, oxygen,...Ch. 10 - Prob. 10.26CPCh. 10 - Prob. 10.27CPCh. 10 - Prob. 10.28CPCh. 10 - Prob. 10.30CPCh. 10 - Prob. 10.31CPCh. 10 - Why dont all molecules with polar covalent bonds...Ch. 10 - Prob. 10.33SPCh. 10 - Prob. 10.34SPCh. 10 - Prob. 10.35SPCh. 10 - Methanol (CH3OH; bp = 65 C) boils nearly 230 C...Ch. 10 - Prob. 10.37SPCh. 10 - Which of the following substances would you expect...Ch. 10 - Prob. 10.39SPCh. 10 - Prob. 10.40SPCh. 10 - The dipole moment of ClF is 0.887 D and the...Ch. 10 - Prob. 10.42SPCh. 10 - Prob. 10.43SPCh. 10 - The class of ions PtX42, where X is a halogen, has...Ch. 10 - Prob. 10.45SPCh. 10 - Prob. 10.46SPCh. 10 - Prob. 10.47SPCh. 10 - Prob. 10.48SPCh. 10 - Prob. 10.49SPCh. 10 - Prob. 10.50SPCh. 10 - Prob. 10.51SPCh. 10 - Mercury has mp = 38.8 C and bp = 356.6 C. What, if...Ch. 10 - Prob. 10.53SPCh. 10 - Prob. 10.54SPCh. 10 - Prob. 10.55SPCh. 10 - Prob. 10.56SPCh. 10 - Prob. 10.57SPCh. 10 - Prob. 10.58SPCh. 10 - How much energy in kilojoules is released when...Ch. 10 - Draw a molar heating curve for ethanol, C2H5OH,...Ch. 10 - Prob. 10.61SPCh. 10 - Prob. 10.62SPCh. 10 - Prob. 10.63SPCh. 10 - Prob. 10.64SPCh. 10 - Prob. 10.65SPCh. 10 - Prob. 10.66SPCh. 10 - Prob. 10.67SPCh. 10 - Prob. 10.68SPCh. 10 - Prob. 10.69SPCh. 10 - Prob. 10.70SPCh. 10 - Prob. 10.71SPCh. 10 - Prob. 10.72SPCh. 10 - Prob. 10.73SPCh. 10 - Prob. 10.74SPCh. 10 - Prob. 10.75SPCh. 10 - Prob. 10.76SPCh. 10 - Which of the substances diamond, Hg, Cl2, glass,...Ch. 10 - Prob. 10.78SPCh. 10 - Prob. 10.79SPCh. 10 - Prob. 10.80SPCh. 10 - Prob. 10.81SPCh. 10 - Prob. 10.82SPCh. 10 - Prob. 10.83SPCh. 10 - Prob. 10.84SPCh. 10 - Prob. 10.85SPCh. 10 - Prob. 10.86SPCh. 10 - Prob. 10.87SPCh. 10 - Prob. 10.88SPCh. 10 - Sodium has a density of 0.971 g/cm3 and...Ch. 10 - Prob. 10.90SPCh. 10 - Prob. 10.91SPCh. 10 - Prob. 10.92SPCh. 10 - Prob. 10.93SPCh. 10 - Prob. 10.94SPCh. 10 - Prob. 10.95SPCh. 10 - Look at the phase diagram of CO2 in Figure 10.29,...Ch. 10 - Prob. 10.97SPCh. 10 - Prob. 10.98SPCh. 10 - Prob. 10.99SPCh. 10 - Prob. 10.100SPCh. 10 - Prob. 10.101SPCh. 10 - Does solid oxygen (Problem 10.99) melt when...Ch. 10 - Prob. 10.103SPCh. 10 - Prob. 10.104SPCh. 10 - Prob. 10.105SPCh. 10 - Prob. 10.106SPCh. 10 - Prob. 10.107SPCh. 10 - Prob. 10.108CHPCh. 10 - Prob. 10.109CHPCh. 10 - Prob. 10.110CHPCh. 10 - Prob. 10.111CHPCh. 10 - Prob. 10.112CHPCh. 10 - Prob. 10.113CHPCh. 10 - Prob. 10.114CHPCh. 10 - Prob. 10.115CHPCh. 10 - Magnesium metal has Hfusion = 9.037 kJ/mol and...Ch. 10 - Prob. 10.117CHPCh. 10 - Prob. 10.118CHPCh. 10 - Prob. 10.119CHPCh. 10 - Prob. 10.120CHPCh. 10 - Prob. 10.121CHPCh. 10 - Prob. 10.122CHPCh. 10 - Prob. 10.123CHPCh. 10 - Calculate the percent volume occupied by the...Ch. 10 - Prob. 10.125CHPCh. 10 - Prob. 10.126CHPCh. 10 - Prob. 10.127CHPCh. 10 - A drawing of the NaCl unit cell is shown in Figure...Ch. 10 - Niobium oxide crystallizes in the following cubic...Ch. 10 - Prob. 10.130CHPCh. 10 - One form of silver telluride (Ag2Te) crystallizes...Ch. 10 - Prob. 10.132CHPCh. 10 - Prob. 10.133MPCh. 10 - Prob. 10.134MPCh. 10 - A group 3A metal has a density of 2.70 g/cm3 and a...Ch. 10 - Prob. 10.136MP
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