Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 10, Problem 10.16P
10-16 What is the relationship between the number of electrons in the valence shell of each of the following atoms and the number of covalent bonds each forms? (a) Carbon(b) Oxygen (c) Nitrogen(d) Hydrogen
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The arrangement of atoms in several biologically important molecules is given here. Complete the Lewis
structures of these molecules by adding multiple bonds and lone pairs. Do not add any more atoms.
(a) the amino acid serine:
車
0-H
H-C-H
H
Н—N—с—с—о—н
H
(b)
нон
H-N-C-N-H
(c) pyruvic acid:
ноо
н—с—с—с—о—н
H.
(d) uracil:
H
(e) carbonic acid:
H-0-C-0-H
Draw the molecules in Problem 1.61 using line structures
Structural Formula
Chapter 10 Solutions
Introduction to General, Organic and Biochemistry
Ch. 10.3 - Prob. 10.1PCh. 10.4 - Prob. 10.2PCh. 10.4 - Prob. 10.3PCh. 10.4 - Prob. 10.4PCh. 10.4 - Prob. 10.5PCh. 10.4 - Prob. 10.6PCh. 10 - Prob. 10.7PCh. 10 - Prob. 10.8PCh. 10 - 10-9 Is there any difference between vanillin made...Ch. 10 - Prob. 10.10P
Ch. 10 - 10-11 What important experiment did Wohler carry...Ch. 10 - Prob. 10.12PCh. 10 - Prob. 10.13PCh. 10 - Prob. 10.14PCh. 10 - 10-15 How many electrons are in the valence shell...Ch. 10 - 10-16 What is the relationship between the number...Ch. 10 - Prob. 10.17PCh. 10 - Prob. 10.18PCh. 10 - 10-19 Write Lewis structures for these ions. (a)...Ch. 10 - 10-20 Why are the following molecular formulas...Ch. 10 - 10-21 Explain how to use the valence-shell...Ch. 10 - 10-22 Suppose you forget to take into account the...Ch. 10 - Suppose you forget to take into account the...Ch. 10 - 10-24 Use the VSEPR model to predict the bond...Ch. 10 - Prob. 10.25PCh. 10 - Prob. 10.26PCh. 10 - 10-27 What is meant by the term functional group?Ch. 10 - 10-28 List three reasons why functional groups are...Ch. 10 - Prob. 10.29PCh. 10 - Prob. 10.30PCh. 10 - Prob. 10.31PCh. 10 - 10-32 Draw a structural formula for the one...Ch. 10 - 10-33 What is the meaning of the term tertiary (...Ch. 10 - Prob. 10.34PCh. 10 - Draw structural formulas for each of the...Ch. 10 - 10-36 Draw structural formulas for the six ketones...Ch. 10 - 10-37 Draw structural formulas for the eight...Ch. 10 - Prob. 10.38PCh. 10 - 10-39 (Chemical Connections 10A) How was Taxol...Ch. 10 - Prob. 10.40PCh. 10 - Prob. 10.41PCh. 10 - Silicon is immediately below carbon in Group 4A of...Ch. 10 - 10-43 Phosphorus is immediately below nitrogen in...Ch. 10 - Draw the structure for a compound with the...Ch. 10 - 10-45 Draw structural formulas for the eight...Ch. 10 - Prob. 10.46PCh. 10 - 10-47 Which of these covalent bonds are polar, and...Ch. 10 - Of the bonds in Problem 10-47, which is the most...Ch. 10 - Prob. 10.49PCh. 10 - Prob. 10.50PCh. 10 - Following is a structural formula for naphthalene....Ch. 10 - Prob. 10.52PCh. 10 - Prob. 10.53PCh. 10 - Urea, (NH.,)2CO, is used in plastics and in fertil...Ch. 10 - Prob. 10.55PCh. 10 - Prob. 10.56PCh. 10 - Aspirin is prepared by the reaction of salicylic-...Ch. 10 - Following is the structural formula of acetamide....Ch. 10 - Prob. 10.59P
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- 3-122 Some of the following structural formulas are incorrect because they contain one or more atoms that do not have their normal number of covalent bonds. Which structural formulas are incorrect, and which atom or atoms in each have the incorrect number of bonds?arrow_forward10-21 Explain how to use the valence-shell electron-pair repulsion (VSEPR) model to predict bond angles and geometry about atoms of carbon, oxygen, and nitrogen.arrow_forward3-41 Describe the structure of sodium chloride in the solid state.arrow_forward
- 16. Which of the following structures is the CORRECT resonance structure of the following. molecule: (A) (B) (C) (D) CH3- CH₂ CH3 -H CH₂CH3 CH₂CH-CH₂ CH3 CH3arrow_forwardChemistry (a) Write three more resonance structures for each of compounds 1 and 2. (b) In each of compounds 1 and 2, determine which resonance structure contributes the most and explain your answer. (c) Are the 3/4 structures resonance structures or different compounds? Same question for 5/6 structures. Explain your answers.arrow_forward(a) Complete the Lewis structure for vinyl chloride by showing all unshared pairs of electrons. (b) Predict the H-C-H, H-C-C, and Cl-C-H bond angles in this molecule. (c) Does vinyl chloride have polar bonds? Is it a polar molecule? Does it have a dipole?arrow_forward
- 3-110 Name and write the formula for the fluorine containing compound present in fluoridated tooth pastes and dental gels.arrow_forward3-127 Amoxicillin is an antibiotic used to treat bacterial infections caused by susceptible microorganisms. Consider the skeletal structure of amoxicillin (y refer to the structure at bottom of page). Where all the bonded atoms are shown but double bonds, triple bonds, and/or lone pairs are missing: (a) Complete the structure of amoxicillin. (b) Identify the various types of geometries present in each central atom using VSEPR theory (e) Determine the various relative bond angles as sociated with each central atom using VSEPR theory. (d) What is the most polar bond in Amoxicillin? (e) Would you predict amoxicillin to be polar or nonpolar? (f) Is amoxicillin expected to possess resonance? Explain why or why not. V Chemical structure for problem 3-127arrow_forward3-107 Ephedrine, a molecule at one time found in the dietary supplement ephedra, has been linked to adverse health reactions, such as heart attacks, strokes, and heart palpitations. The use of ephedra in dietary supplements is now banned by the FDA. (a) Which is the most polar bond in ephedra? (b) Would you predict ephedra to be polar or nonpolar?arrow_forward
- Urea, (NH.,)2CO, is used in plastics and in fertil izers. It is also the primary nitrogen-containing substance excreted by humans. O I I H H Urea Complete the Lewis structure of urea, showing all valence electrons. Predict the bond angle about each C and N. Which is the most polar bond in the molecule? (d, Is urea polar or nonpolar?arrow_forward3-106 Consider the structure of Penicillin G shown below, an antibiotic used to treat bacterial infections caused by gram-positive organisms, derived from Penicillium fungi: (a) Identify the various types of geometries present in each central atom using VSEPR theory. (b) Determine the various relative bond angles associated with each central atom using VSEPR theory (c) Which is the most poiar bond in Penicillin G? (d) Would you predict Penicillin G to be polar or nonpolar?arrow_forward10-15 How many electrons are in the valence shell of each of the following atoms? Write a Lewis structure for an atom of each element. (Hint: Use the Periodic Table.) (a) Carbon(b) Oxygen (c) Nitrogen(d) Fluorinearrow_forward
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