
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 10, Problem 10.13E
Interpretation Introduction
Interpretation:
The reason as to why the given situation might be considered as a problematic definition is to be explained.
Concept introduction:
When an operator acts on a function to give the function back which is multiplied with a constant, then the function is called Eigen function of the operator and the constant is known as eigenvalue. A general eigenvalue equation is represented as,
Where,
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•
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Using the general properties of equilibrium constants
At a certain temperature, the equilibrium constant K for the following reaction is 1.3 × 10 4:
Cl2(g) + CHCl3(g) HCl(g) + CC₁(g)
Use this information to complete the following table.
Suppose a 16. L reaction vessel is filled with 1.6 mol of HCI and
1.6 mol of CCl4. What can you say about the composition of the
mixture in the vessel at equilibrium?
There will be very little Cl2 and CHCl3.
☐ x10
There will be very little HCI and CCl4.
Neither of the above is true.
What is the equilibrium constant for the following reaction? Be
sure your answer has the correct number of significant digits.
HCl(g)+CC14(g)
12
Cl2(9)+CHCl3(9)
K = 0 ☐
What is the equilibrium constant for the following reaction? Be
sure your answer has the correct number of significant digits.
2 Cl₂(9)+2CHCl3(9)
2 HCl(9)+2CC₁₁(9)
K =
✓
00.
18
Ar
Chapter 10 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 10 - State the postulates of quantum mechanics...Ch. 10 - Prob. 10.2ECh. 10 - State whether the following functions are...Ch. 10 - State whether the following functions are...Ch. 10 - Prob. 10.5ECh. 10 - Prob. 10.6ECh. 10 - Evaluate the operations in parts a, b, and f in...Ch. 10 - The following operators and functions are defined:...Ch. 10 - Prob. 10.9ECh. 10 - Indicate which of these expressions yield...
Ch. 10 - Indicate which of these expressions yield an...Ch. 10 - Why is multiplying a function by a constant...Ch. 10 - Prob. 10.13ECh. 10 - Using the original definition of the momentum...Ch. 10 - Under what conditions would the operator described...Ch. 10 - A particle on a ring has a wavefunction =12eim...Ch. 10 - Calculate the uncertainty in position, x, of a...Ch. 10 - For an atom of mercury, an electron in the 1s...Ch. 10 - Classically, a hydrogen atom behaves as if it were...Ch. 10 - The largest known atom, francium, has an atomic...Ch. 10 - How is the Bohr theory of the hydrogen atom...Ch. 10 - Though not strictly equivalent, there is a similar...Ch. 10 - The uncertainty principle is related to the order...Ch. 10 - Prob. 10.24ECh. 10 - Prob. 10.25ECh. 10 - For a particle in a state having the wavefunction...Ch. 10 - Prob. 10.27ECh. 10 - A particle on a ring has a wavefunction =eim,...Ch. 10 - Prob. 10.29ECh. 10 - Prob. 10.30ECh. 10 - Prob. 10.31ECh. 10 - Normalize the following wavefunctions over the...Ch. 10 - Prob. 10.33ECh. 10 - Prob. 10.34ECh. 10 - For an unbound or free particle having mass m in...Ch. 10 - Prob. 10.36ECh. 10 - Prob. 10.37ECh. 10 - Prob. 10.38ECh. 10 - Evaluate the expression for the total energies for...Ch. 10 - Prob. 10.40ECh. 10 - Verify that the following wavefunctions are indeed...Ch. 10 - In exercise 10.41a, the wavefunction is not...Ch. 10 - Prob. 10.43ECh. 10 - Prob. 10.44ECh. 10 - Explain why n=0 is not allowed for a...Ch. 10 - Prob. 10.46ECh. 10 - Prob. 10.47ECh. 10 - Prob. 10.48ECh. 10 - Carotenes are molecules with alternating CC and...Ch. 10 - The electronic spectrum of the molecule butadiene,...Ch. 10 - Prob. 10.51ECh. 10 - Prob. 10.52ECh. 10 - Show that the normalization constants for the...Ch. 10 - Prob. 10.54ECh. 10 - Prob. 10.55ECh. 10 - An official baseball has a mass of 145g. a...Ch. 10 - Is the uncertainty principle consistent with our...Ch. 10 - Prob. 10.58ECh. 10 - Prob. 10.59ECh. 10 - Instead of x=0 to a, assume that the limits on the...Ch. 10 - In a plot of ||2, the maximum maxima in the plot...Ch. 10 - Prob. 10.62ECh. 10 - Prob. 10.63ECh. 10 - The average value of radius in a circular system,...Ch. 10 - Prob. 10.65ECh. 10 - Prob. 10.66ECh. 10 - Prob. 10.67ECh. 10 - Prob. 10.68ECh. 10 - Prob. 10.69ECh. 10 - Assume that for a particle on a ring the operator...Ch. 10 - Mathematically, the uncertainty A in some...Ch. 10 - Prob. 10.72ECh. 10 - Prob. 10.73ECh. 10 - Verify that the wavefunctions in equation 10.20...Ch. 10 - An electron is confined to a box of dimensions...Ch. 10 - a What is the ratio of energy levels having the...Ch. 10 - Consider a one-dimensional particle-in-a-box and a...Ch. 10 - Prob. 10.78ECh. 10 - Prob. 10.79ECh. 10 - Prob. 10.80ECh. 10 - Prob. 10.81ECh. 10 - What are x,y, and z for 111 of a 3-D...Ch. 10 - Prob. 10.83ECh. 10 - Prob. 10.84ECh. 10 - Prob. 10.85ECh. 10 - Prob. 10.86ECh. 10 - Prob. 10.87ECh. 10 - Prob. 10.88ECh. 10 - Substitute (x,t)=eiEt/(x) into the time-dependent...Ch. 10 - Write (x,t)=eiEt/(x) in terms of sine and cosine,...Ch. 10 - Prob. 10.91ECh. 10 - Prob. 10.92ECh. 10 - Prob. 10.93ECh. 10 - Prob. 10.95E
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