
Concept explainers
Interpretation:
The degeneracies of all levels for a cubical box from the lowest-energy wavefunction, described by the set of quantum numbers
Concept introduction:
The Schrödinger equation is used to find the allowed energy levels for electronic transitions in the
Where,
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The energy obtained after applying the operator on wavefunction is known as the eigen value for the wavefunction.

Answer to Problem 10.79E
The degeneracies of all levels for a cubical box from the lowest-energy wavefunction, described by the set of quantum numbers
Explanation of Solution
The formula to calculate energy for an electron confined to a three dimensional box is given below.
Substitute the values in the equation (1) for the three-dimensional box having same dimensions and
Similarly, other values for the energy by changing quantum numbers are calculated as follows.
The values of energies obtained for higher values of
The set of quantum numbers degenerate wavefunctions are as follows:
The degeneracies of all levels for a cubical box from the lowest-energy wavefunction, described by the set of quantum numbers
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Chapter 10 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
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- Complete the reaction in the drawing area below by adding the major products to the right-hand side. If there won't be any products, because nothing will happen under these reaction conditions, check the box under the drawing area instead. Note: if the products contain one or more pairs of enantiomers, don't worry about drawing each enantiomer with dash and wedge bonds. Just draw one molecule to represent each pair of enantiomers, using line bonds at the chiral center. + More... ☐ ☐ : ☐ + G 1. NaOMe Click and drag to start drawing a structure. 2. H +arrow_forward6. Ammonia reacts with nitrogen monoxide and oxygen to form nitrogen and water vapor. If the rate of consumption of NO is 4.5 mollitermin) (a) Find the rate of reaction (b) Find the rate of formations of N; and HO (c) Find the rate of consumption of NH, and O 4NH: 4NO 0:4: +60arrow_forward34. Give the expected major product of each of the following reactions. Conc. HI a. CH3CH2CH2OH b. (CH3)2CHCH2CH2OH Conc. HBr H Conc. HI C. OH Conc.HCI d. (CH3CH2)3COHarrow_forward
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