(a) Interpretation: The structure corresponding to ( 1 E , 4 R ) − 1 , 4 − dimethylcyclodecene is to be drawn. Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name. The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

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Answer 1

Question

Chapter 10, Problem 10.43P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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(a) Draw two different enol tautomers of 2-methylcyclohexanone. (b) Draw two constitutional isomers that are not tautomers, but contain a C=C and an OH group. 2-methylcyclohexanone

(a)(2R,3S)-2,3-dibromohexane, label each structure you have drawn as chiral or achiral.

Draw the structure of an alkyl bromide with molecular formula CgH13Br that fits each description: (a) a 1° alkyl bromide with one stereogenic center; (b) a 2° alkyl bromide with two stereogenic centers; (c) an achiral 3° alkyl bromide.

Answer 2

Question

Chapter 10, Problem 10.43P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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Answer 3

Question

Chapter 10, Problem 10.43P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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Answer 4

Question

Chapter 10, Problem 10.43P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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Answer 5

Chapter 10, Problem 10.43P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 6

Chapter 10, Problem 10.43P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer 7

Chapter 10, Problem 10.43P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer 8

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Answer 9

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Answer 10

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 11

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10 - Prob. 10.1P Ch. 10 - Problem 10.2 How many degrees of unsaturation are...Ch. 10 - Give an example of a compound with molecular...Ch. 10 - Give the IUPAC name for each alkene.Ch. 10 - Give the IUPAC name for each polyfunctional...Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Problem 10.10 Rank the following isomers in order...

Solution Summary: The author explains the systematic naming of organic compound by IUPAC. The prefix E and Z depends upon the location of the higher priority groups.

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Chapter 10 Solutions