Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 1, Problem 77P
a. Draw a Lewis structure for each of the following:
- 1. CH3N2+
- 2. HNO3
- 3. N3-
- 4. CH3CONH2
- 5. O3
b. Draw a structure for each of the species that shows approximate bond angles.
c. Which species have no dipole moment?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Fill in the table. Central atom is listed first. A. Write the number of valence electrons below the formulaB. Draw the Lewis structureC & D. Write the Electron Group Geometry and Molecular Shape NamesE. Write the bond angleF. Write the molecular polarity. "P" for polar and "NP" for nonpolar.
SpeciesValenceElectrons(1 pt.)
LewisStructure(2 pt.)
Electron PairGeometryName(1 pt.)
Molecular ShapeName (1 pts.)
BondAngle (1 pt.)
Molecular Polarity(1 pt.)
PO43-
NOBr
Upload
1. What is the relationship between the following compounds?
H :0: H
H:0:
H
H-C=C-C-C-C-H
H-C-C-C=Ċ-H
H HH
H.
H-C-H
B. constitutional isomers
C. the same structure
A. isotopes
D. composed of different elements
E. no relationship
2. What is the correct Lewis structure for HN3, including the formal charges?
CIH
1) What is the type of molecule? a. AX2E3 b. AX3E2 c. AX5 d. AX2E2
2) What is the molecular geometry of GL2-? a. Linear b. Trigonal Bypyramidal c. Bent or v-shaped d. Seesaw
3) What is the approx bond angle formed by L-G-L bond if the correct molecular geometry is followed? a. 180° b. 120° c. 109.5° d. 90°
4) Considering that L is more electronegative than G, and the en difference is 0.2, is the molecular polar?
5) What is the formal charge of G?
6) What is the formal charge of the labeled atom? (refer to the blue arrow)
Chapter 1 Solutions
Organic Chemistry (8th Edition)
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - a. How many protons do the following species...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 4PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...
Ch. 1.3 - Explain why HCL has a smaller dipole moment than...Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 16PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 20PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 22PCh. 1.4 - Prob. 23PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 25PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.9 - For each of the given species: a. Draw its Lewis...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 35PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 38PCh. 1.14 - Describe the orbitals used in bonding and the bond...Ch. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - a. What is the hybridization of each of the carbon...Ch. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - What of the following molecules would you expect...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 50PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 54PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of each of the carbon...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 59PCh. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Predict the approximate bond angles for the...Ch. 1 - Prob. 62PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 67PCh. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 73PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 75PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - a. Draw a Lewis structure for each of the...Ch. 1 - There are three isomers with molecular formula...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 3. Do the following compounds have dipole moments? If so, use the crossed arrow to indicate the net molecular dipole on top of those structures. H a. b. H C. CI CI a CI 4. Calculate the formal charge for each of the indicated atoms in the compounds below. с H H CI CI H CI H F H₂C H₂C-O-B-F d. e.arrow_forwardAtom A has 4 valence electrons. Atom Z has 6 valence electrons. For the AZ3-2 ion How many valence electrons are in the structure? b. How many single bonds are in the structure? c. How many double bonds are in the structure? d. How many triple bonds are in the structure? e. How many lone pairs are on the central atom in the structure? f. What is the shape of the structure? g. What are the bond angles of this ion?arrow_forward1. Draw the complete Lewis Structure for each. Then determine the electron pair geometry (EPG), make a 3-dimensional representation (drawing), and determine the molecular geometry (MG) for all of them. Determine whether each molecule is polar or non-polar. Formula Lewis structure EPG 3-D drawing MG polar? a. PF3 b. CH;F2 Cl3 d. SC4 e. XeF4arrow_forward
- 1. How many valence electrons in each of the following: C Br N Cl- DRAWING LEWIS STRUCTURES 2. Complete the Lewis structure for CH,0H: 1. Identify how many total valence électrons are in your How many H. molecule valence e- 2. Arrange the atoms in the expected bonding order A H C O H does each atom bring in? 3. Arrange the electrons to that two electrons are in each bond 3. Draw the Lewis structures for the following: and, as much as possible, all valence shells are filled. Use CH,NH2 F2 lone pairs as needed and FOLLOW the OCTET RULE!!!!arrow_forward8. For each molecular fomula, detem ine the electron pair geom etry (EPG), make a 3-dimensional representation, and determ ine the molecular geometry. Determine whether the molecule is polar or non- polar. All of these have central atoms surounded by term inal atom s/one pairs only. Formula A. CHF3 Lewis structure EPG 3-D drawing Mol Geom. Polar molecule? B. SF2arrow_forwardFor each of the following, a. Draw the lewis structure b. Indicate the molecular geometry c. Indicate the bond angles 1. PCI3 2. IBr4- 3. SeF4 4. NH2- 5. SCN- 6. SnCl5-arrow_forward
- Lone Pai. ahedral 2. Consider the following Lewis symbols for elements X and Y. a. What are the Group numbers of X and Y? b. Will a compound of X and Y be ionic or molecular? Page 1 of 9 3. For each of the following bonds, indicate the positive end with a and the negative end with a. Draw an arrow to show the dipole for each. а. N—F b. Si-Br с. c. N-P 4. Which of the following bonds are polar? Circle the more electronegative atom in the pairs that are polar. C-O a. b. H Cl (gas) с. 0-O Page 3 of 9arrow_forwardDraw the Lewis structure for HCN.a.What is the electron domain geometry of C?b.What is the molecular geometry of C?c.What is the approximate bond angle of the H-C-N?d.Is this molecule polar?arrow_forward25.Which of the following does have H- bond? electronegativities: ) = 3.5, H = 2.1, C = 2.5, Cl = 3.0, S = 2.8 O || I. H- C- O-H II. SCl2 III . H | H - C - S -H | H IV. H H - C - O - H | H a.IIIb.IIc.I, II, IVd.I and IVarrow_forward
- Please answer number 4 a B C Darrow_forwardA. Fill in the following table. Acceptable geometries are those with formal charges closest to zero. First atom is the central atom in all formulas.arrow_forward15. Place the following in order of increasing A-X bond angle, where A represents the central atom and X represents the outer atoms in each molecule. HCN H₂O H₂O+ + A. H₂O = H₂O* < HCN. B. H₂O* < H₂O < HCN C. HCNarrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY